Maharashtra HSC Class 12 Chemistry February 2024 question paper
Maximum marks 70 · Time 3 hours
Try each question first, then open its model answer. Where the paper offers a choice, both questions are shown with OR between them.
Section A
1 mark each
- Select and write the correct answer for the following multiple choice type of questions :Q.1 (i)1 markThe spin only magnetic moment of cation is _____.
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- Q.1 (ii)1 markThe linkage present in Lactose is _____.
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- Q.1 (iii)1 markThe product of the following reaction is
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- Q.1 (iv)1 markThe pH of 0.001 M HCl solution is _____.
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- Q.1 (v)1 markThe correct structure of complex having IUPAC name sodium hexanitrocobaltate (III) is
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- Q.1 (vi)1 markThe number of particles present in Face Centred Cubic Unit Cell is/are _____.
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- Q.1 (vii)1 markThe monomer used in preparation of teflon is _____.
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- Q.1 (viii)1 markAmong the following vinylic halide is ______. (Option (c) is printed as a drawn structure — see the figure.)
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- Q.1 (ix)1 markThe product of hydrolysis of propyne in the presence of 1% and 40% is _____.
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- Q.1 (x)1 markIf unit of rate constant is , the order of reaction would be _____.
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- Answer the following questions :Q.2 (i)1 markWrite the name of metal nanoparticle used to remove E.coli bacteria from water.
- Q.2 (ii)1 markWrite the name of reduction product formed when ethyl cyanide is treated with sodium and alcohol.
- Q.2 (iii)1 markComplete the reaction :
- Q.2 (iv)1 markCalculate effective atomic number of ion.
- Q.2 (v)1 markThe compounds of ions are colourless due to ......
- Q.2 (vi)1 markWrite SI unit of molar conductivity.
- Q.2 (vii)1 markWrite the sign convention of work done during expansion of gas.
- Q.2 (viii)1 markWrite the condition of reverse osmosis.
Section B
2 marks each · attempt any 8
- Q.32 marksDerive an expression for maximum work obtainable during isothermal reversible expansion of an ideal gas from initial volume to final volume .
- Q.42 marksWhat are interhalogen compounds? Write the chemical reaction, when chlorine reacts with dry slaked lime.
- Q.52 marksWhat is nano material? Write the reaction involved in sol-gel process during hydrolysis.
- Q.62 marksWrite classification of proteins with an example.
- Q.72 marksCalculate the time required to deposit 2.4 g of Cu, when 2.03 A of current passed through solution. (At. mass of Cu = )
- Q.82 marksWhy amines are basic in nature? Among dimethylamine and diethylamine , which one is more basic?
- Q.92 marksExplain buffer action of sodium acetate-acetic acid buffer.
- Q.10 (a)2 marksWrite preparation of diethyl ether from ethyl bromide.
- Q.10 (b)Write preparation of ethyl cyanide from ethyl bromide.
- Q.112 marksHenry's constant for is at 25 °C. Calculate its solubility in water at 25 °C, if its partial pressure is 0.164 bar.
- Q.122 marksWrite the structure and name of monomer of (a) Nylon-6 (b) Natural rubber
- Q.132 marksDefine Lanthanide contraction. Write the balanced chemical equations when acidified reacts with .
- Q.142 marksDerive the relationship between molar mass, density of the substance and unit cell edge length.
Section C
3 marks each · attempt any 8
- Q.153 marksWhat is osmotic pressure? How will you determine molar mass of solute from osmotic pressure?
- Q.16 (a)3 marksWrite chemical reactions involved in : (a) Rosenmund reduction.
- Q.16 (b)Write chemical reactions involved in : (b) Gatterman Koch formylation.
- Q.16 (c)Write chemical reactions involved in : (c) Cannizzaro reaction of methanal.
- Q.173 marksCalculate the standard enthalpy of combustion of methane, if the standard enthalpy of formation of methane, carbon dioxide and water are , and respectively.
- Q.183 marksWhat is the action of following on ethyl bromide ? (a) silver nitrite (b) Mg in dry ether (c) alcoholic sodium hydroxide
- Q.193 marksFor the reaction . If [B] is doubled at constant [A], the rate of reaction doubled. If [A] is triple and [B] is doubled, the rate of reaction increases by a factor of 6. Calculate the rate law equation.
- Q.203 marksArrange the following in the increasing order of the property mentioned: (i) , , , (acidic strength) (ii) MF, MCl, MBr, MI (ionic character) (iii) HF, HCl, HBr, HI (thermal stability)
- Q.213 marksExplain Wolf-Kishner reduction reaction. Write preparation of propanone by using ethanoyl chloride and dimethyl cadmium.
- Q.223 marksWrite postulates of Werner theory of co-ordination complexes. Write the name of a hexadentate ligand.
- Q.233 marksDefine electrochemical series and write its two applications.
- Q.243 marksIdentify 'A', 'B' and 'C' in following chain reaction and rewrite the chemical reactions:
- Q.253 marksDefine acids and bases according to Bronsted-Lowry theory. Derive relationship between pH and pOH.
- Q.263 marksWrite the preparation of potassium dichromate from chromite ore.
Section D
4 marks each · attempt any 3
- Q.27 (i)4 marksConvert the following : (i) acetaldehyde to isopropyl alcohol.
- Q.27 (ii)Convert the following : (ii) cumene to phenol.
- Q.27 (iii)Convert the following : (iii) anisole to phenol.
- Q.27 (iv)Write two uses of neon.
- Q.28 (i)4 marksDefine : (i) Extensive and Intensive properties (ii) Isobaric and Adiabatic processes
- Q.28 (ii)What are enzymes?
- Q.28 (iii)Write the atomic numbers of transuranium elements.
- Q.29 (i)4 marksPredict the type of cubic lattice of a solid element having edge length of 400 pm and density is 6.25 g/ml (Atomic mass of element = 60)
- Q.29 (ii)Define : Nanoscience
- Q.29 (iii)Write chemical reaction for the preparation of polyacrylonitrile.
- Q.30 (i)4 marksDerive the relation between half life period and rate constant for first order reaction.
- Q.30 (ii)Write the net cell reaction during discharging of lead accumulator.
- Q.30 (iii)Draw the structure of peroxymonosulphuric acid.
- Q.31 (i)4 marksMention the number of unpaired electrons and geometry of following complexes : (i) (ii)
- Q.31 (ii)Convert the following : (a) Ethanenitrile into ethanal. (b) Cyclohexane into adipic acid.