Chemistry · Textbook solutions
Solutions
Every solved example, exercise, and miscellaneous question, in the order the textbook teaches them. Plus every board question asked from this chapter. · 66 questions
Worked Examples
13 q
Solved Examples
Worked · 13
- Eg 1.1Calculate the mole fraction of ethylene glycol in a solution containing 20% of by mass.
- Eg 1.2Calculate the molarity of a solution containing of NaOH in solution.
- Eg 1.3Calculate molality of of ethanoic acid in of benzene.
- Eg 1.4If gas is bubbled through water at , how many millimoles of gas would dissolve in 1 litre of water? Assume that exerts a partial pressure of . Given that Henry's law constant for at is .
- Eg 1.5Vapour pressure of chloroform and dichloromethane at are and respectively. (i) Calculate the vapour pressure of the solution prepared by mixing of and of at and, (ii) mole fractions of each component in vapour phase.
- Eg 1.6The vapour pressure of pure benzene at a certain temperature is . A non-volatile, non-electrolyte solid weighing when added to of benzene (molar mass ). Vapour pressure of the solution, then, is . What is the molar mass of the solid substance?
- Eg 1.7of glucose, , is dissolved in of water in a saucepan. At what temperature will water boil at ? for water is .
- Eg 1.8The boiling point of benzene is . When of a non-volatile solute was dissolved in of benzene, the boiling point is raised to . Calculate the molar mass of the solute. for benzene is .
- Eg 1.9of ethylene glycol is mixed with of water. Calculate (a) the freezing point depression and (b) the freezing point of the solution.
- Eg 1.10of a non-electrolyte solute dissolved in of benzene lowered the freezing point of benzene by . The freezing point depression constant of benzene is . Find the molar mass of the solute.
- Eg 1.11of an aqueous solution of a protein contains of the protein. The osmotic pressure of such a solution at is found to be . Calculate the molar mass of the protein.
- Eg 1.12of benzoic acid dissolved in of benzene shows a depression in freezing point equal to . Molal depression constant for benzene is . What is the percentage association of acid if it forms dimer in solution?
- Eg 1.13of acetic acid , having density , is dissolved in of water. The depression in freezing point observed for this strength of acid was . Calculate the van't Hoff factor and the dissociation constant of acid.
Intext Questions
12 q
- Intext 1.1Calculate the mass percentage of benzene and carbon tetrachloride if of benzene is dissolved in of carbon tetrachloride.
- Intext 1.2Calculate the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride.
- Intext 1.3Calculate the molarity of each of the following solutions: (a) of in of solution (b) of diluted to .
- Intext 1.4Calculate the mass of urea required in making of molal aqueous solution.
- Intext 1.5Calculate (a) molality (b) molarity and (c) mole fraction of KI if the density of 20% (mass/mass) aqueous KI is .
- Intext 1.6, a toxic gas with rotten egg like smell, is used for the qualitative analysis. If the solubility of in water at STP is , calculate Henry's law constant.
- Intext 1.7Henry's law constant for in water is at . Calculate the quantity of in of soda water when packed under pressure at .
- Intext 1.8The vapour pressure of pure liquids A and B are and respectively, at . Find out the composition of the liquid mixture if total vapour pressure is . Also find the composition of the vapour phase.
- Intext 1.9Vapour pressure of pure water at is . of urea is dissolved in of water. Calculate the vapour pressure of water for this solution and its relative lowering.
- Intext 1.10Boiling point of water at is . How much sucrose is to be added to of water such that it boils at .
- Intext 1.11Calculate the mass of ascorbic acid (Vitamin C, ) to be dissolved in of acetic acid to lower its melting point by . .
- Intext 1.12Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving of polymer of molar mass in of water at .
Exercises
41 q
- Ex 1.1Define the term solution. How many types of solutions are formed? Write briefly about each type with an example.
- Ex 1.2Give an example of a solid solution in which the solute is a gas.
- Ex 1.3Define the following terms: (i) Mole fraction (ii) Molality (iii) Molarity (iv) Mass percentage.
- Ex 1.4Concentrated nitric acid used in laboratory work is 68% nitric acid by mass in aqueous solution. What should be the molarity of such a sample of the acid if the density of the solution is ?
- Ex 1.5A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? If the density of solution is , then what shall be the molarity of the solution?
- Ex 1.6How many mL of are required to react completely with mixture of and containing equimolar amounts of both?
- Ex 1.7A solution is obtained by mixing of 25% solution and of 40% solution by mass. Calculate the mass percentage of the resulting solution.
- Ex 1.8An antifreeze solution is prepared from of ethylene glycol and of water. Calculate the molality of the solution. If the density of the solution is , then what shall be the molarity of the solution?
- Ex 1.9A sample of drinking water was found to be severely contaminated with chloroform supposed to be a carcinogen. The level of contamination was 15 ppm (by mass): (i) express this in percent by mass (ii) determine the molality of chloroform in the water sample.
- Ex 1.10What role does the molecular interaction play in a solution of alcohol and water?
- Ex 1.11Why do gases always tend to be less soluble in liquids as the temperature is raised?
- Ex 1.12State Henry's law and mention some important applications.
- Ex 1.13The partial pressure of ethane over a solution containing of ethane is . If the solution contains of ethane, then what shall be the partial pressure of the gas?
- Ex 1.14What is meant by positive and negative deviations from Raoult's law and how is the sign of related to positive and negative deviations from Raoult's law?
- Ex 1.15An aqueous solution of 2% non-volatile solute exerts a pressure of at the normal boiling point of the solvent. What is the molar mass of the solute?
- Ex 1.16Heptane and octane form an ideal solution. At , the vapour pressures of the two liquid components are and respectively. What will be the vapour pressure of a mixture of of heptane and of octane?
- Ex 1.17The vapour pressure of water is at . Calculate vapour pressure of 1 molal solution of a non-volatile solute in it.
- Ex 1.18Calculate the mass of a non-volatile solute (molar mass ) which should be dissolved in octane to reduce its vapour pressure to 80%.
- Ex 1.19A solution containing of non-volatile solute exactly in of water has a vapour pressure of at . Further, of water is then added to the solution and the new vapour pressure becomes at . Calculate: (i) molar mass of the solute (ii) vapour pressure of water at .
- Ex 1.20A 5% solution (by mass) of cane sugar in water has freezing point of . Calculate the freezing point of 5% glucose in water if freezing point of pure water is .
