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Maharashtra HSC Class 12 Chemistry February 2026 question paper

Maximum marks 70 · Time 3 hours

Try each question first, then open its model answer. Where the paper offers a choice, both questions are shown with OR between them.

Section A

1 mark each

  1. Select and write the correct answer for the following multiple choice type of questions :
    Q.1 (i)1 mark
    The electrolyte used in H2−O2\mathrm{H_2 - O_2} fuel cell is _____.

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  2. Q.1 (ii)1 mark
    The oxidation state of bromine in HOBrO2\mathrm{HOBrO_2} oxoacid is _____.

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  3. Q.1 (iii)1 mark
    Acetonitrile may be prepared by heating the following reactants :

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  4. Q.1 (iv)1 mark
    The carbonated water is an example of _____.

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  5. Q.1 (v)1 mark
    The unit of rate constant is per second, the order of reaction is −-

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  6. Q.1 (vi)1 mark
    A system releases 10 kJ of heat and performs 15 kJ of work on the surrounding. Hence the change in internal energy is :

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  7. Q.1 (vii)1 mark
    The co-ordination complex ions [Co(NH3)5(NO2)]2+\mathrm{[Co(NH_3)_5(NO_2)]^{2+}} and [Co(NH3)5(ONO)]2+\mathrm{[Co(NH_3)_5(ONO)]^{2+}} are _____ of each other.

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  8. Q.1 (viii)1 mark
    The correct order for basic strength of amines and ammonia is _____.

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  9. Q.1 (ix)1 mark
    Amongst the following 3d-series elements, having highest value of first ionization enthalpy is _____.

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  10. Q.1 (x)1 mark
    The pOH of 0.01 M HCl solution is _____.

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  11. Answer the following questions :
    Q.2 (i)1 mark
    Write the name of product obtained, when selenium is treated with magnesium metal.
  12. Q.2 (ii)1 mark
    Write the SI unit of cell constant.
  13. Q.2 (iii)1 mark
    Write the name of radioactive element in lanthanide series.
  14. Q.2 (iv)1 mark
    Complete the following reaction : phenol + 3 H2→433KNickel ?+\ 3\,\mathrm{H_2} \xrightarrow[433\mathrm{K}]{\text{Nickel}}\ ?
  15. Q.2 (v)1 mark
    Write the IUPAC name of the structure shown : a benzene ring carrying a −CHO\mathrm{{-}CHO} group and, on the adjacent carbon, an −OH\mathrm{{-}OH} group.
  16. Q.2 (vi)1 mark
    Copper has fcc structure with edge length 495 pm. What is the radius of copper atom in pm?
  17. Q.2 (vii)1 mark
    Write the chemical name of Teflon.
  18. Q.2 (viii)1 mark
    Write the name of nanoparticle which acts as highly effective bacterial disinfectant.

Section B

2 marks each · attempt any 8

  1. Q.32 marks
    Define : (a) Isomorphism (b) Unit Cell
  2. Q.42 marks
    Explain the trends in the following properties of group 17 elements : (i) Atomic radii (ii) Electronegativity
  3. Q.52 marks
    Explain Homoleptic and Heteroleptic complexes with example.
  4. Q.6 (i)2 marks
    Write the reaction of bromine water on glucose.
  5. Q.6 (ii)
    Define – Enantiomers
  6. Q.7 (i)2 marks
    Write example of one dimensional nanostructure of size less than 100 nm.
  7. Q.7 (ii)
    Write the hydrolysis reaction of ethyl methyl ether.
  8. Q.82 marks
    Calculate the osmotic pressure of solution containing 0.822 gm of sucrose in 300 mL of water at 298 K. [Given : Molar mass of sucrose 342 g/mol, R=0.08205 dm3 atm K−1 mol−1R = 0.08205\ \mathrm{dm^{3}\ atm\ K^{-1}\ mol^{-1}}]
  9. Q.92 marks
    Write the mathematical equation of first law of thermodynamics for following processes : (a) Isochoric process (b) Adiabatic process
  10. Q.102 marks
    Write two similarities and two differences between lanthanoids and actinoids.
  11. Q.112 marks
    What is the action of following reagents on chlorobenzene? (i) conc. HNO3\mathrm{HNO_3} (ii) fuming H2SO4\mathrm{H_2SO_4}
  12. Q.122 marks
    Explain Cannizzaro reaction with suitable example.
  13. Q.132 marks
    A chemical reaction occurs in two steps : (i) NO2Cl(g)→slowNO2(g)+Cl(g)\mathrm{NO_2Cl_{(g)} \xrightarrow{slow} NO_{2(g)} + Cl_{(g)}} (ii) NO2Cl(g)+Cl(g)→fastNO2(g)+Cl2(g)\mathrm{NO_2Cl_{(g)} + Cl_{(g)} \xrightarrow{fast} NO_{2(g)} + Cl_{2(g)}} (a) Write down the rate law. (b) Identify the reaction intermediate.
  14. Q.142 marks
    The standard potential of electrode Cu2+\mathrm{Cu^{2+}} (0.02 M) ∣Cu(s)\mid \mathrm{Cu_{(s)}} is 0.337 volt. Calculate its potential in volt.

