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Rate law expression from the given order in each reactant

The same question, asked 3 times: 9 May 2023 S1*, 12 May 2024 S1*, 14 May 2024 S1. Every wording below, oldest first.

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  1. Question 1

    9 May 2023 S1

    81
    For the reaction, NO2(g)+CO(g)→NO(g)+CO2(g)\text{NO}_2(\text{g}) + \text{CO}(\text{g}) \rightarrow \text{NO}(\text{g}) + \text{CO}_2(\text{g}) rate of reaction is proportional to square of NO2\text{NO}_2 and independent of [CO]. What is the rate law equation?

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  2. Question 2

    12 May 2024 S1

    75
    Identify rate law expression for 2NO(g)+Cl2(g)→2NOCl(g)2\text{NO}_{(g)}+\text{Cl}_{2(g)}\rightarrow2\text{NOCl}_{(g)} if the reaction is second order in NO and first order in Cl2\text{Cl}_{2}.

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  3. Question 3

    14 May 2024 S1

    85
    Find the rate law for the reaction CHCl3(g)+Cl2(g)→CCl4(g)+HCl(g)\text{CHCl}_3(\text{g})+\text{Cl}_2(\text{g})\rightarrow\text{CCl}_4(\text{g})+\text{HCl}(\text{g}) if order of reaction with respect to CHCl3\text{CHCl}_3 is one and 12\dfrac{1}{2} with Cl2\text{Cl}_2.

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