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CBSE Class 12 Chemistry 2026 question paper (56/5)

Maximum marks 70 · Time 3 hours · 3 sets

Try each question first, then open its model answer. Where the paper offers a choice, both questions are shown with OR between them.

Section A

1 mark each

  1. Q.11 mark
    Which of the reactions is used in the conversion of a ketone into hydrocarbon ?

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  2. Q.21 mark
    Which of the following reagents are used to prepare primary amines by Hoffmann bromamide degradation reaction ? (i) R−CO−NH2\mathrm{R-CO-NH_2} (ii) NaOH\mathrm{NaOH} (iii) Br2\mathrm{Br_2} (iv) CHCl3\mathrm{CHCl_3}

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  3. Q.31 mark
    The major product of carbylamine reaction is :

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  4. Q.41 mark
    Actinoids show larger number of oxidation states :

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  5. Q.51 mark
    Consider the following reaction and identify A and B : CH3Cl+NaI→dry acetoneA+B\mathrm{CH_3Cl + NaI} \xrightarrow{\text{dry acetone}} \mathrm{A + B}

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  6. Q.61 mark
    The correct formula of Hinsberg’s reagent is :

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  7. Q.71 mark
    Half-life (t1/2)\mathrm{(t_{1/2})} of a first order reaction is 1386 s. The value of rate constant is :

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  8. Q.81 mark
    Which of the following ligands forms a chelate complex ?

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  9. Q.91 mark
    Primary, secondary and tertiary alcohols can be distinguished by :

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  10. Q.101 mark
    Consider the following compounds : C2H5NH2\mathrm{C_2H_5NH_2}, (C2H5)2NH\mathrm{(C_2H_5)_2NH}, C6H5CH2NH2\mathrm{C_6H_5CH_2NH_2}, NH3\mathrm{NH_3}, C6H5NH2\mathrm{C_6H_5NH_2} The correct increasing order of the above compounds on the basis of their basic strength is :

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  11. Q.111 mark
    Identify the polysaccharide among the following :

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  12. Q.121 mark
    The polypeptide chain in a protein has amino acids linked with each other in a specific sequence. This specific sequence of amino acids is called :

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  13. For Questions number 13 to 16, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (A), (B), (C) and (D) as given below.
    Q.131 mark
    Assertion (A) : D (+) – Glucose is dextrorotatory in nature. Reason (R) : (+) represents dextrorotatory nature and D represents the configuration.

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  14. Q.141 mark
    Assertion (A) : Highest oxidation state of Mn is +7 in first series of transition elements. Reason (R) : Transition metals exhibit variable oxidation states.

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  15. Q.151 mark
    Assertion (A) : p-nitrophenol is more acidic than phenol. Reason (R) : Nitro group is an electron-withdrawing group, it stabilises phenoxide ion by dispersal of negative charge.

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  16. Q.161 mark
    Assertion (A) : All aliphatic aldehydes give a positive Fehling’s test. Reason (R) : Aliphatic aldehydes are reduced by Fehling’s reagent.

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Section B

2 marks each

  1. Q.17 (A)2 marks
    1⋅001{\cdot}00 molal aqueous solution of trichloroacetic acid is heated to its boiling point. Boiling point of this solution was found to be 100⋅18∘100{\cdot}18^\circC. Calculate the van’t Hoff factor for trichloroacetic acid. (Given : Kb\mathrm{K_b} for water = 0⋅5120{\cdot}512 K kg mol−1\mathrm{mol^{-1}})
  2. OR

    Q.17 (B)2 marks
    State Henry’s law. Calculate the mole fraction of CO2\mathrm{CO_2} in water at 298 K under 760 mm Hg. (Given : KH\mathrm{K_H} for CO2\mathrm{CO_2} in H2O\mathrm{H_2O} at 298 K = 1⋅25×1061{\cdot}25 \times 10^{6} mm Hg)
  3. Q.182 marks
    (a) Name the cell which was used in the Apollo space programme for providing electrical power. (b) Define limiting molar conductivity.
  4. Q.192 marks
    (a) Complete the following equation : C6H5N2+Cl−+C6H5OH→OH−\mathrm{C_6H_5N_2^{+}Cl^{-} + C_6H_5OH \xrightarrow{OH^{-}}} (b) How will you convert nitromethane to methyl isocyanide ?
  5. Q.202 marks
    (a) What are the products obtained on hydrolysis of sucrose ? (b) What are essential amino acids ?
  6. Q.212 marks
    (a) Write any two fat soluble vitamins. (b) How will you confirm the presence of five – OH groups in a glucose molecule, which are attached to different carbon atoms ?