- Ex 1.21Two elements A and B form compounds having formula and . When dissolved in of benzene , of lowers the freezing point by whereas of lowers it by . The molar depression constant for benzene is . Calculate atomic masses of A and B.
- Ex 1.22At , of glucose present in a litre of its solution has an osmotic pressure of . If the osmotic pressure of the solution is at the same temperature, what would be its concentration?
- Ex 1.23Suggest the most important type of intermolecular attractive interaction in the following pairs. (i) n-hexane and n-octane (ii) and (iii) and water (iv) methanol and acetone (v) acetonitrile and acetone .
- Ex 1.24Based on solute-solvent interactions, arrange the following in order of increasing solubility in n-octane and explain. Cyclohexane, , , .
- Ex 1.25Amongst the following compounds, identify which are insoluble, partially soluble and highly soluble in water? (i) phenol (ii) toluene (iii) formic acid (iv) ethylene glycol (v) chloroform (vi) pentanol.
- Ex 1.26If the density of some lake water is and contains of ions per kg of water, calculate the molarity of ions in the lake.
- Ex 1.27If the solubility product of is , calculate the maximum molarity of in aqueous solution.
- Ex 1.28Calculate the mass percentage of aspirin in acetonitrile when of is dissolved in of .
- Ex 1.29Nalorphene , similar to morphine, is used to combat withdrawal symptoms in narcotic users. Dose of nalorphene generally given is . Calculate the mass of aqueous solution required for the above dose.
- Ex 1.30Calculate the amount of benzoic acid required for preparing of solution in methanol.
- Ex 1.31The depression in freezing point of water observed for the same amount of acetic acid, trichloroacetic acid and trifluoroacetic acid increases in the order given above. Explain briefly.
- Ex 1.32Calculate the depression in the freezing point of water when of is added to of water. , .
- Ex 1.33of is dissolved in of water. The depression in the freezing point of water observed is . Calculate the van't Hoff factor and dissociation constant of fluoroacetic acid.
- Ex 1.34Vapour pressure of water at is . Calculate the vapour pressure of water at when of glucose is dissolved in of water.
- Ex 1.35Henry's law constant for the molality of methane in benzene at is . Calculate the solubility of methane in benzene at under .
- Ex 1.36of liquid A (molar mass ) was dissolved in of liquid B (molar mass ). The vapour pressure of pure liquid B was found to be . Calculate the vapour pressure of pure liquid A and its vapour pressure in the solution if the total vapour pressure of the solution is .
- Ex 1.37Vapour pressures of pure acetone and chloroform at are and respectively. Assuming that they form ideal solution over the entire range of composition, plot , , and as a function of . The experimental data observed for different compositions of mixture is:Plot this data also on the same graph paper. Indicate whether it has positive deviation or negative deviation from the ideal solution.
0 11.8 23.4 36.0 50.8 58.2 64.5 72.1 /mm Hg 0 54.9 110.1 202.4 322.7 405.9 454.1 521.1 /mm Hg 632.8 548.1 469.4 359.7 257.7 193.6 161.2 120.7 - Ex 1.38Benzene and toluene form ideal solution over the entire range of composition. The vapour pressure of pure benzene and toluene at are and respectively. Calculate the mole fraction of benzene in vapour phase if of benzene is mixed with of toluene.
- Ex 1.39The air is a mixture of a number of gases. The major components are oxygen and nitrogen with approximate proportion of 20% is to 79% by volume at . The water is in equilibrium with air at a pressure of . At if the Henry's law constants for oxygen and nitrogen at are and respectively, calculate the composition of these gases in water.
- Ex 1.40Determine the amount of dissolved in of water such that its osmotic pressure is at .
- Ex 1.41Determine the osmotic pressure of a solution prepared by dissolving of in of water at , assuming that it is completely dissociated.
What the board has asked from this chapter
Questions per paper · 21 papers · 2023 to 2026
Bars average the full papers of each year. 54 further questions come from set variants and are listed below.
2023: 4.2 questions per paper. 2024: 4 questions per paper. 2025: 5 questions per paper. 2026: 4.4 questions per paper
2026
32 q
- 2Which of the following is the correct expression of which depends upon the nature of solvent ?
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Colligative Properties and Determination of Molar Mass - 2Which of the following solutions will have the lowest freezing point in water ?
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Colligative Properties and Determination of Molar Mass - 3Which of the following solutions will have the highest osmotic pressure ?
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Colligative Properties and Determination of Molar Mass - 7The boiling point of one molal NaCl solution, assuming NaCl to be completely dissociated in water is : ( for water = K kg )
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Abnormal Molar Masses - 8When a liquid and its vapour are at equilibrium and the pressure is suddenly decreased :
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Vapour Pressure of Liquid Solutions - 8The boiling point of an azeotropic mixture of water and ethanol is less than that of pure water and ethanol. The mixture shows :
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Ideal and Non-ideal Solutions - 9The mole fraction of a solute in molal aqueous solution is :
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Expressing Concentration of Solutions - 10The boiling point of an azeotropic mixture of water and nitric acid is more than that of pure water and nitric acid. The mixture shows :
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Ideal and Non-ideal Solutions - 121 mole of liquid A and 2 moles of liquid B make a solution having a total vapour pressure 40 torr. The vapour pressure of pure A and pure B are 30 torr and 45 torr respectively. The above solution :
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Ideal and Non-ideal Solutions - For questions number 13 to 16, two statements are given – one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (A), (B), (C) and (D) as given below :13Assertion (A) : It is not possible to separate the components of an azeotrope by fractional distillation. Reason (R) : Components of an azeotrope have the same composition in liquid and vapour phase and boil at a constant temperature.
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Ideal and Non-ideal Solutions - For questions number 13 to 16, two statements are given – one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (A), (B), (C) and (D) as given below :15Assertion (A) : Components of azeotropes are easily separated by fractional distillation. Reason (R) : Components of an azeotrope have same composition in liquid and vapour phase.
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Ideal and Non-ideal Solutions - For questions number 13 to 16, two statements are given – one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (A), (B), (C) and (D) as given below :16Assertion (A) : It is not possible to separate the components of an azeotrope by fractional distillation. Reason (R) : Minimum boiling azeotrope is formed by the solutions showing large positive deviation from Raoult’s law.
