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Order solutions by freezing or boiling point using the van't Hoff factor

This type of question, asked 5 times: 2021 Paper 13, 2021 Paper 22, 30 Jan 2024, 22 Jan 2025, 28 Jan 2026 S2. All 5 questions below, oldest first.

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  1. Question 1

    2021 Paper 13

    31
    Which of the following 0.06M0.06M solution has the lowest freezing point?

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  2. Question 2

    2021 Paper 22

    48
    Which one of the following 0.10M0.10M aqueous solutions will exhibit the largest freezing point depression?

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  3. Question 3

    30 Jan 2024

    137
    The solution from the following with highest depression in freezing point/lowest freezing point is

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  4. Question 4

    22 Jan 2025

    42
    Arrange the following solutions in order of their increasing boiling points. (i) 10−4MNaCl10^{- 4}MNaCl (ii) 10−4M10^{- 4}M Urea (iii) 10−3M NaCl10^{- 3}M\ NaCl (iv) 10−2MNaCl10^{- 2}MNaCl

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  5. Question 5

    28 Jan 2026 S2

    39
    Consider the following aqueous solutions. (I) 2.2 g Glucose in 125 mL of solution. (II) 1.9 g Calcium chloride in 250 mL of solution. (III) 9.0 g Urea in 500 mL of solution. (IV) 20.5 g Aluminum sulphate in 750 mL of solution. The correct increasing order of boiling point of these solutions will be: [Given: Molar mass in gmol−1:H=1,C=12, N=14gmol^{- 1}:H = 1,C = 12,\text{ }N = 14, O=16,Cl=35.5,Ca=40,Al=27O = 16,Cl = 35.5,Ca = 40,Al = 27 and S=32S = 32 ]

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