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Match given reactions with their names (Sandmeyer, Gattermann, Wurtz, Fittig and others)

This type of question, asked 2 times: 2021 Paper 26, 2 Apr 2025. All 2 questions below, oldest first.

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  1. Question 1

    2021 Paper 26

    34
    Match List-I with List-II.
    List-IList-II
    (A)C6H5N2+Cl−→Cu2Cl2C6H5Cl+N2C_{6}H_{5}N_{2}^{+}Cl^{-} \xrightarrow{Cu_{2}Cl_{2}} C_{6}H_{5}Cl + N_{2}(i)Wurtz reaction
    (B)C6H5N2+Cl−→Cu, HClC6H5Cl+N2C_{6}H_{5}N_{2}^{+}Cl^{-} \xrightarrow{Cu,\ HCl} C_{6}H_{5}Cl + N_{2}(ii)Sandmeyer reaction
    (C)2CH3CH2Cl+2Na→etherC2H5−C2H5+2NaCl2CH_{3}CH_{2}Cl + 2Na \xrightarrow{\text{ether}} C_{2}H_{5}-C_{2}H_{5} + 2NaCl(iii)Fittig reaction
    (D)2C6H5Cl+2Na→etherC6H5−C6H5+2NaCl2C_{6}H_{5}Cl + 2Na \xrightarrow{\text{ether}} C_{6}H_{5}-C_{6}H_{5} + 2NaCl(iv)Gattermann reaction
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  2. Question 2

    2 Apr 2025

    116
    Match List-I With List-II.
    List-I (Reaction)List-II (Name of reaction)
    (A)2C6H5X+2Na→dry etherC6H5−C6H5+2NaX2C_{6}H_{5}X + 2Na \xrightarrow{\text{dry ether}} C_{6}H_{5}-C_{6}H_{5} + 2NaX(I)Lucas reaction
    (B)ArN2+X−→Cu, HClArCl+N2↑+CuXArN_{2}^{+}X^{-} \xrightarrow{Cu,\ HCl} ArCl + N_{2} \uparrow + CuX(II)Finkelstein reaction
    (C)C2H5Br+NaI→dry acetoneC2H5I+NaBrC_{2}H_{5}Br + NaI \xrightarrow{\text{dry acetone}} C_{2}H_{5}I + NaBr(III)Fittig reaction
    (D)CH3C(OH)(CH3)CH3→HCl, ZnCl2CH3C(Cl)(CH3)CH3CH_{3}C(OH)(CH_{3})CH_{3} \xrightarrow{HCl,\ ZnCl_{2}} CH_{3}C(Cl)(CH_{3})CH_{3}(IV)Gattermann reaction
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