CBSE Class 12 Chemistry 2026 question paper (56/5)
Maximum marks 70 · Time 3 hours · 3 sets
Try each question first, then open its model answer. Where the paper offers a choice, both questions are shown with OR between them.
Section A
1 mark each
- Q.11 markWhich of the reactions is used in the conversion of a ketone into hydrocarbon ?
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- Q.21 markWhich of the following reagents are used to prepare primary amines by Hoffmann bromamide degradation reaction ? (i) (ii) (iii) (iv)
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- Q.31 markThe major product of carbylamine reaction is :
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- Q.41 markActinoids show larger number of oxidation states :
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- Q.51 markConsider the following reaction and identify A and B :
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- Q.61 markThe correct formula of Hinsberg’s reagent is :
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- Q.71 markHalf-life of a first order reaction is 1386 s. The value of rate constant is :
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- Q.81 markWhich of the following ligands forms a chelate complex ?
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- Q.91 markPrimary, secondary and tertiary alcohols can be distinguished by :
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- Q.101 markConsider the following compounds : , , , , The correct increasing order of the above compounds on the basis of their basic strength is :
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- Q.111 markIdentify the polysaccharide among the following :
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- Q.121 markThe polypeptide chain in a protein has amino acids linked with each other in a specific sequence. This specific sequence of amino acids is called :
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- For Questions number 13 to 16, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (A), (B), (C) and (D) as given below.Q.131 markAssertion (A) : D (+) – Glucose is dextrorotatory in nature. Reason (R) : (+) represents dextrorotatory nature and D represents the configuration.
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- Q.141 markAssertion (A) : Highest oxidation state of Mn is +7 in first series of transition elements. Reason (R) : Transition metals exhibit variable oxidation states.
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- Q.151 markAssertion (A) : p-nitrophenol is more acidic than phenol. Reason (R) : Nitro group is an electron-withdrawing group, it stabilises phenoxide ion by dispersal of negative charge.
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- Q.161 markAssertion (A) : All aliphatic aldehydes give a positive Fehling’s test. Reason (R) : Aliphatic aldehydes are reduced by Fehling’s reagent.
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Section B
2 marks each
- Q.17 (A)2 marksmolal aqueous solution of trichloroacetic acid is heated to its boiling point. Boiling point of this solution was found to be C. Calculate the van’t Hoff factor for trichloroacetic acid. (Given : for water = K kg )
OR
Q.17 (B)2 marksState Henry’s law. Calculate the mole fraction of in water at 298 K under 760 mm Hg. (Given : for in at 298 K = mm Hg)- Q.182 marks(a) Name the cell which was used in the Apollo space programme for providing electrical power. (b) Define limiting molar conductivity.
- Q.192 marks(a) Complete the following equation : (b) How will you convert nitromethane to methyl isocyanide ?
- Q.202 marks(a) What are the products obtained on hydrolysis of sucrose ? (b) What are essential amino acids ?
- Q.212 marks(a) Write any two fat soluble vitamins. (b) How will you confirm the presence of five – OH groups in a glucose molecule, which are attached to different carbon atoms ?
Section C
3 marks each
- Q.223 marksCalculate emf of the following cell at 298 K : (Given : V, V, [log 10 = 1])
- Q.233 marks(a) Define order of a reaction. (b) The rate for the following reaction is given by : Rate = (i) How is the rate of reaction affected if we double the concentration of B ? (ii) Write the overall order of a reaction if ‘A’ is present in large excess.
- Q.243 marksThe rate of the chemical reaction doubles when the temperature is raised from 298 K to 308 K. Calculate activation energy for this reaction assuming that it does not change with temperature. (Given : R = J , log 2 = )
- Q.253 marks(a) Write the IUPAC name of the following complex : (b) Differentiate between homoleptic complex and heterolyptic complex. (c) Which type of isomerism is exhibited by the following complex :
- Q.263 marks(a) A coordination compound is mixed with excess of solution, two moles of AgCl are precipitated per mole of the compound. Write the structural formula of the coordination compound. (b) Write the oxidation state and hybridisation of the central metal in the following complex : [Atomic number of Fe = 26] (c) Why is coloured ? [Atomic number of Ni = 28]
- Q.273 marksHow do you convert the following ? (a) Acetophenone to Benzoic acid (b) Acetonitrile to Acetone (c) Benzoic acid to Benzene
- Q.28 (A)3 marks(i) Arrange the following compounds in increasing order of their acidic strengths : , , (ii) Why is more reactive than acetone towards reaction with HCN ? (iii) Complete the equation :
OR
Q.28 (B)3 marksAn organic compound with the molecular formula forms 2,4-DNP derivative, reduces Tollens’ reagent and undergoes Cannizzaro reaction. On vigorous oxidation it gives Benzene-1,2-dicarboxylic acid. Identify the compound and write the reactions of compound 2,4-DNP and when it undergoes Cannizzaro reaction.