Section C

3 marks each

  1. Q.223 marks
    Calculate emf of the following cell at 298 K : Cr (s)∣Cr3+(aq) (0⋅1 M)∥Fe2+(aq) (0⋅01 M)∣Fe (s)\mathrm{Cr\,(s)} \mid \mathrm{Cr^{3+}(aq)}\ (0{\cdot}1\ \mathrm{M}) \parallel \mathrm{Fe^{2+}(aq)}\ (0{\cdot}01\ \mathrm{M}) \mid \mathrm{Fe\,(s)} (Given : ECr3+/Cro=− 0⋅74\mathrm{E^{o}_{Cr^{3+}/Cr}} = -\,0{\cdot}74 V, EFe2+/Feo=− 0⋅44\mathrm{E^{o}_{Fe^{2+}/Fe}} = -\,0{\cdot}44 V, [log 10 = 1])
  2. Q.233 marks
    (a) Define order of a reaction. (b) The rate for the following reaction is given by : A+B→C\mathrm{A + B \rightarrow C} Rate = k[A][B]2\mathrm{k[A][B]^{2}} (i) How is the rate of reaction affected if we double the concentration of B ? (ii) Write the overall order of a reaction if ‘A’ is present in large excess.
  3. Q.243 marks
    The rate of the chemical reaction doubles when the temperature is raised from 298 K to 308 K. Calculate activation energy (Ea)\mathrm{(E_a)} for this reaction assuming that it does not change with temperature. (Given : R = 8⋅3148{\cdot}314 J mol−1\mathrm{mol^{-1}} K−1\mathrm{K^{-1}}, log 2 = 0⋅300{\cdot}30)
  4. Q.253 marks
    (a) Write the IUPAC name of the following complex : K3[Cr(C2O4)3]\mathrm{K_3[Cr(C_2O_4)_3]} (b) Differentiate between homoleptic complex and heterolyptic complex. (c) Which type of isomerism is exhibited by the following complex : [Pt(NH3)2Cl2]\mathrm{[Pt(NH_3)_2Cl_2]}
  5. Q.263 marks
    (a) A coordination compound CrCl3⋅6H2O\mathrm{CrCl_3 \cdot 6H_2O} is mixed with excess of AgNO3\mathrm{AgNO_3} solution, two moles of AgCl are precipitated per mole of the compound. Write the structural formula of the coordination compound. (b) Write the oxidation state and hybridisation of the central metal in the following complex : [Fe(H2O)6]3+\mathrm{[Fe(H_2O)_6]^{3+}} [Atomic number of Fe = 26] (c) Why is [Ni(H2O)6]2+\mathrm{[Ni(H_2O)_6]^{2+}} coloured ? [Atomic number of Ni = 28]
  6. Q.273 marks
    How do you convert the following ? (a) Acetophenone to Benzoic acid (b) Acetonitrile to Acetone (c) Benzoic acid to Benzene
  7. Q.28 (A)3 marks
    (i) Arrange the following compounds in increasing order of their acidic strengths : CH3CH(Br)CH2COOH\mathrm{CH_3CH(Br)CH_2COOH}, CH3−CH(CH3)−COOH\mathrm{CH_3-CH(CH_3)-COOH}, CH3CH2CH(Br)COOH\mathrm{CH_3CH_2CH(Br)COOH} (ii) Why is CH3CHO\mathrm{CH_3CHO} more reactive than acetone towards reaction with HCN ? (iii) Complete the equation : CH3CHO+NH2−NH2→H+\mathrm{CH_3CHO + NH_2-NH_2 \xrightarrow{H^{+}}}
  8. OR

    Q.28 (B)3 marks
    An organic compound with the molecular formula C8H8O\mathrm{C_8H_8O} forms 2,4-DNP derivative, reduces Tollens’ reagent and undergoes Cannizzaro reaction. On vigorous oxidation it gives Benzene-1,2-dicarboxylic acid. Identify the compound and write the reactions of compound 2,4-DNP and when it undergoes Cannizzaro reaction.