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Ideal and Non-ideal Solutions - 17What type of deviation is shown by a mixture of chloroform and acetone from Raoult’s law ? Give reason. What will happen to the boiling point of the solution on mixing chloroform and acetone ?Ideal and Non-ideal Solutions
- 17What type of deviation from Raoult’s law is shown by mixture of ethanol and acetone ? Give reason. What will happen to the boiling point of the solution on mixing ethanol and acetone ?Ideal and Non-ideal Solutions
- 17What type of deviation from Raoult’s law is shown by a mixture of phenol and aniline ? Give reason. What will happen to the boiling point of the solution on mixing phenol and aniline ?Ideal and Non-ideal Solutions
- 17 (A)molal aqueous solution of trichloroacetic acid is heated to its boiling point. Boiling point of this solution was found to be C. Calculate the van’t Hoff factor for trichloroacetic acid. (Given : for water = K kg )Abnormal Molar Masses
- 18 (a)Explain the following with the help of Henry’s law : (i) Bends (ii) AnoxiaSolubility
- 17 (B)State Henry’s law. Calculate the mole fraction of in water at 298 K under 760 mm Hg. (Given : for in at 298 K = mm Hg)Solubility
- 18 (b)How does sprinkling of salt help in clearing the snow covered roads in hilly areas ? Write the name of the colligative property involved in this process.Colligative Properties and Determination of Molar Mass
- 19Explain why, on addition of 1 mol of KCl to 1 litre of water, the boiling point of water increases, while the addition of 1 mol of methyl alcohol to 1 litre of water decreases the boiling point.Colligative Properties and Determination of Molar Mass
- 22When 1.5 g of a non-volatile solute was dissolved in 90 g of benzene, the boiling point of benzene got raised from 353.23 K to 353.93 K. Calculate the molar mass of the solute. (Given for benzene = 2.52 K kg )Colligative Properties and Determination of Molar Mass
- 22A solution containing 8.0 g of a non-volatile solute in 100 g of diethyl ether boils at 36.86 °C whereas pure diethyl ether boils at 35.60 °C. Determine the molar mass of the solute. ( for diethyl ether = 2.02 K kg )Colligative Properties and Determination of Molar Mass
- 2260 g of glucose is dissolved in 250 g of water. Calculate the freezing point of this solution. (molar mass of glucose = 180 g , for water = 1.86 K kg )Colligative Properties and Determination of Molar Mass
- 24An antifreeze solution is prepared by dissolving 31 g of ethylene glycol (Molar mass = ) in 600 g of water. Calculate the freezing point of the solution. ( for water = )Colligative Properties and Determination of Molar Mass
- 24Calculate the boiling point of a solution containing 0.61 g of benzoic acid (Molar mass = 122 g ) in 5 g of in which it dimerises to the extent of 88%. The boiling point and of are 46.2 °C and 2.3 K kg respectively.Abnormal Molar Masses
- 26Calculate the vapour pressure of a solution containing 61 g of benzoic acid (molar mass = 122 g ) dissolved in 500 g of benzene when the vapour pressure of pure benzene at this temperature of experiment is 66 torr. Assume complete dimerization of benzoic acid in benzene.Abnormal Molar Masses
- Osmosis is a process by which the molecules of a solvent pass from a solution of low solute concentration to a solution of high solute concentration through a semi-permeable membrane. Osmotic pressure is a colligative property. When the applied pressure on a solution exceeds its osmotic pressure, reverse osmosis occurs. When two solutions are separated by a semipermeable membrane and they have same osmotic pressure they are said to be isotonic. Of the two solutions separated by a semipermeable membrane, if one is a lower osmotic pressure, it is said to be hypotonic relative to the second solution. If it has a higher osmotic pressure, than the second solution, it is said to be hypertonic relative to the second solution. The osmotic pressure associated with the fluid inside the blood cell is equivalent to that of 0.9% (mass/volume) sodium chloride solution called normal saline solution and it is safe to inject intravenously. Osmotic pressure is vital in daily life and nature. It helps in explain, why IV fluids match blood's osmotic pressure, its also the principle behind food preservation using salt or sugar.29 (a)Calculate the amount of (i = 2.59) dissolved in 2.46 litre of water such that its osmotic pressure is 0.70 atm at 27°C. [Given : R = 0.082 L atm , molar mass of = 111 g ]Colligative Properties and Determination of Molar Mass
- Osmosis is a process by which the molecules of a solvent pass from a solution of low solute concentration to a solution of high solute concentration through a semi-permeable membrane. Osmotic pressure is a colligative property. When the applied pressure on a solution exceeds its osmotic pressure, reverse osmosis occurs. When two solutions are separated by a semipermeable membrane and they have same osmotic pressure they are said to be isotonic. Of the two solutions separated by a semipermeable membrane, if one is a lower osmotic pressure, it is said to be hypotonic relative to the second solution. If it has a higher osmotic pressure, than the second solution, it is said to be hypertonic relative to the second solution. The osmotic pressure associated with the fluid inside the blood cell is equivalent to that of 0.9% (mass/volume) sodium chloride solution called normal saline solution and it is safe to inject intravenously. Osmotic pressure is vital in daily life and nature. It helps in explain, why IV fluids match blood's osmotic pressure, its also the principle behind food preservation using salt or sugar.29 (b)When raisins are kept in water, they get swollen. Name the phenomenon involved in this process.Colligative Properties and Determination of Molar Mass
- Osmosis is a process by which the molecules of a solvent pass from a solution of low solute concentration to a solution of high solute concentration through a semi-permeable membrane. Osmotic pressure is a colligative property. When the applied pressure on a solution exceeds its osmotic pressure, reverse osmosis occurs. When two solutions are separated by a semipermeable membrane and they have same osmotic pressure they are said to be isotonic. Of the two solutions separated by a semipermeable membrane, if one is a lower osmotic pressure, it is said to be hypotonic relative to the second solution. If it has a higher osmotic pressure, than the second solution, it is said to be hypertonic relative to the second solution. The osmotic pressure associated with the fluid inside the blood cell is equivalent to that of 0.9% (mass/volume) sodium chloride solution called normal saline solution and it is safe to inject intravenously. Osmotic pressure is vital in daily life and nature. It helps in explain, why IV fluids match blood's osmotic pressure, its also the principle behind food preservation using salt or sugar.29 (b) ORWhy osmotic pressure is more advantageous than other colligative properties ?Colligative Properties and Determination of Molar Mass
- Osmosis is a process by which the molecules of a solvent pass from a solution of low solute concentration to a solution of high solute concentration through a semi-permeable membrane. Osmotic pressure is a colligative property. When the applied pressure on a solution exceeds its osmotic pressure, reverse osmosis occurs. When two solutions are separated by a semipermeable membrane and they have same osmotic pressure they are said to be isotonic. Of the two solutions separated by a semipermeable membrane, if one is a lower osmotic pressure, it is said to be hypotonic relative to the second solution. If it has a higher osmotic pressure, than the second solution, it is said to be hypertonic relative to the second solution. The osmotic pressure associated with the fluid inside the blood cell is equivalent to that of 0.9% (mass/volume) sodium chloride solution called normal saline solution and it is safe to inject intravenously. Osmotic pressure is vital in daily life and nature. It helps in explain, why IV fluids match blood's osmotic pressure, its also the principle behind food preservation using salt or sugar.29 (c)Which phenomenon is responsible for desalination of sea water ?Colligative Properties and Determination of Molar Mass
- 31 (A)(i) Calculate the freezing point of a solution when g of was dissolved in 250 g of water, assuming undergoes complete dissociation. (Given : Molar mass of = 184 g , for water = K kg ) (ii) Write two differences between ideal and non-ideal solutions.Abnormal Molar Masses
- 31 (B)(i) A solution is prepared by dissolving g of potassium sulphate in 2 L of water at C. Assuming potassium sulphate is completely dissociated, determine its osmotic pressure. (Given : R = L atm , Molar mass of = 174 g ) (ii) What type of azeotrope will be formed by a solution of acetone and chloroform ? Give reason.Abnormal Molar Masses
2025
44 q
- 1In case of association, abnormal molar mass of solute will
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Abnormal Molar Masses - 2Which of the following solutions will have the highest boiling point in water ?
