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Statements about hyperconjugation and carbocation stability

This type of question, asked 3 times: 2021 Paper 17, 3 Apr 2025, 23 Jan 2026 S2. All 3 questions below, oldest first.

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  1. Question 1

    2021 Paper 17

    37
    Given below are two statements: Statement I: Hyperconjugation is a permanent effect. Statement II: Hyperconjugation in ethyl cation (CH3−C+H2)\left( CH_{3}-\overset{+}{C}H_{2} \right) involves the overlapping of Csp 2−H1 sC_{sp}\ ^{2}-H_{1\text{ }s} bond with empty 2p2p orbital of other carbon. Choose the correct option:

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  2. Question 2

    3 Apr 2025

    115
    Given below are two statements : Statement I : Hyperconjugation is not a permanent effect. Statement II : In general, greater the number of alkyl groups attached to a positively charged C -atom, greater is the hyperconjugation interaction and stabilization of the cation. In the light of the above statements, choose the correct answer from the options given below

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  3. Question 3

    23 Jan 2026 S2

    32
    Given below are two statements: Statement I: (CH3)3C⊕\left( {CH}_{3} \right)_{3}\overset{\oplus}{C} is more stable than C⊕H3\overset{\oplus}{C}H_{3} as nine hyperconjugation interactions are possible in (CH3)3C⊕\left( {CH}_{3} \right)_{3}\overset{\oplus}{C}. Statement II: C⊕H3\overset{\oplus}{C}H_{3} is less stable than (CH3)3C⊕\left( {CH}_{3} \right)_{3}\overset{\oplus}{C} as only three hyperconjugation interactions are possible in C⊕H3\overset{\oplus}{C}H_{3}. In the light of the above statements, choose the correct answer from the options given below.

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