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CBSE Class 12 Chemistry 2023 question paper (56/1)

Maximum marks 70 · Time 3 hours · 3 sets

Try each question first, then open its model answer. Where the paper offers a choice, both questions are shown with OR between them.

Section A

1 mark each

  1. Q.11 mark
    The colligative property used for the determination of molar mass of polymers and proteins is :

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  2. Q.21 mark
    Low concentration of oxygen in the blood and tissues of people living at high altitude is due to :

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  3. Q.31 mark
    The correct cell to represent the following reaction is : Zn+2Ag+⟶Zn2++2Ag\mathrm{Zn} + 2\mathrm{Ag}^{+} \longrightarrow \mathrm{Zn}^{2+} + 2\mathrm{Ag}

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  4. Q.41 mark
    ΔG\Delta \mathrm{G} and Ecell∘\mathrm{E}^{\circ}_{\mathrm{cell}} for a spontaneous reaction will be :

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  5. Q.51 mark
    Which of the following is affected by catalyst ?

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  6. Q.61 mark
    The order of the reaction H2 (g)+Cl2 (g)→ hν 2HCl (g)\mathrm{H_2\,(g)} + \mathrm{Cl_2\,(g)} \xrightarrow{\ h\nu\ } 2\mathrm{HCl\,(g)} is :

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  7. Q.71 mark
    The most common and stable oxidation state of a Lanthanoid is :

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  8. Q.81 mark
    The compounds [Co(SO4) (NH3)5] Br\mathrm{[Co(SO_4)\,(NH_3)_5]\,Br} and [Co(Br) (NH3)5] SO4\mathrm{[Co(Br)\,(NH_3)_5]\,SO_4} represent :

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  9. Q.91 mark
    The synthesis of alkyl fluoride is best obtained from :

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  10. Q.101 mark
    In the reaction R−OH+HCl→ZnCl2RCl+H2O\mathrm{R-OH} + \mathrm{HCl} \xrightarrow{\mathrm{ZnCl_2}} \mathrm{RCl} + \mathrm{H_2O}, what is the correct order of reactivity of alcohol ?

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  11. Q.111 mark
    CH3CONH2\mathrm{CH_3CONH_2} on reaction with NaOH and Br2\mathrm{Br_2} in alcoholic medium gives :

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  12. Q.121 mark
    Which of the following is least basic ?

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  13. Q.131 mark
    The glycosidic linkage involved in linking the glucose units in amylase part of starch is :

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  14. Q.141 mark
    An α\alpha-helix is a structural feature of :

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  15. For Questions number 15 to 18, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (a), (b), (c) and (d) as given below.
    Q.151 mark
    Assertion (A) : −NH2-\mathrm{NH_2} group is o- and p-directing in electrophilic substitution reactions. Reason (R) : Aniline cannot undergo Friedel-Crafts reaction.

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  16. Q.161 mark
    Assertion (A) : Acetylation of aniline gives a monosubstituted product. Reason (R) : Activating effect of −NHCOCH3-\mathrm{NHCOCH_3} group is more than that of amino group.

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  17. Q.171 mark
    Assertion (A) : The molecularity of the reaction H2+Br2⟶2HBr\mathrm{H_2} + \mathrm{Br_2} \longrightarrow 2\mathrm{HBr} appears to be 2. Reason (R) : Two molecules of the reactants are involved in the given elementary reaction.

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  18. Q.181 mark
    Assertion (A) : Low spin tetrahedral complexes are rarely observed. Reason (R) : Crystal field splitting energy is less than pairing energy for tetrahedral complexes.

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Section B

2 marks each

  1. Q.192 marks
    What is Henry's law ? Give one application of it.
  2. Q.20 (a)2 marks
    On diluting two electrolytes 'A' and 'B', the Λm\Lambda_{\mathrm{m}} of 'A' increases 25 times while that of 'B' increases by 1⋅51{\cdot}5 times. Which of the two electrolytes is strong ? Justify your answer graphically.
  3. OR