Section D
- Ethers are prepared by the dehydration of alcohols in presence of protic acids at 413 K. Symmetrical and unsymmetrical ethers can also be prepared by Williamson synthesis. This reaction involves attack of an alkoxide ion on primary alkyl halide. If a tertiary alkyl halide is used, elimination reaction occurs and an alkene is formed, no ether is formed. C – O bond in ethers are cleaved under drastic conditions with excess of HI. When unsymmetrical ethers react with HI, the alkyl halide is formed from smaller alkyl group. If one of the alkyl group is tertiary, the alkyl halide is formed from the tertiary alkyl group because tertiary alkyl carbocation is more stable than the primary carbocation. Cleavage of alkyl aryl ethers takes place at the alkyl-oxygen bond due to more stable aryl-oxygen bond. The order of reactivity of hydrogen halides is HI > HBr > HCl. Aromatic ethers undergo electrophilic substitution reactions. The alkoxy group attached to the aromatic ring activates the ring towards electrophilic substitution and directs the incoming group to ortho- and para-positions.Q.29 (a)2 marksComplete the following equations : (i) anisole + (ii) anisole
- Q.29 (b)1 markWrite the names of alkyl halide and sodium alkoxide used to prepare tert-butyl ethyl ether.
OR
Q.29 (b) OR1 markAnisole on reaction with HI gives phenol and and not methanol and iodobenzene. Justify the statement.- Q.29 (c)1 markWhy is C – O – C bond angle in ethers slightly greater than tetrahedral angle ?
- Electrochemistry is the study of the relationship between chemical energy and electrical energy. Many spontaneously occurring chemical reactions liberate electrical energy. In electrolysis, electrical energy is converted directly into chemical energy. The product of an electrolytic reaction depends on the nature of the material being electrolysed and the type of electrode used. Oxidising and reducing species present in the electrolytic cell and their standard electrode potential too, affect the products of electrolysis. Electrolysis plays an important role in most people’s daily lives, whether it is for the manufacturing of aluminium, electroplating of metals, or the synthesis of chemical compounds. Michael Faraday was the first scientist who proposed two laws to explain the quantitative aspects of electrolysis, popularly known as Faraday’s laws of electrolysis. Faraday’s laws of electrolysis provide a basis for mathematical analysis of the mass deposited at electrodes and the amount of charge passed through them. Faraday’s laws are fundamental in various applications, including electroplating, metal extraction, battery technology and chemical synthesis. These laws also help in environmental monitoring and in various chemistry experiments.Q.30 (a)2 marksPredict the products of electrolysis in each of the following : (i) An aqueous solution of with platinum electrodes. (ii) A concentrated solution of with platinum electrodes.
- Q.30 (b)1 markHow much charge in faraday is required for the reduction of 1 mol of to Ag ?
OR
Q.30 (b) OR1 markState Faraday’s second law of electrolysis.- Q.30 (c)1 markThe following reactions occur at the anode during the electrolysis of aqueous sodium chloride solution : V (I) V (II) Which reaction is feasible at the anode and why ?
Section E
5 marks each
- Q.31 (A)5 marks(i) Calculate the freezing point of a solution when g of was dissolved in 250 g of water, assuming undergoes complete dissociation. (Given : Molar mass of = 184 g , for water = K kg ) (ii) Write two differences between ideal and non-ideal solutions.
