NDA Chemistry · Teaching notes

Industrial and Applied Chemistry — NDA Chemistry

Industrial Chemistry is pure named-fact recall — 28 PYQs across 2017–2026, almost every one a 'which is correct / which is NOT' about a manufactured gas, a fertilizer, a building material, a paint additive, or an alloy. There is no derivation to do; the marks go to whoever has memorised the table. The chapter teaches in five movements, grouped by industry: (1) Industrial gases, manufacturing and reactions — water gas, syngas, the Haber process, acid-rain gases and airbag chemistry; (2) Fertilizers — the nutrient each fertilizer supplies (N, P or K), how superphosphate and nitrolim are made, and the urea traps; (3) Cement, glass and building materials — what glass and Portland cement are made from, and the property statements the bank loves to falsify; (4) Paints and coatings — the role of each additive (pigment, binder, drier, thinner, anti-skinning, antifoaming), the chapter's hardest pocket; (5) Common industrial substances and alloys — plaster of Paris, borax, soft soap, and the composition of solder. Most concepts are reference tables: learn the table, win the marks.

Subtopic notes

PYQ weightage by concept

12 concepts · 28 PYQs — where the marks actually sit, so you know what to drill first

Industrial Gases, Manufacturing and Reactions8 PYQs · 29%
ConceptPYQsShare
Applied gas facts — acid rain, airbags, atmosphere414%
Water gas, syngas and producer gas311%
Named manufacturing processes14%
Fertilizers5 PYQs · 18%
ConceptPYQsShare
Which nutrient each fertilizer supplies311%
How superphosphate and nitrolim are made27%
Cement, Glass and Building Materials6 PYQs · 21%
ConceptPYQsShare
Glass — nature and raw materials414%
Portland cement — raw materials and compounds27%
Paints and Coatings4 PYQs · 14%
ConceptPYQsShare
Paint ingredients and their roles311%
Emulsion paint additives — true/false facts14%
Common Industrial Substances and Alloys5 PYQs · 18%
ConceptPYQsShare
Plaster of Paris, borax and soft soap311%
Common alloys and their composition14%
Raw materials of Portland cement14%

Formula & revision sheet

0 formulas · 12 reference tables · 19 gotchas across all subtopics — the exam-eve cheat-sheet

Industrial Gases, Manufacturing and Reactions

Reference tables (3)

Water gas, syngas and producer gas4 rows
Gas mixtureCompositionHow it is made
Water gas (syngas)CO + H₂Steam over red-hot coke
Water gas and syngas are the SAME mixture: carbon monoxide + hydrogen. Do not pick CO + H₂O.
Producer gasCO + N₂Limited air over red-hot coke
Coal gasH₂ + CH₄ + CODestructive distillation of coal
Natural gasMainly CH₄ (methane)Underground deposits
Named manufacturing processes4 rows
ProductProcessKey reaction / catalyst
Ammonia (NH₃)Haber–BoschN₂ + 3H₂ → 2NH₃, iron catalyst
Ammonia is manufactured by the Haber (Haber–Bosch) process.
Sulphuric acid (H₂SO₄)Contact2SO₂ + O₂ → 2SO₃, V₂O₅ catalyst
Nitric acid (HNO₃)OstwaldCatalytic oxidation of ammonia
Washing soda (Na₂CO₃)SolvayAmmonia-soda process
Applied gas facts — acid rain, airbags, atmosphere4 rows
PhenomenonChemistry / factAnswer the bank wants
Acid rainSO₂ and NOₓ dissolve in rainSulphur dioxide (SO₂)
The single biggest cause of acid rain in NDA options is sulphur dioxide.
Airbag inflation2NaN₃ → 2Na + 3N₂Sodium azide → nitrogen gas
Airbags work by sodium azide decomposing into nitrogen gas.
2nd most abundant atmospheric gasN₂ ≈ 78%, O₂ ≈ 21%Oxygen
Nitrogen is first (most abundant); OXYGEN is second.
Paper physical testingMechanical, surface, optical, permeabilityAll four properties tested

Watch out for (5)

Fertilizers

Reference tables (2)

Which nutrient each fertilizer supplies6 rows
FertilizerNutrient suppliedNote
UreaNitrogen (N)≈ 46% N — highest-N solid fertilizer
Urea is a NITROGEN fertilizer, not a phosphorus one.
Ammonium nitrateNitrogen (N)Common N fertilizer
Ammonium sulphateNitrogen (N)Common N fertilizer
Superphosphate of limePhosphorus (P)Made from rock phosphate + H₂SO₄
Muriate of potash (KCl)Potassium (K)Main K source
Ammonium sulphide ((NH₄)₂S)None — not a fertilizerA lab reagent
Ammonium SULPHIDE is the odd one out — it is NOT used as a fertilizer (sulphate, nitrate and phosphate of ammonium all are).
How superphosphate and nitrolim are made2 rows
FertilizerMade fromKey fact
Superphosphate of limeCalcium phosphate + sulphuric acidMakes phosphate soluble
Superphosphate = rock phosphate (calcium phosphate) treated with H₂SO₄.
Nitrolim (calcium cyanamide)Calcium carbide (CaC₂) + nitrogenDecomposes to ammonia in soil
Nitrolim supplies nitrogen only, is inorganic, and is NOT an NPK fertilizer.

