NDA Chemistry · Teaching notes

Metals and Non-Metals — NDA Chemistry

Metals and Non-Metals is a compact recall chapter — about 17 PYQs across 2017–2026, almost every one a 'which is correct' or 'which is NOT' about reactivity, an ore, corrosion, or an alloy. There is no derivation to do; the marks go to whoever has the reactivity series and the ore/alloy tables memorised. The chapter teaches in four movements, building from general properties up to applications: (1) Reactivity series and reactions with water — the order of metals from most to least reactive, which metals float, which react with cold water versus steam, and the alkali-metal melting-point trend; (2) Extraction of metals and ores — the common ores and the reduction method each metal needs (carbon reduction, electrolysis, or none for native metals); (3) Corrosion and its prevention — why iron rusts, why copper turns green, and how galvanization and sacrificial protection work; (4) Alloys and their composition — what brass, bronze, steel, amalgam, stainless steel and NaK are made of. Most concepts are reference tables: learn the table, win the marks.

Subtopic notes

PYQ weightage by concept

9 concepts · 17 PYQs — where the marks actually sit, so you know what to drill first

Reactivity Series and Reactions with Water6 PYQs · 35%
ConceptPYQsShare
Reactions with water and alkali-metal trends529%
The reactivity series — order of metals16%
Metals versus non-metals — the property contrastfoundation
Extraction of Metals and Ores2 PYQs · 12%
ConceptPYQsShare
Common ores and their metals16%
Extraction method versus reactivity16%
Corrosion and Its Prevention5 PYQs · 29%
ConceptPYQsShare
Preventing corrosion — galvanization and sacrificial protection318%
Corrosion of common metals212%
Alloys and Their Composition4 PYQs · 24%
ConceptPYQsShare
Common alloys and their composition318%
Special-purpose alloys16%

Formula & revision sheet

0 formulas · 9 reference tables · 11 gotchas across all subtopics — the exam-eve cheat-sheet

Reactivity Series and Reactions with Water

Reference tables (3)

Metals versus non-metals — the property contrast5 rows
PropertyMetalsNon-metals
Electron behaviourLose electrons (electropositive)Gain/share electrons (electronegative)
AppearanceLustrous (shiny)Dull (except graphite, iodine)
MalleabilityMalleable and ductileBrittle when solid
ConductivityGood conductorsPoor conductors (except graphite)
Nature of oxideBasicAcidic
Metal oxide + water → base; non-metal oxide + water → acid. This is a common 'which statement is correct' test.
Metals are electropositive and form basic oxides; non-metals are electronegative and form acidic oxides.
The reactivity series — order of metals3 rows
ReactivityMetals (in order)
Most reactivePotassium (K), Sodium (Na), Calcium (Ca)
Moderately reactiveMagnesium (Mg), Aluminium (Al), Zinc (Zn), Iron (Fe)
Least reactiveCopper (Cu), Mercury (Hg), Silver (Ag), Gold (Au)
Decreasing reactivity: K > Na > Ca > Mg > Al > Zn > Fe > Pb > Cu > Hg > Ag > Au.
Reactions with water and alkali-metal trends5 rows
MetalReacts with water?Note
Potassium / SodiumYes, with cold waterFloat and react vigorously (less dense than water)
Both K and Na float on water; potassium reacts even more vigorously than sodium.
CalciumYes, with cold waterReacts steadily, releasing H₂
MagnesiumNo (cold); yes with steamDoes NOT react with cold water
IronNo (cold); slow with steamDoes NOT liberate H₂ from cold water
CopperNoBelow hydrogen — does not react with water
Reactivity with water: Zinc > Iron > Lead > Copper. Caesium has the lowest alkali-metal melting point.

Watch out for (4)

Extraction of Metals and Ores

Reference tables (2)

Common ores and their metals6 rows
OreFormulaMetal
CinnabarHgSMercury
Cinnabar is the ore the bank tests most — it gives mercury.
BauxiteAl₂O₃·2H₂OAluminium
HaematiteFe₂O₃Iron
Zinc blendeZnSZinc
Copper pyritesCuFeS₂Copper
GalenaPbSLead
Cinnabar = mercury, bauxite = aluminium, haematite = iron, galena = lead.
Extraction method versus reactivity3 rows
Reactivity bandExtraction methodExample
Most reactive (K, Na, Ca, Mg, Al)Electrolysis of molten oreAluminium by electrolysis
Carbon CANNOT reduce these — they bind oxygen too strongly. Aluminium is the classic 'needs electrolysis' answer.
Moderate (Zn, Fe, Pb, Cu)Reduction with carbon (coke)ZnO + C → Zn + CO
Least reactive (Ag, Au)Found native; no reductionGold occurs as free metal
Carbon reduction works for moderate metals (Zn, Fe, Pb, Cu); reactive metals need electrolysis; noble metals occur native.

Watch out for (2)

Corrosion and Its Prevention

Reference tables (2)

Corrosion of common metals4 rows
MetalCorrosion productColour / behaviour
IronHydrated iron(III) oxide (rust)Reddish-brown; flakes off — corrodes rapidly
Of the common metals, iron corrodes the fastest — its rust flakes away and exposes fresh metal.
CopperBasic copper carbonateGreen coat (patina) in moist air
The green coat on old copper is basic copper carbonate, NOT copper oxide.
AluminiumAluminium oxideThin, protective layer — stops further attack
SilverSilver sulphideBlack tarnish in sulphur-containing air
Iron rusts (reddish-brown) fastest; copper goes green (basic carbonate); aluminium self-protects.
Preventing corrosion — galvanization and sacrificial protection4 rows
MethodWhat is appliedWhy it works
GalvanizationThin layer of zincZinc is more reactive — sacrifices itself to protect iron
Zinc protects iron even when scratched because it is more electropositive than iron (sacrificial protection).
Painting / oilingPaint or grease filmKeeps air and moisture off the metal
ElectroplatingTin or chromium layerInert coating barrier
AlloyingMix with Cr, Ni (stainless steel)Forms a corrosion-resistant alloy
Galvanization (zinc coat) is the headline method; zinc works as a sacrificial anode because it is more reactive than iron.

Watch out for (2)

Alloys and Their Composition

Reference tables (2)

Common alloys and their composition6 rows
AlloyCompositionNote
BrassCopper + ZincBoth metals
BronzeCopper + TinCu + Sn — the bank's favourite composition question
SteelIron + CarbonCarbon is a non-metal — the 'alloy with a non-metal' answer
Steel is the alloy that contains a NON-METAL (carbon). Brass, bronze and amalgam are metal-only.
Stainless steelIron + Chromium + Nickel (+ C)Tin is NOT an essential component
Essential components of stainless steel are Fe, Cr and Ni — tin is the odd one out.
AmalgamMercury + another metalMercury-based alloy
SolderLead + TinLow-melting joining alloy
Brass = Cu+Zn, Bronze = Cu+Sn, Steel = Fe+C, Stainless steel = Fe+Cr+Ni, Amalgam = Hg-based.
Special-purpose alloys4 rows
AlloyCompositionSpecial use
NaKSodium + PotassiumCoolant / heat transfer in nuclear reactors
Potassium is alloyed with sodium (NaK) to transfer heat in nuclear reactors.
NichromeNickel + ChromiumHeating elements (high resistance)
MagnaliumAluminium + MagnesiumLight, strong structural parts
Type metalLead + Tin + AntimonyPrinting type
NaK (sodium + potassium) is the nuclear-reactor heat-transfer coolant.

Watch out for (3)