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Colligative Properties and Determination of Molar Mass - 2Which of the following aqueous solutions will have the highest osmotic pressure ?
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Colligative Properties and Determination of Molar Mass - 2Which of the following solution in water will have the lowest freezing point ?
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Colligative Properties and Determination of Molar Mass - 5The value of Henry's constant is :
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Solubility - 7Which of the following aqueous solutions will have the highest freezing point ?
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Colligative Properties and Determination of Molar Mass - 8The freezing point of one molal KCl solution, assuming KCl to be completely dissociated in water, is : ( for water = K kg )
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Abnormal Molar Masses - 8A solution of acetone in chloroform :
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Ideal and Non-ideal Solutions - 8On mixing 30 mL of acetone with 20 mL of chloroform, the total volume of solution is :
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Ideal and Non-ideal Solutions - 9A solution of acetone in ethanol :
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Ideal and Non-ideal Solutions - 12An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because ________.
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Colligative Properties and Determination of Molar Mass - For Questions number 13 to 16, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (A), (B), (C) and (D) as given below.14Assertion (A) : Cooking time is reduced in pressure cooker. Reason (R) : Boiling point of water inside the pressure cooker is lowered down.
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Vapour Pressure of Liquid Solutions - For Questions number 13 to 16, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (A), (B), (C) and (D) as given below.14Assertion (A) : Cooking time is reduced in pressure cooker. Reason (R) : Boiling point of water inside the pressure cooker is elevated.
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Vapour Pressure of Liquid Solutions - For Questions number 13 to 16, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (A), (B), (C) and (D) as given below.14Assertion (A) : Henry's law constant decreases with increase in temperature. Reason (R) : As the temperature increases, solubility of gases in liquids decreases.
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Solubility - For Questions number 13 to 16, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (A), (B), (C) and (D) as given below.14Assertion (A) : Aquatic species are more comfortable in cold water than in warm water. Reason (R) : Solubility of oxygen gas in water decreases with increase in temperature.
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Solubility - 17State Raoult’s law for a solution containing volatile components. Why is the vapour pressure of an aqueous solution of glucose lower than that of water ?Vapour Pressure of Liquid Solutions
- 17Define osmotic pressure. Why is measurement of osmotic pressure method preferred for the determination of molar masses of macromolecules such as proteins and polymers ?Colligative Properties and Determination of Molar Mass
- 17 (A)Give reasons : (a) Cooking is faster in pressure cooker than in an open pan. (b) On mixing liquid X and liquid Y, volume of the resulting solution decreases. What type of deviation from Raoult's law is shown by the resulting solution ? What change in temperature would you observe after mixing liquids X and Y ?Ideal and Non-ideal Solutions
- 17What is meant by negative deviation from Raoult’s law ? Give an example. What type of azeotrope is formed by negative deviation ?Ideal and Non-ideal Solutions
- 17 (a)Calculate the elevation of boiling point of a solution when 3 g of (Molar mass = 111 g ) was dissolved in 260 g of water, assuming that undergoes complete dissociation. ( for water = K kg )Abnormal Molar Masses
- 17(a) A and B liquids on mixing show rise in temperature. Which type of deviation from Raoult’s law is there and why ? (b) Why can azeotropic mixture not be separated by fractional distillation ?Ideal and Non-ideal Solutions
- 17What is meant by positive deviation from Raoult’s law ? Give an example. What type of azeotrope is formed by positive deviation ?Ideal and Non-ideal Solutions
- 17State Henry’s law. Why are aquatic species more comfortable in cold water as compared to warm water ?Solubility
- 17 (b)Liquids 'X' and 'Y' form an ideal solution. The vapour pressure of pure 'X' and pure 'Y' are 120 mm Hg and 160 mm Hg respectively. Calculate the vapour pressure of the solution containing equal moles of 'X' and 'Y'.Vapour Pressure of Liquid Solutions
- 17 (B)Define Azeotrope. What type of Azeotrope is formed by negative deviation from Raoult's law ? Give an example.Ideal and Non-ideal Solutions
- 22Vapour pressure of pure water at 298 K is mm Hg. Calculate the lowering in vapour pressure of an aqueous solution which freezes at . ( of water = K kg )Colligative Properties and Determination of Molar Mass
- 22A solution of glucose (molar mass = 180 g ) in water has a boiling point of 100.20 °C. Calculate the freezing point of the same solution. Molal constants for water and are 1.86 K kg and 0.512 K kg respectively.Colligative Properties and Determination of Molar Mass
- 22Henry's law constant for in water is Pa at 298 K. Calculate the number of moles of in 540 g of soda water when packed under Pa at the same temperature.Solubility
- 22g of acetic acid (Molar mass = 60 g ) dissolved in 30 g of benzene shows a depression in freezing point equal to °C. Calculate the percentage association of acid if it forms a dimer in the solution. (Given : for benzene = K kg )Abnormal Molar Masses
- 22Henry's law constant for in water is Pa at 298 K. Calculate the number of moles of in 500 ml of soda water when packed under Pa at the same temperature.Solubility
- 22A solution containing 15 g urea (molar mass = 60 g ) per litre of solution in water has the same osmotic pressure (isotonic) as a solution of glucose (molar mass = 180 g ) in water. Calculate the mass of glucose present in one litre of its solution.Colligative Properties and Determination of Molar Mass
- 22At 25 °C the saturated vapour pressure of water is 24 mm Hg. Find the saturated vapour pressure of a 5% aqueous solution of urea at the same temperature. (Molar mass of urea = 60 g )Colligative Properties and Determination of Molar Mass