    Q.20 (b)2 marks
    The electrical resistance of a column of 0⋅050{\cdot}05 mol L−1\mathrm{L^{-1}} NaOH solution of diameter 1 cm and length 50 cm is 5⋅55×1035{\cdot}55 \times 10^{3} ohm. Calculate the conductivity.
  4. Q.212 marks
    Complete the following equations : (a) 2MnO4−+5NO2−+6H+⟶2\mathrm{MnO_4^{-}} + 5\mathrm{NO_2^{-}} + 6\mathrm{H}^{+} \longrightarrow (b) Cr2O72−+14H++6e−⟶\mathrm{Cr_2O_7^{2-}} + 14\mathrm{H}^{+} + 6\mathrm{e}^{-} \longrightarrow
  5. Q.222 marks
    (a) CH3−CH(OH)−CH3→PCl5’A’→AgCN’B’\mathrm{CH_3-CH(OH)-CH_3} \xrightarrow{\mathrm{PCl_5}} \text{'A'} \xrightarrow{\mathrm{AgCN}} \text{'B'} (b) CH3CH2CH2Cl+KOH→ethanol’A’→HBr’B’\mathrm{CH_3CH_2CH_2Cl} + \mathrm{KOH} \xrightarrow{\text{ethanol}} \text{'A'} \xrightarrow{\mathrm{HBr}} \text{'B'} Identify 'A' and 'B' in the above reactions.
  6. Q.23 (a)2 marks
    Account for the following : (i) Phenol is a stronger acid than an alcohol. (ii) The boiling point of alcohols decreases with increase in branching of alkyl chain.
  7. OR

    Q.23 (b)2 marks
    (i) Write the mechanism of the following reaction : CH3CH2OH→443 KH+CH2=CH2+H2O\mathrm{CH_3CH_2OH} \xrightarrow[443\ \mathrm{K}]{\mathrm{H}^{+}} \mathrm{CH_2 = CH_2} + \mathrm{H_2O} (ii) Write the equation involved in Reimer-Tiemann reaction.
  8. Q.242 marks
    Explain briefly : (a) Carbylamine reaction (b) Gabriel phthalimide synthesis
  9. Q.252 marks
    (a) Write chemical reaction to show that open structure of D-glucose contains the straight chain. (b) What type of linkage is responsible for the formation of protein ?

Section C

3 marks each

  1. Q.263 marks
    (a) Differentiate between Ideal solution and Non-ideal solution. (b) 30 g of urea is dissolved in 846 g of water. Calculate the vapour pressure of water for this solution if vapour pressure of pure water at 298 K is 23⋅823{\cdot}8 mm Hg.
  2. Q.273 marks
    Write main product formed when : (a) Methyl chloride is treated with NaI/Acetone. (b) 2,4,6-trinitrochlorobenzene is subjected to hydrolysis. (c) n-Butyl chloride is treated with alcoholic KOH.
  3. Q.283 marks
    How do you convert the following : (Any three) (a) Phenol to picric acid (b) Propanone to 2-Methylpropan-2-ol (c) Phenol to anisole (d) Propene to Propan-1-ol
  4. Q.29 (a)3 marks
    Explain why : (i) Carboxyl group in benzoic acid is meta directing. (ii) Sodium bisulphite is used for the purification of aldehydes and ketones. (iii) Carboxylic acids do not give characteristic reactions of carbonyl group.
  5. OR

    Q.29 (b)3 marks
    An organic compound 'A', having the molecular formula C3H8O\mathrm{C_3H_8O} on treatment with Cu at 573 K, gives 'B'. 'B' does not reduce Fehling's solution but gives a yellow precipitate of the compound 'C' with I2/NaOH\mathrm{I_2/NaOH}. Deduce the structures of A, B and C.
  6. Q.303 marks
    (a) What are the hydrolysis products of (i) Lactose, (ii) Maltose ? (b) Give the basic structural difference between starch and cellulose.

Section D

  1. The rate of reaction is concerned with decrease in concentration of reactants or increase in the concentration of products per unit time. It can be expressed as instantaneous rate at a particular instant of time and average rate over a large interval of time. Mathematical representation of rate of reaction is given by rate law. Rate constant and order of a reaction can be determined from rate law or its integrated rate equation.
    Q.31 (i)1 mark
    What is average rate of reaction ?
  2. Q.31 (ii)1 mark
    Write two factors that affect the rate of reaction.
  3. Q.31 (iii) (a)2 marks
    (1) What happens to rate of reaction for zero order reaction ? (2) What is the unit of k for zero order reaction ?
  4. OR

    Q.31 (iii) (b)2 marks
    (1) For a reaction P+2Q⟶Products\mathrm{P} + 2\mathrm{Q} \longrightarrow \text{Products} Rate =k[P]1/2 [Q]1= \mathrm{k[P]}^{1/2}\,\mathrm{[Q]}^{1}. What is the order of the reaction ? (2) Define pseudo first order reaction with an example.
  5. In coordination compounds, metals show two types of linkages, primary and secondary. Primary valencies are ionisable and are satisfied by negatively charged ions. Secondary valencies are non-ionisable and are satisfied by neutral or negative ions having lone pair of electrons. Primary valencies are non-directional while secondary valencies decide the shape of the complexes.
    Q.32 (i)1 mark
    If PtCl2⋅2NH3\mathrm{PtCl_2 \cdot 2NH_3} does not react with AgNO3\mathrm{AgNO_3}, what will be its formula ?
  6. Q.32 (ii)1 mark
    What is the secondary valency of [Co(en)3]3+\mathrm{[Co(en)_3]^{3+}} ?
  7. Q.32 (iii) (a)2 marks
    (1) Write the formula of Iron(III)hexacyanidoferrate(II). (2) Write the IUPAC name of [Co(NH3)5Cl] Cl2\mathrm{[Co(NH_3)_5Cl]\,Cl_2}.
  8. OR

