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Rate constant of a first order reaction when the reactant falls to a quarter in a given time

The same question, asked 2 times: May 2021 S1*, 16 Apr 2026 S2. Every wording below, oldest first.

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  1. Question 1

    May 2021 S1

    65
    What is the rate constant of a first order reaction, if 0.08 mole of reactant reduces to 0.02 mole in 23.03 minutes?

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  2. Question 2

    16 Apr 2026 S2

    29
    If for a first-order reaction, [A]0=1.0[A]_0 = 1.0 M and [A]t=0.25[A]_t = 0.25 M after 276 s, find the value of the rate constant (k).

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