Section D

  1. Ethers are prepared by the dehydration of alcohols in presence of protic acids at 413 K. Symmetrical and unsymmetrical ethers can also be prepared by Williamson synthesis. This reaction involves SN2\mathrm{S_N2} attack of an alkoxide ion on primary alkyl halide. If a tertiary alkyl halide is used, elimination reaction occurs and an alkene is formed, no ether is formed. C – O bond in ethers are cleaved under drastic conditions with excess of HI. When unsymmetrical ethers react with HI, the alkyl halide is formed from smaller alkyl group. If one of the alkyl group is tertiary, the alkyl halide is formed from the tertiary alkyl group because tertiary alkyl carbocation is more stable than the primary carbocation. Cleavage of alkyl aryl ethers takes place at the alkyl-oxygen bond due to more stable aryl-oxygen bond. The order of reactivity of hydrogen halides is HI > HBr > HCl. Aromatic ethers undergo electrophilic substitution reactions. The alkoxy group attached to the aromatic ring activates the ring towards electrophilic substitution and directs the incoming group to ortho- and para-positions.
    Q.29 (a)2 marks
    Complete the following equations : (i) anisole (C6H5OCH3)\mathrm{(C_6H_5OCH_3)} + CH3Cl→CS2Anhyd. AlCl3\mathrm{CH_3Cl} \xrightarrow[\mathrm{CS_2}]{\text{Anhyd. } \mathrm{AlCl_3}} (ii) anisole (C6H5OCH3)→Conc. (HNO3+H2SO4)\mathrm{(C_6H_5OCH_3)} \xrightarrow{\text{Conc. } \mathrm{(HNO_3 + H_2SO_4)}}
  2. Q.29 (b)1 mark
    Write the names of alkyl halide and sodium alkoxide used to prepare tert-butyl ethyl ether.
  3. OR

    Q.29 (b) OR1 mark
    Anisole on reaction with HI gives phenol and CH3−I\mathrm{CH_3 - I} and not methanol and iodobenzene. Justify the statement.
  4. Q.29 (c)1 mark
    Why is C – O – C bond angle in ethers slightly greater than tetrahedral angle ?
  5. Electrochemistry is the study of the relationship between chemical energy and electrical energy. Many spontaneously occurring chemical reactions liberate electrical energy. In electrolysis, electrical energy is converted directly into chemical energy. The product of an electrolytic reaction depends on the nature of the material being electrolysed and the type of electrode used. Oxidising and reducing species present in the electrolytic cell and their standard electrode potential too, affect the products of electrolysis. Electrolysis plays an important role in most people’s daily lives, whether it is for the manufacturing of aluminium, electroplating of metals, or the synthesis of chemical compounds. Michael Faraday was the first scientist who proposed two laws to explain the quantitative aspects of electrolysis, popularly known as Faraday’s laws of electrolysis. Faraday’s laws of electrolysis provide a basis for mathematical analysis of the mass deposited at electrodes and the amount of charge passed through them. Faraday’s laws are fundamental in various applications, including electroplating, metal extraction, battery technology and chemical synthesis. These laws also help in environmental monitoring and in various chemistry experiments.
    Q.30 (a)2 marks
    Predict the products of electrolysis in each of the following : (i) An aqueous solution of CuCl2\mathrm{CuCl_2} with platinum electrodes. (ii) A concentrated solution of H2SO4\mathrm{H_2SO_4} with platinum electrodes.
  6. Q.30 (b)1 mark
    How much charge in faraday is required for the reduction of 1 mol of Ag+\mathrm{Ag^{+}} to Ag ?
  7. OR

    Q.30 (b) OR1 mark
    State Faraday’s second law of electrolysis.
  8. Q.30 (c)1 mark
    The following reactions occur at the anode during the electrolysis of aqueous sodium chloride solution : Cl−(aq)⟶12Cl2(g)+e−\mathrm{Cl^{-}(aq)} \longrightarrow \frac{1}{2}\mathrm{Cl_2(g) + e^{-}} E(cell)o=1⋅36\mathrm{E^{o}_{(cell)}} = 1{\cdot}36 V (I) 2H2O (l)⟶O2(g)+4H+(aq)+4e−\mathrm{2H_2O}\,(l) \longrightarrow \mathrm{O_2(g) + 4H^{+}(aq) + 4e^{-}} E(cell)o=1⋅23\mathrm{E^{o}_{(cell)}} = 1{\cdot}23 V (II) Which reaction is feasible at the anode and why ?