    Q.32 (iii) (b)2 marks
    Write the hybridization and magnetic behaviour of [Ni(CN)4]2−\mathrm{[Ni(CN)_4]^{2-}}. [Atomic number : Ni = 28]

Section E

5 marks each

  1. Q.33 (a)5 marks
    (i) State Kohlrausch's law of independent migration of ions. Write an expression for the limiting molar conductivity of acetic acid according to Kohlrausch's law. (ii) Calculate the maximum work and log⁡Kc\log \mathrm{K_c} for the given reaction at 298 K : Ni (s)+2Ag+ (aq)⇌Ni2+ (aq)+2Ag (s)\mathrm{Ni\,(s)} + 2\mathrm{Ag}^{+}\,\mathrm{(aq)} \rightleftharpoons \mathrm{Ni}^{2+}\,\mathrm{(aq)} + 2\mathrm{Ag\,(s)} Given : ENi2+/Ni∘=− 0⋅25\mathrm{E}^{\circ}_{\mathrm{Ni}^{2+}/\mathrm{Ni}} = -\,0{\cdot}25 V, EAg+/Ag∘=+ 0⋅80\mathrm{E}^{\circ}_{\mathrm{Ag}^{+}/\mathrm{Ag}} = +\,0{\cdot}80 V 1 F = 96500 C mol−1\mathrm{mol^{-1}}
  2. OR

    Q.33 (b)5 marks
    (i) State Faraday's first law of electrolysis. How much charge, in terms of Faraday, is required for the reduction of 1 mol Cu2+\mathrm{Cu}^{2+} to Cu ? (ii) Calculate emf of the following cell at 298 K for Mg (s)∣Mg2+ (0⋅1 M)∥Cu2+ (0⋅01 M)∣Cu (s)\mathrm{Mg\,(s)} \mid \mathrm{Mg}^{2+}\,(0{\cdot}1\ \mathrm{M}) \parallel \mathrm{Cu}^{2+}\,(0{\cdot}01\ \mathrm{M}) \mid \mathrm{Cu\,(s)} [Ecell∘=+ 2⋅71\mathrm{E}^{\circ}_{\mathrm{cell}} = +\,2{\cdot}71 V, 1 F = 96500 C mol−1\mathrm{mol^{-1}}, log⁡10=1\log 10 = 1]
  3. Q.345 marks
    Assign reason for each of the following : (i) Manganese exhibits the highest oxidation state of +7 among the 3d series of transition elements. (ii) Transition metals and their compounds are generally found to be good catalysts in chemical reactions. (iii) Cr2+\mathrm{Cr}^{2+} is reducing in nature while with the same d-orbital configuration (d4)(\mathrm{d}^{4}) Mn3+\mathrm{Mn}^{3+} is an oxidising agent. (iv) Zn has lowest enthalpy of atomization. (v) Cu+\mathrm{Cu}^{+} is unstable in an aqueous solution.
  4. Q.35 (a)5 marks
    (i) Carry out the following conversions : (1) Ethanal to But-2-en-1-al (2) Propanoic acid to 2-chloropropanoic acid (ii) An alkene with molecular formula C5H10\mathrm{C_5H_{10}} on ozonolysis gives a mixture of two compounds 'B' and 'C'. Compound 'B' gives positive Fehling test and also reacts with iodine and NaOH solution. Compound 'C' does not give Fehling solution test but forms iodoform. Identify the compounds 'A', 'B' and 'C'.
  5. OR

    Q.35 (b)5 marks
    (i) Distinguish with a suitable chemical test : (1) CH3COCH2CH3\mathrm{CH_3COCH_2CH_3} and CH3CH2CH2CHO\mathrm{CH_3CH_2CH_2CHO} (2) Ethanal and Ethanoic acid (ii) Write the structure of oxime of acetone. (iii) Identify A to D. CH3COOH→PCl5A→H2/Pd−BaSO4B→(ii) H3O+(i) CH3/MgBrC\mathrm{CH_3COOH} \xrightarrow{\mathrm{PCl_5}} \mathrm{A} \xrightarrow{\mathrm{H_2/Pd-BaSO_4}} \mathrm{B} \xrightarrow[\mathrm{(ii)\ H_3O^{+}}]{\mathrm{(i)\ CH_3/MgBr}} \mathrm{C} and B→LiAlH4D\mathrm{B} \xrightarrow{\mathrm{LiAlH_4}} \mathrm{D}