Section C

3 marks each · attempt any 8

  1. Q.15 (i)3 marks
    Derive relationship between relative lowering of vapour pressure and molar mass of non volatile solute.
  2. Q.15 (ii)
    Write statement of second law of thermodynamics.
  3. Q.16 (i)3 marks
    Convert, acetamide into ethyl amine.
  4. Q.16 (ii)
    Explain amphoteric nature of water.
  5. Q.17 (i)3 marks
    Convert the following : (i) Ethanol into sodium ethoxide. (ii) Phenol into o-phenol sulfonic acid.
  6. Q.17 (ii)
    Convert : Bromomethane into methoxyethane.
  7. Q.18 (i)3 marks
    What is peptide linkage?
  8. Q.18 (ii)
    Write general characteristics of interhalogen compounds.
  9. Q.19 (i)3 marks
    (i) Write observed electronic configuration of chromium (Z = 24). (ii) Calculate magnetic moment of Ti3+\mathrm{Ti^{3+}} by using spin only formula. (Z of Ti = 22)
  10. Q.19 (ii)
    Define Green chemistry.
  11. Q.20 (i)3 marks
    Write examples of coordination metal complexes in biology.
  12. Q.20 (ii)
    Calculate the work done in oxidation of 2 moles of SO2\mathrm{SO_2} at 298K, if SO2(g)+12O2(g)→SO3(g)\mathrm{SO_{2(g)} + \tfrac{1}{2}O_{2(g)} \rightarrow SO_{3(g)}} [Given : R=8.314 J/K/molR = 8.314\ \mathrm{J/K/mol}]
  13. Q.21 (i)3 marks
    Write the formula to measure % atom economy according to green chemistry.
  14. Q.21 (ii)
    Convert : (a) Benzene into benzaldehyde (b) Cyclohexene into adipic acid
  15. Q.22 (i)3 marks
    Write a reaction for preparation of Nylon-6.
  16. Q.22 (ii)
    The salt of Sc3+\mathrm{Sc^{3+}} ion is colourless and the salt of Mn3+\mathrm{Mn^{3+}} ion is coloured. Explain. [Z of Sc = 21 and Z of Mn = 25]
  17. Q.23 (i)3 marks
    Write the postulates of Werner's theory of co-ordination complexes.
  18. Q.23 (ii)
    What is the action of ethane – 1, 2 – diol on acetone?
  19. Q.24 (i)3 marks
    Write Tollen's reagent test for acetaldehyde.
  20. Q.24 (ii)
    Write the structure of zwitter ion of sulfanilic acid. Write the reaction between benzene diazonium chloride and phenol in alkaline medium.
  21. Q.25 (i)3 marks
    Define : Common ion effect.
  22. Q.25 (ii)
    Write preparation of glucose from starch.
  23. Q.26 (i)3 marks
    Draw the structure of 2, 4 – dinitrophenylhydrazone of acetaldehyde.
  24. Q.26 (ii)
    The rate of A+B→P\mathrm{A + B \rightarrow P} is 3.6×10−2 mol/dm3/s3.6 \times 10^{-2}\ \mathrm{mol/dm^{3}/s}. When [A] = 0.2 M and [B] = 0.1 M. Calculate the rate constant if reaction is first order in B and second order in A.

Section D

4 marks each · attempt any 3

  1. Q.27 (i)4 marks
    Define : Isotonic solution
  2. Q.27 (ii)
    Define : Molecularity of reaction
  3. Q.27 (iii)
    State and explain Hess's law of constant heat summation.
  4. Q.28 (i)4 marks
    Define : (a) Schottky defect (b) Ferromagnetism
  5. Q.28 (ii)
    (ii) Write the name of catalyst used in preparation of HDP. (iii) Draw structure of isoprene unit of natural rubber.
  6. Q.29 (i)4 marks
    Calculate effective atomic number of Fe2+\mathrm{Fe^{2+}} in [Fe(CN)6]4−\mathrm{[Fe(CN)_6]^{4-}} [Given : (Z = 26)]
  7. Q.29 (ii)
    (ii) Draw neat and labelled diagram of lead accumulator. (iii) Write two advantages of hydrogen – oxygen fuel cell.
  8. Q.30 (i)4 marks
    Convert, ethanoic acid to ethanol.
  9. Q.30 (ii)
    Explain the mechanism of alkaline hydrolysis of bromomethane.
  10. Q.31 (i)4 marks
    Acetic acid is 5% ionised in its decimolar solution. Calculate the dissociation constant of acetic acid.
  11. Q.31 (ii)
    Write chemical formula of epsom salt. Give two uses of H2SO4\mathrm{H_2SO_4}.