Section E

5 marks each

  1. Q.31 (A)5 marks
    (i) Calculate the freezing point of a solution when 10⋅510{\cdot}5 g of MgBr2\mathrm{MgBr_2} was dissolved in 250 g of water, assuming MgBr2\mathrm{MgBr_2} undergoes complete dissociation. (Given : Molar mass of MgBr2\mathrm{MgBr_2} = 184 g mol−1\mathrm{mol^{-1}}, Kf\mathrm{K_f} for water = 1⋅861{\cdot}86 K kg mol−1\mathrm{mol^{-1}}) (ii) Write two differences between ideal and non-ideal solutions.
  2. OR

    Q.31 (B)5 marks
    (i) A solution is prepared by dissolving 0⋅0250{\cdot}025 g of potassium sulphate in 2 L of water at 27∘27^\circC. Assuming potassium sulphate is completely dissociated, determine its osmotic pressure. (Given : R = 0⋅0820{\cdot}082 L atm K−1\mathrm{K^{-1}} mol−1\mathrm{mol^{-1}}, Molar mass of K2SO4\mathrm{K_2SO_4} = 174 g mol−1\mathrm{mol^{-1}}) (ii) What type of azeotrope will be formed by a solution of acetone and chloroform ? Give reason.
  3. Q.32 (A)5 marks
    (i) (I) Why do transition metals show variable oxidation states ? (II) Out of Mn2+\mathrm{Mn^{2+}} and Ti2+\mathrm{Ti^{2+}} which will be more paramagnetic and why ? [Atomic No. : Ti = 22, Mn = 25] (III) Which ion is the strongest oxidising agent in the options given below : Cr3+\mathrm{Cr^{3+}}, V3+\mathrm{V^{3+}}, Mn3+\mathrm{Mn^{3+}} Give reason. [Atomic No. : Cr = 24, V = 23, Mn = 25] (ii) Complete and balance the following equations : (I) 2MnO2+4KOH+O2⟶\mathrm{2MnO_2 + 4KOH + O_2 \longrightarrow} (II) 5C2O42−+2MnO4−+16H+⟶\mathrm{5C_2O_4^{2-} + 2MnO_4^{-} + 16H^{+} \longrightarrow}
  4. OR

    Q.32 (B)5 marks
    (i) What is meant by lanthanoid contraction ? (ii) Why do transition metals form coloured compounds ? (iii) Why are EM2+/Mo\mathrm{E^{o}_{M^{2+}/M}} values for Mn and Zn more negative than expected ? (iv) Which is the most stable oxidation state of Cu and why ? (v) Why is Ce4+\mathrm{Ce^{4+}} in aqueous solution a good oxidising agent ?
  5. Q.33 (A)5 marks
    (i) (I) Which of the following is more reactive towards SN1\mathrm{S_N1} reaction : 2-Bromo-2-methylbutane or 1-Bromopentane (II) What type of halide is present in the following compound : CH3−CH(CH3)−C(Cl)=CH2\mathrm{CH_3 - CH(CH_3) - C(Cl) = CH_2} (III) Why is chloroform stored in dark coloured bottles ? (ii) Define the following terms : (I) Ambident Nucleophiles (II) Racemic mixture
  6. OR

    Q.33 (B)5 marks
    (i) Answer the following : (I) Which isomer of C4H9Br\mathrm{C_4H_9Br} is most reactive towards SN1\mathrm{S_N1} reaction ? (II) Predict the alkene that would be formed by dehydrohalogenation of 1-Bromo-1-methylcyclohexane. (III) Although chlorine shows strong – I effect, yet it is ortho/para-directing in electrophilic aromatic substitution reactions. Why ? (ii) Write the major product in the following reactions : (I) 2 C6H5Cl→Na/dry Ether2\,\mathrm{C_6H_5Cl} \xrightarrow{\mathrm{Na/dry\ Ether}} (II) 4-nitrocumene (O2N−C6H4−CH(CH3)2\mathrm{(O_2N - C_6H_4 - CH(CH_3)_2}, para)) + Br2→heat\mathrm{Br_2} \xrightarrow{\text{heat}}