Maharashtra HSC Class 12 Chemistry February 2026 question paper
Maximum marks 70 · Time 3 hours
Try each question first, then open its model answer. Where the paper offers a choice, both questions are shown with OR between them.
Section A
1 mark each
- Select and write the correct answer for the following multiple choice type of questions :Q.1 (i)1 markThe electrolyte used in fuel cell is _____.
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- Q.1 (ii)1 markThe oxidation state of bromine in oxoacid is _____.
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- Q.1 (iii)1 markAcetonitrile may be prepared by heating the following reactants :
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- Q.1 (iv)1 markThe carbonated water is an example of _____.
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- Q.1 (v)1 markThe unit of rate constant is per second, the order of reaction is
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- Q.1 (vi)1 markA system releases 10 kJ of heat and performs 15 kJ of work on the surrounding. Hence the change in internal energy is :
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- Q.1 (vii)1 markThe co-ordination complex ions and are _____ of each other.
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- Q.1 (viii)1 markThe correct order for basic strength of amines and ammonia is _____.
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- Q.1 (ix)1 markAmongst the following 3d-series elements, having highest value of first ionization enthalpy is _____.
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- Q.1 (x)1 markThe pOH of 0.01 M HCl solution is _____.
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- Answer the following questions :Q.2 (i)1 markWrite the name of product obtained, when selenium is treated with magnesium metal.
- Q.2 (ii)1 markWrite the SI unit of cell constant.
- Q.2 (iii)1 markWrite the name of radioactive element in lanthanide series.
- Q.2 (iv)1 markComplete the following reaction : phenol
- Q.2 (v)1 markWrite the IUPAC name of the structure shown : a benzene ring carrying a group and, on the adjacent carbon, an group.
- Q.2 (vi)1 markCopper has fcc structure with edge length 495 pm. What is the radius of copper atom in pm?
- Q.2 (vii)1 markWrite the chemical name of Teflon.
- Q.2 (viii)1 markWrite the name of nanoparticle which acts as highly effective bacterial disinfectant.
Section B
2 marks each · attempt any 8
- Q.32 marksDefine : (a) Isomorphism (b) Unit Cell
- Q.42 marksExplain the trends in the following properties of group 17 elements : (i) Atomic radii (ii) Electronegativity
- Q.52 marksExplain Homoleptic and Heteroleptic complexes with example.
- Q.6 (i)2 marksWrite the reaction of bromine water on glucose.
- Q.6 (ii)Define – Enantiomers
- Q.7 (i)2 marksWrite example of one dimensional nanostructure of size less than 100 nm.
- Q.7 (ii)Write the hydrolysis reaction of ethyl methyl ether.
- Q.82 marksCalculate the osmotic pressure of solution containing 0.822 gm of sucrose in 300 mL of water at 298 K. [Given : Molar mass of sucrose 342 g/mol, ]
- Q.92 marksWrite the mathematical equation of first law of thermodynamics for following processes : (a) Isochoric process (b) Adiabatic process
- Q.102 marksWrite two similarities and two differences between lanthanoids and actinoids.
- Q.112 marksWhat is the action of following reagents on chlorobenzene? (i) conc. (ii) fuming
- Q.122 marksExplain Cannizzaro reaction with suitable example.
- Q.132 marksA chemical reaction occurs in two steps : (i) (ii) (a) Write down the rate law. (b) Identify the reaction intermediate.
- Q.142 marksThe standard potential of electrode (0.02 M) is 0.337 volt. Calculate its potential in volt.
Section C
3 marks each · attempt any 8
- Q.15 (i)3 marksDerive relationship between relative lowering of vapour pressure and molar mass of non volatile solute.
- Q.15 (ii)Write statement of second law of thermodynamics.
- Q.16 (i)3 marksConvert, acetamide into ethyl amine.
- Q.16 (ii)Explain amphoteric nature of water.
- Q.17 (i)3 marksConvert the following : (i) Ethanol into sodium ethoxide. (ii) Phenol into o-phenol sulfonic acid.
- Q.17 (ii)Convert : Bromomethane into methoxyethane.
- Q.18 (i)3 marksWhat is peptide linkage?
- Q.18 (ii)Write general characteristics of interhalogen compounds.
- Q.19 (i)3 marks(i) Write observed electronic configuration of chromium (Z = 24). (ii) Calculate magnetic moment of by using spin only formula. (Z of Ti = 22)
- Q.19 (ii)Define Green chemistry.
- Q.20 (i)3 marksWrite examples of coordination metal complexes in biology.
- Q.20 (ii)Calculate the work done in oxidation of 2 moles of at 298K, if [Given : ]
- Q.21 (i)3 marksWrite the formula to measure % atom economy according to green chemistry.
- Q.21 (ii)Convert : (a) Benzene into benzaldehyde (b) Cyclohexene into adipic acid
- Q.22 (i)3 marksWrite a reaction for preparation of Nylon-6.
- Q.22 (ii)The salt of ion is colourless and the salt of ion is coloured. Explain. [Z of Sc = 21 and Z of Mn = 25]
- Q.23 (i)3 marksWrite the postulates of Werner's theory of co-ordination complexes.
- Q.23 (ii)What is the action of ethane – 1, 2 – diol on acetone?
- Q.24 (i)3 marksWrite Tollen's reagent test for acetaldehyde.
- Q.24 (ii)Write the structure of zwitter ion of sulfanilic acid. Write the reaction between benzene diazonium chloride and phenol in alkaline medium.
- Q.25 (i)3 marksDefine : Common ion effect.
- Q.25 (ii)Write preparation of glucose from starch.
- Q.26 (i)3 marksDraw the structure of 2, 4 – dinitrophenylhydrazone of acetaldehyde.
- Q.26 (ii)The rate of is . When [A] = 0.2 M and [B] = 0.1 M. Calculate the rate constant if reaction is first order in B and second order in A.
Section D
4 marks each · attempt any 3
- Q.27 (i)4 marksDefine : Isotonic solution
- Q.27 (ii)Define : Molecularity of reaction
- Q.27 (iii)State and explain Hess's law of constant heat summation.
- Q.28 (i)4 marksDefine : (a) Schottky defect (b) Ferromagnetism
- Q.28 (ii)(ii) Write the name of catalyst used in preparation of HDP. (iii) Draw structure of isoprene unit of natural rubber.
- Q.29 (i)4 marksCalculate effective atomic number of in [Given : (Z = 26)]
- Q.29 (ii)(ii) Draw neat and labelled diagram of lead accumulator. (iii) Write two advantages of hydrogen – oxygen fuel cell.
- Q.30 (i)4 marksConvert, ethanoic acid to ethanol.
- Q.30 (ii)Explain the mechanism of alkaline hydrolysis of bromomethane.
- Q.31 (i)4 marksAcetic acid is 5% ionised in its decimolar solution. Calculate the dissociation constant of acetic acid.
- Q.31 (ii)Write chemical formula of epsom salt. Give two uses of .