OR
Q.31 (B)5 marks(i) A solution is prepared by dissolving g of potassium sulphate in 2 L of water at C. Assuming potassium sulphate is completely dissociated, determine its osmotic pressure. (Given : R = L atm , Molar mass of = 174 g ) (ii) What type of azeotrope will be formed by a solution of acetone and chloroform ? Give reason.- Q.32 (A)5 marks(i) (I) Why do transition metals show variable oxidation states ? (II) Out of and which will be more paramagnetic and why ? [Atomic No. : Ti = 22, Mn = 25] (III) Which ion is the strongest oxidising agent in the options given below : , , Give reason. [Atomic No. : Cr = 24, V = 23, Mn = 25] (ii) Complete and balance the following equations : (I) (II)
OR
Q.32 (B)5 marks(i) What is meant by lanthanoid contraction ? (ii) Why do transition metals form coloured compounds ? (iii) Why are values for Mn and Zn more negative than expected ? (iv) Which is the most stable oxidation state of Cu and why ? (v) Why is in aqueous solution a good oxidising agent ?- Q.33 (A)5 marks(i) (I) Which of the following is more reactive towards reaction : 2-Bromo-2-methylbutane or 1-Bromopentane (II) What type of halide is present in the following compound : (III) Why is chloroform stored in dark coloured bottles ? (ii) Define the following terms : (I) Ambident Nucleophiles (II) Racemic mixture
OR
Q.33 (B)5 marks(i) Answer the following : (I) Which isomer of is most reactive towards reaction ? (II) Predict the alkene that would be formed by dehydrohalogenation of 1-Bromo-1-methylcyclohexane. (III) Although chlorine shows strong – I effect, yet it is ortho/para-directing in electrophilic aromatic substitution reactions. Why ? (ii) Write the major product in the following reactions : (I) (II) 4-nitrocumene , para +
Section A
1 mark each
- Q.11 markWhich of the following reagents are used to prepare primary amines by Hoffmann bromamide degradation reaction ? (i) (ii) (iii) (iv)
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- Q.21 markThe correct formula of Hinsberg’s reagent is :
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- Q.31 markActinoids show larger number of oxidation states :
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- Q.41 markConsider the following reaction and identify A and B :
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- Q.51 markThe major product of carbylamine reaction is :
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- Q.61 markWhich of the reactions is used in the conversion of a ketone into hydrocarbon ?
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- Q.71 markWhich of the following ligands forms a chelate complex ?
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- Q.81 markHalf-life of a first order reaction is 1386 s. The value of rate constant is :
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- Q.91 markThe polypeptide chain in a protein has amino acids linked with each other in a specific sequence. This specific sequence of amino acids is called :
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- Q.101 markIdentify the polysaccharide among the following :
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- Q.111 markConsider the following compounds : , , , , The correct increasing order of the above compounds on the basis of their basic strength is :
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- Q.121 markPrimary, secondary and tertiary alcohols can be distinguished by :
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- For Questions number 13 to 16, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (A), (B), (C) and (D) as given below.Q.131 markAssertion (A) : All aliphatic aldehydes give a positive Fehling’s test. Reason (R) : Aliphatic aldehydes are reduced by Fehling’s reagent.
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- Q.141 markAssertion (A) : D (+) – Glucose is dextrorotatory in nature. Reason (R) : (+) represents dextrorotatory nature and D represents the configuration.
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- Q.151 markAssertion (A) : Highest oxidation state of Mn is +7 in first series of transition elements. Reason (R) : Transition metals exhibit variable oxidation states.
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- Q.161 markAssertion (A) : p-nitrophenol is more acidic than phenol. Reason (R) : Nitro group is an electron-withdrawing group, it stabilises phenoxide ion by dispersal of negative charge.
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Section B
2 marks each
- Q.172 marks(a) Complete the following equation : (b) How will you convert nitromethane to methyl isocyanide ?
- Q.182 marks(a) Name any two materials other than hydrogen that can be used as fuel in fuel cells. (b) Define molar conductivity.
- Q.19 (a)2 marksmolal aqueous solution of trichloroacetic acid is heated to its boiling point. Boiling point of this solution was found to be C. Calculate the van’t Hoff factor for trichloroacetic acid. (Given : for water = K kg )
OR
Q.19 (b)2 marksState Henry’s law. Calculate the mole fraction of in water at 298 K under 760 mm Hg. (Given : for in at 298 K = mm Hg)- Q.202 marks(a) Write the hydrolysis products of lactose. (b) What are non-essential amino acids ?
