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NDA Chemistry · Chemical Reactions

Physical vs Chemical Changes

A physical change alters only the form or state of a substance with no new substance formed; a chemical change rearranges atoms into a genuinely new substance — that is what a chemical reaction is.

Why this matters

The foundation of the whole chapter — a chemical reaction IS a chemical change, so everything later builds on this one distinction. The bank asks it directly as 'which of the following is a chemical change?', testing whether you can tell burning, rusting and neutralisation apart from melting, dissolving and evaporating.

Concept 1 of 1: Telling a physical change from a chemical change

Ask one question: is a NEW substance formed? Melting ice, dissolving sugar and boiling water just change the form — the substance is still water or sugar, so they are physical. Burning, rusting and reacting an acid with a base make something new, so they are chemical.

Definition

The test and the markers:

  • Physical change — no new substance; usually reversible; only state, shape or size changes. Examples: melting ice, boiling water, dissolving sugar, breaking glass, magnetising iron.
  • Chemical change — a new substance forms; usually irreversible; often shows heat/light, colour change, gas evolution or a precipitate. Examples: burning, rusting, cooking, neutralisation, digestion, photosynthesis.
  • Neutralisation (acid + base, e.g. NaOH + HCl → NaCl + H₂O) is a chemical change — a new salt forms.
  • Burning magnesium (2Mg + O₂ → 2MgO) is a chemical change — the bright white light and the new white solid MgO are the giveaways.
ProcessChange typeWhy
Melting of icePhysicalStill water, only state changes — reversible
Boiling / evaporation of waterPhysicalWater vapour is still water
Dissolving sugar in waterPhysicalSugar can be recovered by evaporation
Mixing NaOH and HClChemicalNeutralisation — new salt (NaCl) + water form
Mixing an acid and a base is a chemical change, not just mixing — a new substance (the salt) is made.
Burning of magnesium ribbonChemicalNew substance MgO forms with light and heat
Burning is always a chemical change — a new oxide forms.
Rusting of ironChemicalNew substance (hydrated iron oxide) forms
Practice this concept4 quick reps

The same idea in a real exam question:

NDA · Sep 2024 · Q120Easy

Example 1 · Chemical Reactions · Physical vs Chemical Changes

Which one among the following is an example of chemical change ?

Dissolving and boiling are physical, not chemical

Dissolving sugar, boiling water and melting ice make NO new substance — they are physical changes even though the substance looks different. The marker for a chemical change is a NEW substance, not just a new appearance.

Mixing an acid and a base is a chemical change

Mixing NaOH and HCl is not 'just mixing' — they react (neutralisation) to form a new salt and water, so it is a chemical change.

Burning is always chemical

Any burning or combustion (magnesium ribbon, fuel, a candle wick) is a chemical change — a new oxide or combustion product forms, releasing heat and often light.

Summary — formulas & gotchas at a glance

A revision cheat-sheet for the formulas and gotchas above. Click any concept name to jump back to its full explanation.

Reference tables (1)

Telling a physical change from a chemical change6 rows
ProcessChange typeWhy
Melting of icePhysicalStill water, only state changes — reversible
Boiling / evaporation of waterPhysicalWater vapour is still water
Dissolving sugar in waterPhysicalSugar can be recovered by evaporation
Mixing NaOH and HClChemicalNeutralisation — new salt (NaCl) + water form
Mixing an acid and a base is a chemical change, not just mixing — a new substance (the salt) is made.
Burning of magnesium ribbonChemicalNew substance MgO forms with light and heat
Burning is always a chemical change — a new oxide forms.
Rusting of ironChemicalNew substance (hydrated iron oxide) forms

Watch out for (3)

Test yourself on Chemical Reactions

15 past NDA questions from this chapter, timed at 15 minutes and marked the way the exam marks it. You see your score and every answer the moment you finish. Free to start.