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Colour of cobalt(II) complexes: pink [Co(H2O)6]2+ and blue [CoCl4]2-

This type of question, asked 2 times: 14 May 2026 S1, 15 May 2026 S1. All 2 questions below, oldest first.

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  1. Question 1

    14 May 2026 S1

    35
    Complex [Co(H2O)6]2+[\mathrm{Co(H_2O)_6}]^{2+} when dissolved in water forms a pink solution. But when this solution is treated with concentrated hydrochloric acid, it turns deep blue to form another complex [CoCl4]2−[\mathrm{CoCl_4}]^{2-}. Identify the main reason for this colour change.

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  2. Question 2

    15 May 2026 S1

    35
    Cobalt chloride, when dissolved in water, forms a pink-colored solution. Identify the reason.

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