- 22 (a)Shweta mixed two liquids A and B of 10 mL each. After mixing, the volume of the solution was found to be mL. (i) Why was there a volume change after mixing the liquids ? (ii) Will there be an increase or decrease of temperature after mixing ? (iii) Give one example for this type of solution.Ideal and Non-ideal Solutions
- 22 (b)(i) How does sprinkling of salt help in clearing the snow covered roads in hilly areas ? (ii) What happens when red blood cells are kept in (mass/vol) NaCl solution ? Justify your answer. (iii) Write an application of reverse osmosis.Colligative Properties and Determination of Molar Mass
- 25An aqueous solution of NaOH was made and its molar mass from the measurement of osmotic pressure at was found to be 25 g . Calculate the percentage dissociation of NaOH in this solution. [Atomic mass : Na = 23 u, O = 16 u, H = 1 u]Abnormal Molar Masses
- 27An aqueous solution of NaOH was made and its molar mass from the measurement of osmotic pressure at was found to be 28 g . Calculate the percentage dissociation of NaOH in this solution. [Atomic mass : Na = u, O = u, H = u]Abnormal Molar Masses
- According to the generally accepted definition of the ideal solution there are equal interaction forces acting between molecules belonging to the same or different species. (This is equivalent to the statement that the activity of the components equals the concentration.) Strictly speaking, this condition is fulfilled only in exceptional cases for mixtures (optical isomers, isotopic mixtures of an element, hydrocarbon mixtures). It is still usual to talk about ideal solutions as limiting cases in reality since very dilute solutions behave ideally with respect to the solvent. This view is further supported by the fact that Raoult's law empirically found for describing the behaviour of the solvent in dilute solutions can be deduced thermodynamically via the assumption of ideal behaviour of the solvent.29 (a)Give one example of miscible liquid pair which shows negative deviation from Raoult's law. What is the reason for such deviation ?Ideal and Non-ideal Solutions
- The spontaneous flow of the solvent through a semipermeable membrane from a pure solvent to a solution or from a dilute solution to a concentrated solution is called osmosis. The phenomenon of osmosis can be demonstrated by taking two eggs of the same size. In an egg, the membrane below the shell and around the egg material is semipermeable. The outer hard shell can be removed by putting the egg in dilute hydrochloric acid. After removing the hard shell, one egg is placed in distilled water and the other in a saturated salt solution. After some time, the egg placed in distilled water swells-up while the egg placed in salt solution shrinks. The external pressure applied to stop the osmosis is termed as osmotic pressure (a colligative property). Reverse osmosis takes place when the applied external pressure becomes larger than the osmotic pressure.29 (a)Define reverse osmosis. Name one SPM which can be used in the process of reverse osmosis.Colligative Properties and Determination of Molar Mass
- According to the generally accepted definition of the ideal solution there are equal interaction forces acting between molecules belonging to the same or different species. (This is equivalent to the statement that the activity of the components equals the concentration.) Strictly speaking, this condition is fulfilled only in exceptional cases for mixtures (optical isomers, isotopic mixtures of an element, hydrocarbon mixtures). It is still usual to talk about ideal solutions as limiting cases in reality since very dilute solutions behave ideally with respect to the solvent. This view is further supported by the fact that Raoult's law empirically found for describing the behaviour of the solvent in dilute solutions can be deduced thermodynamically via the assumption of ideal behaviour of the solvent.29 (b) (i)State Raoult's law for a solution containing volatile components.Vapour Pressure of Liquid Solutions
- The spontaneous flow of the solvent through a semipermeable membrane from a pure solvent to a solution or from a dilute solution to a concentrated solution is called osmosis. The phenomenon of osmosis can be demonstrated by taking two eggs of the same size. In an egg, the membrane below the shell and around the egg material is semipermeable. The outer hard shell can be removed by putting the egg in dilute hydrochloric acid. After removing the hard shell, one egg is placed in distilled water and the other in a saturated salt solution. After some time, the egg placed in distilled water swells-up while the egg placed in salt solution shrinks. The external pressure applied to stop the osmosis is termed as osmotic pressure (a colligative property). Reverse osmosis takes place when the applied external pressure becomes larger than the osmotic pressure.29 (b) (i)What do you expect to happen when red blood corpuscles (RBC's) are placed in 0.5% solution ?Colligative Properties and Determination of Molar Mass
- The spontaneous flow of the solvent through a semipermeable membrane from a pure solvent to a solution or from a dilute solution to a concentrated solution is called osmosis. The phenomenon of osmosis can be demonstrated by taking two eggs of the same size. In an egg, the membrane below the shell and around the egg material is semipermeable. The outer hard shell can be removed by putting the egg in dilute hydrochloric acid. After removing the hard shell, one egg is placed in distilled water and the other in a saturated salt solution. After some time, the egg placed in distilled water swells-up while the egg placed in salt solution shrinks. The external pressure applied to stop the osmosis is termed as osmotic pressure (a colligative property). Reverse osmosis takes place when the applied external pressure becomes larger than the osmotic pressure.29 (b) (ii)Which one of the following will have higher osmotic pressure in 1 M or 1 M urea solution. Justify your answer.Abnormal Molar Masses
- According to the generally accepted definition of the ideal solution there are equal interaction forces acting between molecules belonging to the same or different species. (This is equivalent to the statement that the activity of the components equals the concentration.) Strictly speaking, this condition is fulfilled only in exceptional cases for mixtures (optical isomers, isotopic mixtures of an element, hydrocarbon mixtures). It is still usual to talk about ideal solutions as limiting cases in reality since very dilute solutions behave ideally with respect to the solvent. This view is further supported by the fact that Raoult's law empirically found for describing the behaviour of the solvent in dilute solutions can be deduced thermodynamically via the assumption of ideal behaviour of the solvent.29 (b) (ii)Raoult's law is a special case of Henry's law. Comment.Solubility
