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Spontaneity of a cell reaction, or the best electrode pair, from standard reduction potentials

This type of question, asked 4 times: 25 Apr 2025 S2, 13 Apr 2026 S1, 17 Apr 2026 S2, 18 Apr 2026 S2. All 5 questions below, oldest first.

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  1. Question 1

    25 Apr 2025 S2

    63
    If standard reduction potential ( E∘E^{\circ} ) of (Mg(aq)+2∣Mg(s)),(Ag(aq)+∣Ag(s)),(Zn(aq)+2∣Zn(s))\left( Mg_{(aq)}^{+ 2}\mid Mg_{(s)} \right),\left( Ag_{(aq)}^{+}\mid Ag_{(s)} \right),\left( Zn_{(aq)}^{+ 2}\mid Zn_{(s)} \right) and (Cu(aq )+2∣Cu(s))\left( Cu_{(\text{aq~})}^{+ 2}\mid Cu_{(s)} \right) are −2.37 V,+0.79 V,−0.76 V- 2.37\text{ }V, + 0.79\text{ }V, - 0.76\text{ }V and +0.34 V respectively. Which of the following reaction is spontaneous?

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  2. Question 2

    13 Apr 2026 S1

    24
    Identify from following cell reactions that is spontaneous under standard state of conditions.

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  3. Question 3

    17 Apr 2026 S2

    27
    If standard reduction potential (E0)(E^0) of (Al(aq)+3∣Al(s))\left(\mathrm{Al^{+3}_{(aq)}|Al_{(s)}}\right), (Fe(aq)+2∣Fe(s))\left(\mathrm{Fe^{+2}_{(aq)}|Fe_{(s)}}\right), (Cu(aq)+2∣Cu(s))\left(\mathrm{Cu^{+2}_{(aq)}|Cu_{(s)}}\right) and (Ag(aq)+1∣Ag(s))\left(\mathrm{Ag^{+1}_{(aq)}|Ag_{(s)}}\right) are −1.66-1.66 V, −0.44-0.44 V, +0.34+0.34 V and +0.79+0.79 V respectively. Which of the following reaction is non spontaneous ?

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  4. Question 4

    18 Apr 2026 S2

    25
    If standard reduction potential of Zn, Ni and Fe are −0.76 V-0.76\ \mathrm{V}, −0.23 V-0.23\ \mathrm{V} and −0.44 V-0.44\ \mathrm{V} respectively. For the reaction (Stated below) to be spontaneous find out electrodes X and Y considering above electrode potentials X(s)+Y(aq)+2⟶X(aq)+2+Y(s)\mathrm{X_{(s)} + Y^{+2}_{(aq)} \longrightarrow X^{+2}_{(aq)} + Y_{(s)}}

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  5. Question 5

    18 Apr 2026 S2

    26
    If standard reduction potential of four electrodes A, B, C, D are +2.5 V+2.5\ \mathrm{V}, +3.0 V+3.0\ \mathrm{V}, −2.0 V-2.0\ \mathrm{V} and −1.5 V-1.5\ \mathrm{V} respectively. When is the standard emf of cell maximum?

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