Watch out for (3)

Cement, Glass and Building Materials

Reference tables (2)

Glass — nature and raw materials5 rows
AspectGlass factNote
Physical natureAmorphous, non-crystalline solidSupercooled liquid; no definite melting point
Glass is a non-crystalline amorphous solid — a supercooled liquid.
Source of silicaSand (SiO₂)The silica-providing raw material
Sand is the source of silica in glass-making.
Other raw materialsSoda ash, limestone, boraxBorax → borosilicate (pyrex)
NOT a glass materialGypsum (CaSO₄·2H₂O)Belongs to cement/plaster, not glass
Gypsum is the trap option — it is NOT used in making glass.
Pyrex vs soda glassPyrex is harderPyrex has boron oxide; heat-resistant
'Soda glass is harder than pyrex' is FALSE — pyrex (borosilicate) is the harder, more heat-resistant one.
Portland cement — raw materials and compounds6 rows
AspectCement factNote
Raw materialsLime, silica, alumina+ a little iron oxide
Essential constituents of Portland cement: silica, alumina, lime.
Alite3CaO·SiO₂Tricalcium silicate
Belite2CaO·SiO₂Dicalcium silicate
Aluminate3CaO·Al₂O₃Tricalcium aluminate
NOT in cement4CaO·SiO₂No such silicate; only 3:1 and 2:1
4CaO·SiO₂ is the trap — it is NOT a standard cement compound.
Setting regulatorGypsum (small amount)Slows the setting time

Watch out for (3)

Paints and Coatings

Reference tables (2)

Paint ingredients and their roles6 rows
Role in paintWhat it doesCorrect example
PigmentColour + opacityTitanium dioxide (TiO₂)
TiO₂ is the standard white pigment; phthalocyanine is a blue/green pigment.
Binder (film-former)Holds pigment, forms the filmSilicones (also resins / drying oils)
Silicones are the binder; TiO₂, novolac and phthalocyanine in that question are pigment/resin distractors.
Thinner (solvent)Thins the paintTurpentine
DrierAccelerates drying (oxidation)Metal naphthenates
Naphthenates are DRIERS, not thinners. Turpentine is the thinner.
Anti-skinning agentPrevents skin in storagePolyhydroxy phenol
Anti-skinning agent = polyhydroxy phenol — not gelatin, pyridine or NMP.
Antifoaming agentStops foam in emulsion paintPine oil
Emulsion paint additives — true/false facts3 rows
Statement about emulsion paintTrue or falseWhy
Pine oil is used as antifoaming agentTruePine oil controls foam
Protective colloids decrease stabilityFalseThey INCREASE stability
Protective colloids stabilise the emulsion — they increase, not decrease, stability.
Oxidizable-oil driers accelerate dryingTrueOxidation speeds film formation

Watch out for (4)

Common Industrial Substances and Alloys

Reference tables (3)

Common alloys and their composition5 rows
AlloyCompositionUse
SolderLead (Pb) + tin (Sn)Joining/soldering metals
Solder is an alloy of lead and tin (Pb + Sn).
BrassCopper + zinc (Cu + Zn)Fittings, instruments
BronzeCopper + tin (Cu + Sn)Statues, coins, bearings
SteelIron + carbon (Fe + C)Construction, tools
DuraluminAl + Cu + Mg + MnAircraft (light, strong)
Plaster of Paris, borax and soft soap3 rows
SubstanceFormula / compositionKey fact
Plaster of ParisCaSO₄·½H₂OCalcium sulphate hemihydrate; from gypsum
Plaster of Paris = CaSO₄·½H₂O (½ water per CaSO₄), not CaSO₄·2H₂O (that is gypsum).
BoraxNa, B, O, H (Na₂B₄O₇·10H₂O)Sodium tetraborate decahydrate
Borax contains sodium, boron, oxygen and hydrogen.
Soft soapPotassium soapContains potassium (K)
Soft soap = potassium salt; HARD soap = sodium salt.
Raw materials of Portland cement4 rows
Raw materialProvidesSource
LimestoneLime (CaO)Calcium carbonate rock
Clay / sandSilica (SiO₂)Clay, sand
ClayAlumina (Al₂O₃)Aluminosilicate clay
Iron ore + gypsumIron oxide; setting controlAdded in small amounts
Lime, silica and alumina are the essential trio — gypsum is only a setting regulator.

Watch out for (4)