- Q.212 marks(a) Name two water-soluble vitamins. (b) How will you prove the absence of free – CHO group in the cyclic structure of glucose molecule ?
Section C
3 marks each
- Q.223 marksCalculate emf of the following cell at 298 K : (Given : V, V, [log 10 = 1])
- Q.233 marksHow do you convert the following ? (a) Toluene to Benzaldehyde (b) Benzoyl chloride to Acetophenone (c) Bromobenzene to Benzoic acid
- Q.243 marksThe rate of a particular reaction quadruples when the temperature increases from 293 K to 313 K. Calculate the energy of activation of the reaction assuming that it does not change with temperature. (Given : log 4 = , R = )
- Q.253 marks(a) Write the IUPAC name of the given complex : (b) Define polydentate ligand. Give an example. (c) Mention the type of isomerism exhibited by the given complex :
- Q.263 marks(a) A coordination compound is mixed with excess of solution, one mole of AgCl is precipitated per mole of the compound. Write the structural formula of the coordination compound. (b) Write the oxidation state and hybridisation of the central metal in the given complex : . [Atomic number : Fe = 26] (c) Why is coloured ? [Atomic number : Ti = 22]
- Q.273 marks(a) Define order of a reaction. (b) The rate for the following reaction is given by : Rate = (i) How is the rate of reaction affected if we double the concentration of B ? (ii) Write the overall order of a reaction if ‘A’ is present in large excess.
- Q.28 (a)3 marks(i) Arrange the following compounds in increasing order of their acidic strengths : , , (ii) Why is more reactive than acetone towards reaction with HCN ? (iii) Complete the equation :
OR
Q.28 (b)3 marksAn organic compound with the molecular formula forms 2,4-DNP derivative, reduces Tollens’ reagent and undergoes Cannizzaro reaction. On vigorous oxidation it gives Benzene-1,2-dicarboxylic acid. Identify the compound and write the reactions of compound 2,4-DNP and when it undergoes Cannizzaro reaction.
Section D
- Electrochemistry is the study of the relationship between chemical energy and electrical energy. Many spontaneously occurring chemical reactions liberate electrical energy. In electrolysis, electrical energy is converted directly into chemical energy. The product of an electrolytic reaction depends on the nature of the material being electrolysed and the type of electrode used. Oxidising and reducing species present in the electrolytic cell and their standard electrode potential too, affect the products of electrolysis. Electrolysis plays an important role in most people’s daily lives, whether it is for the manufacturing of aluminium, electroplating of metals, or the synthesis of chemical compounds. Michael Faraday was the first scientist who proposed two laws to explain the quantitative aspects of electrolysis, popularly known as Faraday’s laws of electrolysis. Faraday’s laws of electrolysis provide a basis for mathematical analysis of the mass deposited at electrodes and the amount of charge passed through them. Faraday’s laws are fundamental in various applications, including electroplating, metal extraction, battery technology and chemical synthesis. These laws also help in environmental monitoring and in various chemistry experiments.Q.29 (a)2 marksPredict the products of electrolysis in each of the following : (i) An aqueous solution of with platinum electrodes. (ii) A concentrated solution of with platinum electrodes.
- Q.29 (b) (i)1 markHow much charge in faraday is required for the reduction of 1 mol of to Ag ?
OR
Q.29 (b) (ii)1 markState Faraday’s second law of electrolysis.- Q.29 (c)1 markThe following reactions occur at the anode during the electrolysis of aqueous sodium chloride solution : V (I) V (II) Which reaction is feasible at the anode and why ?
- Ethers are prepared by the dehydration of alcohols in presence of protic acids at 413 K. Symmetrical and unsymmetrical ethers can also be prepared by Williamson synthesis. This reaction involves attack of an alkoxide ion on primary alkyl halide. If a tertiary alkyl halide is used, elimination reaction occurs and an alkene is formed, no ether is formed. C – O bond in ethers are cleaved under drastic conditions with excess of HI. When unsymmetrical ethers react with HI, the alkyl halide is formed from smaller alkyl group. If one of the alkyl group is tertiary, the alkyl halide is formed from the tertiary alkyl group because tertiary alkyl carbocation is more stable than the primary carbocation. Cleavage of alkyl aryl ethers takes place at the alkyl-oxygen bond due to more stable aryl-oxygen bond. The order of reactivity of hydrogen halides is HI > HBr > HCl. Aromatic ethers undergo electrophilic substitution reactions. The alkoxy group attached to the aromatic ring activates the ring towards electrophilic substitution and directs the incoming group to ortho- and para-positions.Q.30 (a)2 marksComplete the following equations : (i) anisole + (ii) anisole
- Q.30 (b) (i)1 markWrite the names of alkyl halide and sodium alkoxide used to prepare tert-butyl ethyl ether.