- The spontaneous flow of the solvent through a semipermeable membrane from a pure solvent to a solution or from a dilute solution to a concentrated solution is called osmosis. The phenomenon of osmosis can be demonstrated by taking two eggs of the same size. In an egg, the membrane below the shell and around the egg material is semipermeable. The outer hard shell can be removed by putting the egg in dilute hydrochloric acid. After removing the hard shell, one egg is placed in distilled water and the other in a saturated salt solution. After some time, the egg placed in distilled water swells-up while the egg placed in salt solution shrinks. The external pressure applied to stop the osmosis is termed as osmotic pressure (a colligative property). Reverse osmosis takes place when the applied external pressure becomes larger than the osmotic pressure.29 (c)Why osmotic pressure is a colligative property ?Colligative Properties and Determination of Molar Mass
- According to the generally accepted definition of the ideal solution there are equal interaction forces acting between molecules belonging to the same or different species. (This is equivalent to the statement that the activity of the components equals the concentration.) Strictly speaking, this condition is fulfilled only in exceptional cases for mixtures (optical isomers, isotopic mixtures of an element, hydrocarbon mixtures). It is still usual to talk about ideal solutions as limiting cases in reality since very dilute solutions behave ideally with respect to the solvent. This view is further supported by the fact that Raoult's law empirically found for describing the behaviour of the solvent in dilute solutions can be deduced thermodynamically via the assumption of ideal behaviour of the solvent.29 (c)Write two characteristics of an ideal solution.Ideal and Non-ideal Solutions
2024
34 q
- 1Van’t Hoff factor for solution, assuming complete ionization is
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Abnormal Molar Masses - 4For an electrolyte undergoing association in a solvent, the van't Hoff factor :
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Abnormal Molar Masses - 4The system that forms maximum boiling azeotrope is :
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Ideal and Non-ideal Solutions - 5Phenol dimerises in benzene having van't Hoff factor . Its degree of association is :
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Abnormal Molar Masses - 6Isotonic solutions have the same
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Colligative Properties and Determination of Molar Mass - 8An azeotropic solution of two liquids has boiling point lower than either of them when it :
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Ideal and Non-ideal Solutions - 8Van’t Hoff factor for solution assuming the complete dissociation is
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Abnormal Molar Masses - 8An azeotropic solution of two liquids has boiling point higher than either of them when it :
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Ideal and Non-ideal Solutions - 8On mixing 10 mL of acetone with 50 mL of chloroform, the total volume of the solution will be :
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Ideal and Non-ideal Solutions - 9The relative lowering of vapour pressure of an aqueous solution containing non-volatile solute is . The mole fraction of the non-volatile solute is :
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Colligative Properties and Determination of Molar Mass - 11A 1% solution of solute 'X' is isotonic with a 6% solution of sucrose (molar mass = 342 g ). The molar mass of solute 'X' is :
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Colligative Properties and Determination of Molar Mass - 12Van’t Hoff factor for solution, assuming complete ionization is
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Abnormal Molar Masses - For Questions number 13 to 16, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (A), (B), (C) and (D) as given below.13Assertion (A) : and are zero for non-ideal solutions. Reason (R) : Solute-solvent interactions are not same as pure solute-solute and pure solvent-solvent interactions in non-ideal solutions.
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Ideal and Non-ideal Solutions - For Questions number 13 to 16, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (A), (B), (C) and (D) as given below.13Assertion (A) : Addition of ethylene glycol to water lowers its freezing point. Reason (R) : Ethylene glycol is insoluble in water due to lack of its ability to form hydrogen bonds with water molecules.
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Colligative Properties and Determination of Molar Mass - For Questions number 13 to 16, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (A), (B), (C) and (D) as given below.13Assertion (A) : When NaCl is added to water a depression in freezing point is observed. Reason (R) : NaCl undergoes dissociation in water.
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Colligative Properties and Determination of Molar Mass - For Questions number 13 to 16, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (A), (B), (C) and (D) as given below.13Assertion (A) : and are zero for an ideal solution. Reason (R) : The solution which obeys Raoult's law over the entire range of concentration is called an ideal solution.
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Ideal and Non-ideal Solutions - For Questions number 13 to 16, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (A), (B), (C) and (D) as given below.15Assertion (A) : for an ideal solution is not equal to zero. Reason (R) : A – B interactions in an ideal solution are same as between A – A and B – B interactions.
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Ideal and Non-ideal Solutions - For Questions number 13 to 16, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (A), (B), (C) and (D) as given below.16Assertion (A) : When NaCl is added in water, elevation in boiling point is observed. Reason (R) : Elevation in boiling point is a colligative property.
