PYQ Vault

NDA Chemistry · Matter and Its States

Physical vs Chemical Changes

A physical change alters only the form or state of a substance and is usually reversible; a chemical change makes a brand-new substance with new properties and is usually irreversible.

Why this matters

Four PYQs, all EASY, all the same two shapes: 'which one is a chemical change?' and 'which statement is NOT correct?'. The entire subtopic rests on one test — is a new substance formed? — plus knowing which everyday examples sit on each side. Souring of milk, rusting and burning are chemical; melting, boiling and dissolving are physical.

Concept 1 of 2: The test: is a new substance formed?

Only one question separates the two kinds of change: after the change, do you still have the same substance (just in a new form), or a completely new substance? Same substance = physical. New substance = chemical.

Definition

The distinguishing features:

  • Physical change — only the physical form or state changes; no new substance is formed; the chemical composition of the molecules stays the same; usually reversible. Examples: melting, boiling, freezing, dissolving, cutting, magnetising.
  • Chemical change — a new substance with new properties is formed; the chemical composition changes; usually irreversible and often releases or absorbs energy. Examples: rusting, burning, cooking, souring of milk.
  • Some events involve both: a burning candle melts wax (physical) and burns the vapour (chemical) at the same time.
  • The interconversion of states of matter (ice ⇌ water ⇌ steam) is a physical change — same H₂O molecules throughout.
FeaturePhysical changeChemical change
New substance?NoYes
Molecular compositionUnchangedChanged
Reversible?Usually yesUsually no
ExamplesMelting, boiling, dissolvingRusting, burning, souring
Burning a candle is BOTH: wax melting is physical, vapour burning is chemical.
The whole distinction is one question: is a new substance formed?
Practice this conceptself-check · 4 quick reps

The same idea in a real exam question:

NDA · Sep 2025 · Q101Easy

Example 1 · Matter and Its States · Physical vs Chemical Changes

Which one of the following statements is NOT correct ?

Physical change keeps the composition

A common false statement is 'during a physical change, the chemical composition of molecules changes' — that is NOT correct. In a physical change the molecules are unchanged; only the form/state differs.

Concept 2 of 2: Examples: which side is each change on?

The bank simply lists four everyday events and asks which one is the chemical (or the only non-chemical) change. The trick events are the ones that look physical but make a new substance — souring of milk and the natural greying of hair.

Definition

Sort the common bank examples:

  • Chemical changes (new substance formed): rusting of iron, burning of coal/candle, souring of milk (lactose → lactic acid by bacteria), natural greying of hair (loss of pigment by a chemical process), cooking food, reaction of acid with base, digestion.
  • Physical changes (no new substance): melting of ice, boiling of water, dissolving salt/sugar in water, cutting paper, magnetising iron, glowing of a bulb filament.
EventChange typeWhy
Rusting of ironChemicalIron → iron oxide (new substance)
Burning of coalChemicalCarbon → CO₂ + ash
Souring of milkChemicalBacteria turn lactose into lactic acid
Souring of milk LOOKS physical but is chemical — a new acid is formed.
Greying of hair (natural)ChemicalPigment chemically lost — irreversible
Natural greying of hair is a chemical change, not a physical one.
Melting of icePhysicalStill H₂O, just a state change
Reaction of acid with baseChemicalForms salt + water
Practice this concept4 quick reps

The same idea in a real exam question:

NDA · Sep 2025 · Q100Easy

Example 2 · Matter and Its States · Physical vs Chemical Changes

Which one of the following is NOT a chemical change ?

Souring and greying are chemical

Souring of milk and natural greying of hair both look harmless and physical, but each forms a new substance — they are chemical changes. Melting, boiling and dissolving are the physical ones.

Summary — formulas & gotchas at a glance

A revision cheat-sheet for the formulas and gotchas above. Click any concept name to jump back to its full explanation.

Reference tables (2)

The test: is a new substance formed?4 rows
FeaturePhysical changeChemical change
New substance?NoYes
Molecular compositionUnchangedChanged
Reversible?Usually yesUsually no
ExamplesMelting, boiling, dissolvingRusting, burning, souring
Burning a candle is BOTH: wax melting is physical, vapour burning is chemical.
The whole distinction is one question: is a new substance formed?
Examples: which side is each change on?6 rows
EventChange typeWhy
Rusting of ironChemicalIron → iron oxide (new substance)
Burning of coalChemicalCarbon → CO₂ + ash
Souring of milkChemicalBacteria turn lactose into lactic acid
Souring of milk LOOKS physical but is chemical — a new acid is formed.
Greying of hair (natural)ChemicalPigment chemically lost — irreversible
Natural greying of hair is a chemical change, not a physical one.
Melting of icePhysicalStill H₂O, just a state change
Reaction of acid with baseChemicalForms salt + water

Watch out for (2)

Test yourself on Matter and Its States

15 past NDA questions from this chapter, timed at 15 minutes and marked the way the exam marks it. You see your score and every answer the moment you finish. Free to start.