OR
Q.30 (b) (ii)1 markAnisole on reaction with HI gives phenol and and not methanol and iodobenzene. Justify the statement.- Q.30 (c)1 markWhy is C – O – C bond angle in ethers slightly greater than tetrahedral angle ?
Section E
5 marks each
- Q.31 (a)5 marks(i) (I) Which of the following is more reactive towards reaction : 2-Bromo-2-methylbutane or 1-Bromopentane (II) What type of halide is present in the following compound : (III) Why is chloroform stored in dark coloured bottles ? (ii) Define the following terms : (I) Ambident Nucleophiles (II) Racemic mixture
OR
Q.31 (b)5 marks(i) Answer the following : (I) Which isomer of is most reactive towards reaction ? (II) Predict the alkene that would be formed by dehydrohalogenation of 1-Bromo-1-methylcyclohexane. (III) Although chlorine shows strong – I effect, yet it is ortho/para-directing in electrophilic aromatic substitution reactions. Why ? (ii) Write the major product in the following reactions : (I) (II) 4-nitrocumene , para +- Q.32 (a)5 marks(i) Calculate the freezing point of a solution when g of was dissolved in 250 g of water, assuming undergoes complete dissociation. (Given : Molar mass of = 184 g , for water = K kg ) (ii) Write two differences between ideal and non-ideal solutions.
OR
Q.32 (b)5 marks(i) A solution is prepared by dissolving g of potassium sulphate in 2 L of water at C. Assuming potassium sulphate is completely dissociated, determine its osmotic pressure. (Given : R = L atm , Molar mass of = 174 g ) (ii) What type of azeotrope will be formed by a solution of acetone and chloroform ? Give reason.- Q.33 (a)5 marks(i) (I) Why do transition metals show variable oxidation states ? (II) Out of and which will be more paramagnetic and why ? [Atomic No. : Ti = 22, Mn = 25] (III) Which ion is the strongest oxidising agent in the options given below : , , Give reason. [Atomic No. : Cr = 24, V = 23, Mn = 25] (ii) Complete and balance the following equations : (I) (II)
OR
Q.33 (b)5 marks(i) What is meant by lanthanoid contraction ? (ii) Why do transition metals form coloured compounds ? (iii) Why are values for Mn and Zn more negative than expected ? (iv) Which is the most stable oxidation state of Cu and why ? (v) Why is in aqueous solution a good oxidising agent ?
Section A
1 mark each
- Q.11 markThe major product of carbylamine reaction is :
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- Q.21 markConsider the following reaction and identify A and B :
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- Q.31 markWhich of the reactions is used in the conversion of a ketone into hydrocarbon ?
Tap an option to check your answer.
- Q.41 markWhich of the following reagents are used to prepare primary amines by Hoffmann bromamide degradation reaction ? (i) (ii) (iii) (iv)
Tap an option to check your answer.
- Q.51 markThe correct formula of Hinsberg’s reagent is :
Tap an option to check your answer.
- Q.61 markActinoids show larger number of oxidation states :
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- Q.71 markPrimary, secondary and tertiary alcohols can be distinguished by :
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- Q.81 markConsider the following compounds : , , , , The correct increasing order of the above compounds on the basis of their basic strength is :
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- Q.91 markIdentify the polysaccharide among the following :
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- Q.101 markThe polypeptide chain in a protein has amino acids linked with each other in a specific sequence. This specific sequence of amino acids is called :
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- Q.111 markHalf-life of a first order reaction is 1386 s. The value of rate constant is :
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- Q.121 markWhich of the following ligands forms a chelate complex ?
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- For Questions number 13 to 16, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (A), (B), (C) and (D) as given below.Q.131 markAssertion (A) : p-nitrophenol is more acidic than phenol. Reason (R) : Nitro group is an electron-withdrawing group, it stabilises phenoxide ion by dispersal of negative charge.
