Maharashtra HSC Class 12 Chemistry July 2024 question paper
Maximum marks 70 · Time 3 hours
Try each question first, then open its model answer. Where the paper offers a choice, both questions are shown with OR between them.
Section A
1 mark each
- Select and write the correct answer for the following multiple choice type of questions :Q.1 (i)1 markIntegrated rate law equation for a zero order reaction is
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- Q.1 (ii)1 markThe spin only magnetic moment of ion is ____.
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- Q.1 (iii)1 markThe relation between radius of sphere and edge length in simple cubic lattice is ____.
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- Q.1 (iv)1 markThe monomer used in the preparation of thermocol is ____.
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- Q.1 (v)1 markThe pH of 0.01 M solution of HCl is
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- Q.1 (vi)1 markWhich of the following -amino acids do not contain chiral centre?
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- Q.1 (vii)1 markAmong the following benzylic halide is ____. (The four options are drawn structures — see the figure.)
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- Q.1 (viii)1 markNeutral complex in the following is _____
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- Q.1 (ix)1 markThe reaction used to convert toluene to benzaldehyde is known as :
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- Q.1 (x)1 markA better reagent to convert primary alcohol to aldehyde is ____.
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- Answer the following questions :Q.2 (i)1 markWrite the name of insecticide which is effectively used instead of DDT.
- Q.2 (ii)1 markWrite the name of hydrocarbon formed when methyl magnesium iodide is treated with ammonia.
- Q.2 (iii)1 markCalculate the standard potential of the following cell at 25°C : ,
- Q.2 (iv)1 markWrite the IUPAC name of .
- Q.2 (v)1 markWrite the electronic configuration of ion. (Atomic number of zinc is 30).
- Q.2 (vi)1 markWrite the IUPAC name of amine formed when acetamide undergoes Hofmann bromamide degradation.
- Q.2 (vii)1 markWrite the condition for spontaneity of reaction with respect to entropy.
- Q.2 (viii)1 markWrite the relation between van't Hoff factor and degree of dissociation of an electrolyte.
Section B
2 marks each · attempt any 8
- Q.32 marksThe normal boiling point of ethyl acetate is 77.06 °C. A solution of 50 g of non-volatile solute in 150 g ethyl acetate boils at 82.60 °C. Calculate molar mass of solute.
- Q.42 marksDeduce first law of thermodynamics for : (a) isothermal process (b) isochoric process
- Q.52 marksComplete the following equations : (i) (ii)
- Q.62 marksDifferentiate between ionic crystals and covalent crystals.
- Q.72 marksWhat is the mass of Cu metal produced at the cathode during the passage of 5 ampere of current through solution for 100 minutes? [Molar mass of Cu = ]
- Q.82 marksDefine Buffer solution. Write the Henderson Hasselbalch equation for acidic buffer.
- Q.92 marksWrite two principles of green chemistry.
- Q.102 marksWrite the preparation of Nylon-6 polymer and its two uses.
- Q.112 marksDefine : (a) Pyrometallurgy. (b) Roasting.
- Q.122 marksWrite salient features of mechanism.
- Q.132 marksWhat is the denaturation of proteins? Write the name of only pyrimidine base in RNA.
- Q.142 marksWrite the reaction when ethylamine is treated with : (a) excess of ethyl bromide (b) Hinsberg's reagent
Section C
3 marks each · attempt any 8
- Q.153 marksConstruct a cell using standard hydrogen electrode and zinc electrode. Write its cell reaction and cell representation. Calculate cell potential of a cell with ions. Standard potential of a cell is V.
- Q.163 marksState Henry's Law. Write four conditions for ideal solutions.
- Q.173 marksWrite one example of each of ionisation, linkage and hydrated isomerism.
- Q.183 marksCalculate the standard enthalpy of the reaction : from the following reactions : (i) , (ii) , (iii) ,
- Q.193 marksDerive Ostwald's dilution law for weak acid. Obtain relation between solubility product and its solubility for .
- Q.203 marks60% of the reactant decomposes in 45 minutes in a first order reaction. Calculate the half life period of the reaction. Write the relation between half life period and initial concentration for zero order reaction.
- Q.213 marksWrite the conditions of colour of transition metal ion. Write the alloy used in Fischer Tropsch process.
- Q.223 marksExplain anomalous behaviour of oxygen with respect to atomicity, magnetic property and oxidation state.
- Q.23 (i)3 marksExplain cross Cannizzaro reaction.
- Q.23 (ii)Draw structure of Zwitter ion of sulfanilic acid.
- Q.243 marksIdentify A, B, C and rewrite the chemical reactions : , and
- Q.253 marksExplain optical isomerism in 2-chlorobutane.
- Q.263 marksWrite Clemmenson's reduction reaction of propanone. Write Fehling solution test for ethanal.
Section D
4 marks each · attempt any 3
- Q.27 (i)4 marksHow is dioxygen prepared in laboratory from ?
- Q.27 (ii)Write the chemical reaction to convert : (a) phenol to benzoquinone (b) phenol to cyclohexanol
- Q.28 (i)4 marksDefine : (a) Standard enthalpy of combustion. (b) Enthalpy of atomization.
- Q.28 (ii)Draw the structure of D-ribose sugar.
- Q.28 (iii)Write the uses of bronze alloy.
- Q.29 (i)4 marksDistinguish between order and molecularity of a reaction.
- Q.29 (ii)Write gases liberated at cathode and anode during electrolysis of aqueous NaCl solution.
- Q.29 (iii)Write two uses of neon.
- Q.30 (i)4 marksWhen gold crystallizes, it forms face-centred cubic cell. The unit cell edge length is 408 pm. Calculate the density of gold. [Molar mass of gold = ]
- Q.30 (ii)Which flower is an example of self cleaning?
- Q.314 marksExplain the formation of ion on the basis of Valence bond theory. Convert the following : (a) acetic acid to ethyl acetate (b) acetic acid to ethyl alcohol.