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Colligative Properties and Determination of Molar Mass - 17 (a)Define molal depression constant. How is it related to enthalpy of fusion ?Colligative Properties and Determination of Molar Mass
- 17A 6% solution of glucose (molar mass = 180 g ) is isotonic with solution of an unknown organic substance. Calculate the molecular weight of the unknown organic substance.Colligative Properties and Determination of Molar Mass
- 18Calculate the molar mass of a compound when 6.3 g of it is dissolved in 27 g of chloroform to form a solution that has a boiling point of . The boiling point of pure chloroform is and for chloroform is .Colligative Properties and Determination of Molar Mass
- 18A solution containing 60 g of a non-volatile solute in 250 g of water freezes at 270.67 K. Calculate the molar mass of the solute. ( of water = 1.86 K kg ).Colligative Properties and Determination of Molar Mass
- 1818 g of a non-volatile solute is dissolved in 200 g of freezes at 272.07 K. Calculate the molecular mass of solute ( for water = 1.86 )Colligative Properties and Determination of Molar Mass
- 17 (b)What type of deviation is shown by ethanol and acetone mixture ? Give reason. What type of azeotropic mixture is formed by that deviation ?Ideal and Non-ideal Solutions
- 21A 4% solution of urea (molar mass = 60 g ) is isotonic with solution of an unknown organic substance. Calculate the molecular weight of the unknown organic substance.Colligative Properties and Determination of Molar Mass
- 21A 3% solution of glucose (molar mass = 180 g ) is isotonic with solution of an unknown organic substance. Calculate the molecular weight of the unknown organic substance.Colligative Properties and Determination of Molar Mass
- 22A solution is prepared by dissolving 5 g of a non-volatile solute in 200 g of water. It has a vapour pressure of mm Hg at 300 K. Calculate the molar mass of the solute. (Vapour pressure of pure water at 300 K = 32 mm Hg)Colligative Properties and Determination of Molar Mass
- 26The vapour pressure of a solvent at 283 K is 100 mm Hg. Calculate the vapour pressure of a dilute solution containing 1 mole of a strong electrolyte AB in 50 moles of the solvent at 283 K (assuming complete dissociation of solute AB).Abnormal Molar Masses
- 31 (a)(i) At the same temperature, gas is more soluble in water than gas. Which one of them will have higher value of and why ? (ii) How does the size of blood cells change when placed in an aqueous solution containing more than (mass/volume) sodium chloride ? (iii) 1 molal aqueous solution of an electrolyte is 60% ionized. Calculate the boiling point of the solution. (Given : for )Abnormal Molar Masses
- 32 (a)(i) Ishan’s automobile radiator is filled with 1.0 kg of water. How many grams of ethylene glycol (Molar mass = 62 g ) must Ishan add to get the freezing point of the solution lowered to . for water is 1.86 K kg . (ii) What type of deviation from Raoult’s law is shown by ethanol and acetone mixture ? Give reason.Colligative Properties and Determination of Molar Mass
- 31 (b)(i) The vapour pressures of A and B at are 75 mm Hg and 25 mm Hg, respectively. If A and B are mixed such that the mole fraction of A in the mixture is , then calculate the mole fraction of B in vapour phase. (ii) Define colligative property. Which colligative property is preferred for the molar mass determination of macromolecules ? (iii) Why are equimolar solutions of sodium chloride and glucose not isotonic ?Colligative Properties and Determination of Molar Mass
- 32 (a)(i) Define reverse osmosis. (ii) Why are aquatic species more comfortable in cold water in comparison to warm water ? (iii) A solution containing 2 g of glucose (M = 180 g ) in 100 g of water is prepared at 303 K. If the vapour pressure of pure water at 303 K is 32.8 mm Hg, what would be the vapour pressure of the solution ?Vapour Pressure of Liquid Solutions
- 32 (b)(i) Predict whether Van't Hoff factor will be less or greater than one, when Ethanoic acid is dissolved in benzene. (ii) Define ideal solution. (iii) Calculate the mass of (molar mass = 111 g ) to be dissolved in 500 g of water to lower its freezing point by 2K, assuming that undergoes complete dissociation. ( for water = 1.86 K kg )Abnormal Molar Masses
- 32 (b)(i) Boiling point of water at 750 mm Hg pressure is . How much sucrose (Molar mass = 342 g ) is to be added to 500 g of water such that it boils at ? ( for water K kg ). (ii) State Henry’s law and write its any one application.Colligative Properties and Determination of Molar Mass
2023
37 q
- 1On dissolving ammonium chloride in water at room temperature, the solution feels cool to touch. Under which of the following conditions does salt dissolve faster ?
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Solubility - 1A compound undergoes complete dimerization in a given organic solvent. The Van't Hoff factor 'i' is :
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Abnormal Molar Masses - 1A compound undergoes complete dissociation in water. The Van't Hoff factor 'i' is :
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Abnormal Molar Masses - 1The colligative property used for the determination of molar mass of polymers and proteins is :
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Colligative Properties and Determination of Molar Mass - 1A compound undergoes complete tetramerization in a given organic solvent. The Van't Hoff factor 'i' is :
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Abnormal Molar Masses - 2Low concentration of oxygen in the blood and tissues of people living at high altitude is due to :
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Solubility - 7Which of the following aqueous solution will have highest boiling point ?
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Colligative Properties and Determination of Molar Mass - 7Out of the following 1.0 M aqueous solutions, which one will show largest freezing point depression ?
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Abnormal Molar Masses - 71 mole of liquid A and 2 moles of liquid B make a solution having a total vapour pressure 40 torr. The vapour pressure of pure A and pure B are 45 torr and 30 torr respectively. The above solution
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Ideal and Non-ideal Solutions - 7Solubility of gas in liquid decreases with increase in
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Solubility - 7Value of Henry's constant :
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Solubility - 7An azeotropic mixture of two liquids will have a boiling point lower than either of the two liquids when it
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Ideal and Non-ideal Solutions - 9If molality of a dilute solution is doubled, the value of the molal elevation constant will be
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Colligative Properties and Determination of Molar Mass - 9An azeotropic mixture of two liquids has a boiling point higher than either of the two liquids when it :
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Ideal and Non-ideal Solutions - 10Which of the following colligative property is used to find the molar mass of proteins ?
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Colligative Properties and Determination of Molar Mass - 10Which one of the following pairs will not form an ideal solution ?
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Ideal and Non-ideal Solutions - 10Isotonic solutions have :
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Colligative Properties and Determination of Molar Mass - Given below are two statements labelled as Assertion (A) and Reason (R). Select the most appropriate answer from the options given below :15Assertion (A) : Osmotic pressure is a colligative property. Reason (R) : Osmotic pressure is proportional to the molality.
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Colligative Properties and Determination of Molar Mass - Given below are two statements labelled as Assertion (A) and Reason (R). Select the most appropriate answer from the options given below :15Assertion (A) : The enthalpy of mixing is equal to zero for an ideal solution. Reason (R) : For an ideal solution the interaction between solute and solvent molecules is stronger than the interactions between solute-solute or solvent-solvent molecules.
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Ideal and Non-ideal Solutions - Given below are two statements labelled as Assertion (A) and Reason (R). Select the most appropriate answer from the options given below :15Assertion (A) : Elevation in boiling point is a colligative property. Reason (R) : The lowering of vapour pressure of solution causes elevation in boiling point.
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Colligative Properties and Determination of Molar Mass - For Questions number 15 to 18, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (a), (b), (c) and (d) as given below.15Assertion (A) : When glucose is added to water, an elevation in boiling point is observed. Reason (R) : The lowering of vapour pressure causes elevation in the boiling point.
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Colligative Properties and Determination of Molar Mass - For Questions number 15 to 18, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (a), (b), (c) and (d) as given below.15Assertion (A) : When NaCl is added to water, a depression in freezing point is observed. Reason (R) : The lowering of vapour pressure of a solution causes depression in the freezing point.