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- Q.141 markAssertion (A) : All aliphatic aldehydes give a positive Fehling’s test. Reason (R) : Aliphatic aldehydes are reduced by Fehling’s reagent.
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- Q.151 markAssertion (A) : D (+) – Glucose is dextrorotatory in nature. Reason (R) : (+) represents dextrorotatory nature and D represents the configuration.
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- Q.161 markAssertion (A) : Highest oxidation state of Mn is +7 in first series of transition elements. Reason (R) : Transition metals exhibit variable oxidation states.
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Section B
2 marks each
- Q.172 marks(a) What are the products obtained on hydrolysis of sucrose ? (b) What are essential amino acids ?
- Q.182 marks(a) Name the cell used in hearing aids and watches. (b) Define conductivity. Why is direct current (DC) not used for the measurement of resistance of an ionic solution ?
- Q.192 marks(a) Complete the equation : (b) How will you convert chlorobenzene to p-chloroaniline ?
- Q.20 (a)2 marksmolal aqueous solution of trichloroacetic acid is heated to its boiling point. Boiling point of this solution was found to be C. Calculate the van’t Hoff factor for trichloroacetic acid. (Given : for water = K kg )
OR
Q.20 (b)2 marksState Henry’s law. Calculate the mole fraction of in water at 298 K under 760 mm Hg. (Given : for in at 298 K = mm Hg)- Q.212 marks(a) Name the disease caused by the deficiency of Vitamin A. (b) How will you confirm the presence of carbonyl group as an aldehydic group in glucose ?
Section C
3 marks each
- Q.223 marksCalculate emf of the following cell at 298 K : (Given : V, V, [log 10 = 1])
- Q.233 marks(a) Define order of a reaction. (b) The rate for the following reaction is given by : Rate = (i) How is the rate of reaction affected if we double the concentration of B ? (ii) Write the overall order of a reaction if ‘A’ is present in large excess.
- Q.243 marksThe rate of a particular reaction quadruples when the temperature increases from 300 K to 320 K. Calculate the energy of activation of the reaction assuming that it does not change with temperature. (Given : log 4 = , R = )
- Q.253 marks(a) Write the IUPAC name of the given complex : (b) Differentiate between a double salt and a complex. (c) Mention the type of isomerism exhibited by the following complex :
- Q.263 marks(a) A coordination compound is mixed with excess of solution, three moles of AgCl are precipitated per mole of the compound. Write the structural formula of the coordination compound. (b) Write the oxidation state and hybridisation of the central metal in the given complex : . [Atomic number : Cr = 24] (c) Why is colourless ?
- Q.273 marksHow do you convert the following ? (a) Benzene to m-Nitroacetophenone (b) Bromobenzene to 1-Phenylethanol (c) But-3-en-2-one to Prop-2-en-1-oic acid
- Q.28 (a)3 marks(i) Arrange the following compounds in increasing order of their acidic strengths : , , (ii) Why is more reactive than acetone towards reaction with HCN ? (iii) Complete the equation :
OR
Q.28 (b)3 marksAn organic compound with the molecular formula forms 2,4-DNP derivative, reduces Tollens’ reagent and undergoes Cannizzaro reaction. On vigorous oxidation it gives Benzene-1,2-dicarboxylic acid. Identify the compound and write the reactions of compound 2,4-DNP and when it undergoes Cannizzaro reaction.
Section D
- Ethers are prepared by the dehydration of alcohols in presence of protic acids at 413 K. Symmetrical and unsymmetrical ethers can also be prepared by Williamson synthesis. This reaction involves attack of an alkoxide ion on primary alkyl halide. If a tertiary alkyl halide is used, elimination reaction occurs and an alkene is formed, no ether is formed. C – O bond in ethers are cleaved under drastic conditions with excess of HI. When unsymmetrical ethers react with HI, the alkyl halide is formed from smaller alkyl group. If one of the alkyl group is tertiary, the alkyl halide is formed from the tertiary alkyl group because tertiary alkyl carbocation is more stable than the primary carbocation. Cleavage of alkyl aryl ethers takes place at the alkyl-oxygen bond due to more stable aryl-oxygen bond. The order of reactivity of hydrogen halides is HI > HBr > HCl. Aromatic ethers undergo electrophilic substitution reactions. The alkoxy group attached to the aromatic ring activates the ring towards electrophilic substitution and directs the incoming group to ortho- and para-positions.Q.29 (a)2 marksComplete the following equations : (i) anisole + (ii) anisole
- Q.29 (b) (i)1 markWrite the names of alkyl halide and sodium alkoxide used to prepare tert-butyl ethyl ether.
