Clemmensen and Wolff-Kishner reductions of C=O to CH2
This type of question, asked 12 times: May 2021 S1, 2 May 2023 S2, 9 May 2023 S2, 16 May 2023 S2, 9 May 2024 S1, 13 May 2024 S2, 14 May 2024 S1, 14 May 2024 S2, 25 Apr 2025 S1, 20 Apr 2026 S2, 12 May 2026 S1, 19 May 2026 S1. All 13 questions below, oldest first.
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Question 1
May 2021 S1
89
Identify the reaction in which the carbonyl group of aldehydes and ketones is reduced to a methylene group on treatment with zinc-amalgam and conc. HCl.
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Question 2
2 May 2023 S2
85
Identify the product B in the following reaction. Ethyl phenyl ketone H2N-NH2 A KOH,HO(CH2)2OHΔ B
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Question 3
9 May 2023 S2
64
What type of following compounds is obtained in first step of Wolf-Kishner reduction of carbonyl compounds?
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Question 4
16 May 2023 S2
78
Identify name of reaction when aldehyde or ketone react with Zn-Hg/conc. HCl to give alkane.
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Question 5
9 May 2024 S1
88
Identify the product 'B' in following reaction. Ethyl phenyl ketone H2N−NH2 A KOH,(HO−CH2)2,Δ B
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Question 6
13 May 2024 S2
78
Which of the following is Wolf-Kishner reduction?
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Question 7
14 May 2024 S1
91
Identify the reaction in which carbonyl group of aldehydes and ketones is reduced to methylene group on treatment with hydrazine followed by heating with sodium hydroxide in ethylene glycol.
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Question 8
14 May 2024 S2
60
Which of the following is Clemmensen reduction?
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Question 9
25 Apr 2025 S1
78
Identify the name of reaction if carbonyl group of aldehydes and ketones is reduced to methylene group on treatment with hydrazine followed by heating with sodium hydroxide in ethylene glycol.
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Question 10
20 Apr 2026 S2
42
Which of the following reactions is preferentially used to prepare the corresponding paraffins from alkanone?
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Question 11
12 May 2026 S1
40
C=O+4[H]Zn−Hg,conc.HClΔ−CH2+H2O
(Carbonyl group in aldehydes and ketones) (Methylene group)
Identify the name of above reaction.
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Question 12
19 May 2026 S1
18
Which reaction is used to synthesize straight-chain alkylbenzenes?
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Question 13
19 May 2026 S1
16
Which of the following compounds is obtained in the first step of Wolf - Kishner reduction when alkyl aryl ketones are reduced to alkyl benzene?