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Colligative Properties and Determination of Molar Mass - For Questions number 15 to 18, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (a), (b), (c) and (d) as given below.15Assertion (A) : When NaCl is added to water, a depression in freezing point is observed. Reason (R) : The vapour pressure of solution is increased which causes depression in freezing point.
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Colligative Properties and Determination of Molar Mass - 19What is Henry's law ? Give one application of it.Solubility
- 19A solution is prepared by dissolving 10 g of non-volatile solute in 200 g of water. It has a vapour pressure of mm Hg at 308 K. Calculate the molar mass of the solute. (Vapour pressure of pure water at 308 K = 32 mm Hg)Colligative Properties and Determination of Molar Mass
- 19The vapour pressure of pure liquid X and pure liquid Y at 25 °C are 120 mm Hg and 160 mm Hg respectively. If equal moles of X and Y are mixed to form an ideal solution, calculate the vapour pressure of the solution.Vapour Pressure of Liquid Solutions
- 20 (a)What type of deviation from Raoult's law is shown by a mixture of ethanol and acetone ? Give reason.Ideal and Non-ideal Solutions
- 20 (b)Define Azeotrope. What type of azeotrope is formed by negative deviation from Raoult's law ? Give an example.Ideal and Non-ideal Solutions
- 23On mixing liquid X and liquid Y, volume of the resulting solution decreases. What type of deviation from Raoult's law is shown by the resulting solution ? What change in temperature would you observe after mixing liquids X and Y ?Ideal and Non-ideal Solutions
- 25Give reasons for the following : (a) Aquatic animals are more comfortable in cold water in comparison to warm water. (b) Sprinkling of salt helps in clearing the snow-covered roads in hilly areas.Solubility
- 26(a) Differentiate between Ideal solution and Non-ideal solution. (b) 30 g of urea is dissolved in 846 g of water. Calculate the vapour pressure of water for this solution if vapour pressure of pure water at 298 K is mm Hg.Ideal and Non-ideal Solutions
- 26Give reason : (a) Measurement of osmotic pressure method is preferred for the determination of molar masses of macromolecules such as proteins and polymers. (b) Aquatic animals are more comfortable in cold water than in warm water. (c) Elevation of boiling point of 1 M KCl solution is nearly double than that of 1 M sugar solution.Colligative Properties and Determination of Molar Mass
- 28g of acetic acid (M = 60 g ) dissolved in 30 g of benzene shows a depression in freezing point equal to . Calculate the percentage association of acid if it forms a dimer in the solution. (Given : for benzene = K kg )Abnormal Molar Masses
- 29When 19.5 g of (Molar mass = 78 g ), is dissolved in 500 g of water, the depression in freezing point is observed to be 1°C. Calculate the degree of dissociation of . [Given : for water = 1.86 K kg ]Abnormal Molar Masses
- 29If benzoic acid (M = 122 g ) is associated into a dimer when dissolved in benzene and the osmotic pressure of a solution of g of benzoic acid in 100 mL benzene is atm at , then what is the percentage association of benzoic acid ? (Given : R = L atm )Abnormal Molar Masses
- 33 (a)(i) Why is boiling point of 1M NaCl solution more than that of 1M glucose solution ? (ii) A non-volatile solute 'X' (molar mass = 50 g ) when dissolved in 78g of benzene reduced its vapour pressure to 90%. Calculate the mass of X dissolved in the solution. (iii) Calculate the boiling point elevation for a solution prepared by adding 10g of to 200g of water assuming is completely dissociated. ( for Water = 0.512 K kg , Molar mass = 95g )Colligative Properties and Determination of Molar Mass
- 33 (b)(i) Why is the value of Van't Hoff factor for ethanoic acid in benzene close to 0.5 ? (ii) Determine the osmotic pressure of a solution prepared by dissolving g of in 2L of solution at 25 °C, assuming that is completely dissociated. (R = 0.082 L atm , Molar mass = 174g ) (iii) When 25.6g of Sulphur was dissolved in 1000g of benzene, the freezing point lowered by 0.512 K. Calculate the formula of Sulphur . ( for benzene = 5.12 K kg , Atomic mass of Sulphur = 32g )Abnormal Molar Masses
The 10 board questions to practise first
The questions the board asked again come first, most asked first. Each one says how often and when.
Question 1
Asked 3 times: 2023, 2024, 2026
8The boiling point of an azeotropic mixture of water and ethanol is less than that of pure water and ethanol. The mixture shows :Tap an option to check your answer.
Question 2
Asked 3 times: 2023, 2024, 2026
10The boiling point of an azeotropic mixture of water and nitric acid is more than that of pure water and nitric acid. The mixture shows :Tap an option to check your answer.
Question 3
Asked 3 times: 2023, 2024, 2026
17What type of deviation from Raoult’s law is shown by mixture of ethanol and acetone ? Give reason. What will happen to the boiling point of the solution on mixing ethanol and acetone ?Question 4
Asked 2 times: 2023*, 2026 (* = numbers or wording changed that year)
121 mole of liquid A and 2 moles of liquid B make a solution having a total vapour pressure 40 torr. The vapour pressure of pure A and pure B are 30 torr and 45 torr respectively. The above solution :Tap an option to check your answer.
Question 5
Asked 2 times: 2023*, 2026 (* = numbers or wording changed that year)
2Which of the following solutions will have the lowest freezing point in water ?Tap an option to check your answer.
Question 6
Asked 2 times: 2023, 2025
22g of acetic acid (Molar mass = 60 g ) dissolved in 30 g of benzene shows a depression in freezing point equal to °C. Calculate the percentage association of acid if it forms a dimer in the solution. (Given : for benzene = K kg )Question 7
Asked 2 times: 2023, 2025
17 (b)Liquids 'X' and 'Y' form an ideal solution. The vapour pressure of pure 'X' and pure 'Y' are 120 mm Hg and 160 mm Hg respectively. Calculate the vapour pressure of the solution containing equal moles of 'X' and 'Y'.Question 8
Asked 2 times: 2024*, 2025 (* = numbers or wording changed that year)
8On mixing 30 mL of acetone with 20 mL of chloroform, the total volume of solution is :Tap an option to check your answer.
Question 9
Asked 2 times: 2023, 2025
17 (B)Define Azeotrope. What type of Azeotrope is formed by negative deviation from Raoult's law ? Give an example.Question 10
Asked 2 times: 2023*, 2024 (* = numbers or wording changed that year)
12Van’t Hoff factor for solution, assuming complete ionization isTap an option to check your answer.