OR
Q.29 (b) (ii)1 markAnisole on reaction with HI gives phenol and and not methanol and iodobenzene. Justify the statement.- Q.29 (c)1 markWhy is C – O – C bond angle in ethers slightly greater than tetrahedral angle ?
- Electrochemistry is the study of the relationship between chemical energy and electrical energy. Many spontaneously occurring chemical reactions liberate electrical energy. In electrolysis, electrical energy is converted directly into chemical energy. The product of an electrolytic reaction depends on the nature of the material being electrolysed and the type of electrode used. Oxidising and reducing species present in the electrolytic cell and their standard electrode potential too, affect the products of electrolysis. Electrolysis plays an important role in most people’s daily lives, whether it is for the manufacturing of aluminium, electroplating of metals, or the synthesis of chemical compounds. Michael Faraday was the first scientist who proposed two laws to explain the quantitative aspects of electrolysis, popularly known as Faraday’s laws of electrolysis. Faraday’s laws of electrolysis provide a basis for mathematical analysis of the mass deposited at electrodes and the amount of charge passed through them. Faraday’s laws are fundamental in various applications, including electroplating, metal extraction, battery technology and chemical synthesis. These laws also help in environmental monitoring and in various chemistry experiments.Q.30 (a)2 marksPredict the products of electrolysis in each of the following : (i) An aqueous solution of with platinum electrodes. (ii) A concentrated solution of with platinum electrodes.
- Q.30 (b) (i)1 markHow much charge in faraday is required for the reduction of 1 mol of to Ag ?
OR
Q.30 (b) (ii)1 markState Faraday’s second law of electrolysis.- Q.30 (c)1 markThe following reactions occur at the anode during the electrolysis of aqueous sodium chloride solution : V (I) V (II) Which reaction is feasible at the anode and why ?
Section E
5 marks each
- Q.31 (a)5 marks(i) (I) Why do transition metals show variable oxidation states ? (II) Out of and which will be more paramagnetic and why ? [Atomic No. : Ti = 22, Mn = 25] (III) Which ion is the strongest oxidising agent in the options given below : , , Give reason. [Atomic No. : Cr = 24, V = 23, Mn = 25] (ii) Complete and balance the following equations : (I) (II)
OR
Q.31 (b)5 marks(i) What is meant by lanthanoid contraction ? (ii) Why do transition metals form coloured compounds ? (iii) Why are values for Mn and Zn more negative than expected ? (iv) Which is the most stable oxidation state of Cu and why ? (v) Why is in aqueous solution a good oxidising agent ?- Q.32 (a)5 marks(i) (I) Which of the following is more reactive towards reaction : 2-Bromo-2-methylbutane or 1-Bromopentane (II) What type of halide is present in the following compound : (III) Why is chloroform stored in dark coloured bottles ? (ii) Define the following terms : (I) Ambident Nucleophiles (II) Racemic mixture
OR
Q.32 (b)5 marks(i) Answer the following : (I) Which isomer of is most reactive towards reaction ? (II) Predict the alkene that would be formed by dehydrohalogenation of 1-Bromo-1-methylcyclohexane. (III) Although chlorine shows strong – I effect, yet it is ortho/para-directing in electrophilic aromatic substitution reactions. Why ? (ii) Write the major product in the following reactions : (I) (II) 4-nitrocumene , para +- Q.33 (a)5 marks(i) Calculate the freezing point of a solution when g of was dissolved in 250 g of water, assuming undergoes complete dissociation. (Given : Molar mass of = 184 g , for water = K kg ) (ii) Write two differences between ideal and non-ideal solutions.
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Q.33 (b)5 marks(i) A solution is prepared by dissolving g of potassium sulphate in 2 L of water at C. Assuming potassium sulphate is completely dissociated, determine its osmotic pressure. (Given : R = L atm , Molar mass of = 174 g ) (ii) What type of azeotrope will be formed by a solution of acetone and chloroform ? Give reason.