Kind of structural isomerism (ionisation, solvate, linkage, coordination) shown by given complexes

1. A.
   Coordinate
2. B.
   Solvate
3. C.
   Ionization
4. D.
   Linkage

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1. A.
   $\left\lbrack Cr\left( H_{2}O \right)_{6} \right\rbrack{Cl}_{3}$ and $\left\lbrack Cr\left( H_{2}O \right)_{5}Cl \right\rbrack{Cl}_{2} \cdot H_{2}O$
2. B.
   $\left\lbrack Co\left( {NH}_{3} \right)_{5}{SO}_{4} \right\rbrack Br$ and $\left\lbrack Co\left( {NH}_{3} \right)_{5}Br \right\rbrack{SO}_{4}$
3. C.
   $\left\lbrack Co\left( {NH}_{3} \right)_{6} \right\rbrack\left\lbrack Cr(CN)_{6} \right\rbrack$ and $\left\lbrack Cr\left( {NH}_{3} \right)_{6} \right\rbrack\left\lbrack Co(CN)_{6} \right\rbrack$
4. D.
   $\left\lbrack Fe\left( H_{2}O \right)_{5}SCN \right\rbrack^{+}$and $\left\lbrack Fe\left( H_{2}O \right)_{5}NCS \right\rbrack^{+}$

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1. A.
   $[\mathrm{Cr(H_2O)_4(O_2N)}]\mathrm{Cl_2}$
2. B.
   $[\mathrm{Cr(H_2O)_4Cl_2}](\mathrm{NO_2})$
3. C.
   $[\mathrm{Cr(H_2O)_4Cl(ONO)}]\mathrm{Cl}$
4. D.
   $[\mathrm{Cr(H_2O)_4Cl_2(NO_2)}]\mathrm{H_2O}$

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1. A.
   Geometrical isomerism
2. B.
   linkage isomerism
3. C.
   Optical isomerism
4. D.
   Coordination isomerism

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1. A.
   $\mathrm{[Co(NH_3)_5(NO_2)]^{2\oplus}}$ and $\mathrm{[Co(NH_3)_5(ONO)]^{2\oplus}}$
2. B.
   $\mathrm{[Co(NH_3)_5SO_4]Br}$ and $\mathrm{[Co(NH_3)_5Br]SO_4}$
3. C.
   $\mathrm{[Co(NH_3)_6][Cr(CN)_6]}$ and $\mathrm{[Cr(NH_3)_6][Co(CN)_6]}$
4. D.
   $\mathrm{[Cr(H_2O)_6]Cl_3}$ and $\mathrm{[Cr(H_2O)_5Cl]Cl_2 \cdot H_2O}$

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1. A.
   Solvate isomerism.
2. B.
   Co-ordinate Isomerism.
3. C.
   Ionisation Isomerism.
4. D.
   Linkage Isomerism.

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1. A.
   $\mathrm{[Co(en)_3]Cl_3}$
2. B.
   $\mathrm{[Co(en)_2Cl_2]Cl}$
3. C.
   $\mathrm{[Co(en)_2NO_2Cl]Br}$
4. D.
   $\mathrm{[Co(NH_3)_5Cl]Br_2}$

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