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Acids, Bases and Salts formulas

1 formula, 10 reference tables and 17 common traps for CDS Chemistry Acids, Bases and Salts, grouped by subtopic.

Full notes with worked examples

Acids, Bases and Oxides

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Three definitions of an acid and a base

DefinitionAcidBaseExample
ArrheniusGives H⁺ in waterGives OH⁻ in waterHCl → H⁺ + Cl⁻; NaOH → Na⁺ + OH⁻
Brønsted–LowryProton donorProton acceptorHSO₄⁻ + H₂O → H₃O⁺ + SO₄²⁻: water takes the proton, so water is the baseQ
CDS 2017 (II): in this reaction water acts as a base.
LewisElectron-pair acceptorElectron-pair donorAcids: BF₃, AlCl₃, Co³⁺, Mg²⁺. Bases: NH₃, H₂O, OH⁻, F⁻Q
CDS 2025 (I): AlCl₃, Co³⁺ and BF₃ are all Lewis acids. Anything with a lone pair to give, such as NH₃ or OH⁻, is a Lewis base.
Electron-poor molecules (BF₃, AlCl₃) and small, highly charged metal ions are the usual Lewis acids.

Bases, alkalis and acids in water

StatementTrue or falseWhy
All bases are alkalisFalseOnly the bases that dissolve in water are alkalisQ
All alkalis dissolve in waterTrueDissolving is what makes a base an alkali
Alkalis are soapy, bitter and corrosiveTrueThe standard properties of an alkali
Adding water to an alkali gives out heatTrueDissolving NaOH or KOH is exothermicQ
An acid solution conducts because it holds H⁺ ionsTrueThe ions carry the chargeQ
Diluting an acid raises its H₃O⁺ concentrationFalseThe ions spread through more volume, so it fallsQ
To dilute, add water to the concentrated acidFalseAdd the acid to water, slowly

Acidic, basic, amphoteric and neutral oxides

Kind of oxideExamplesReacts with
BasicNa₂O, MgO, CaO, CuOAcids, giving a salt and waterQ
CDS 2026 (II): CuO in hydrochloric acid turns blue-green because copper(II) chloride forms.
AcidicCO₂, SO₂, P₄O₁₀Bases; in water it gives an acidQ
CDS 2018 (I): CO₂ is the gas that dissolves in water to give an acidic solution.
AmphotericZnO, Al₂O₃Both acids and basesQ
Both have been asked: ZnO (CDS 2020 II) and Al₂O₃ (CDS 2024 I).
NeutralCO, NO, N₂ONeither acids nor bases

Common traps

Water is not always neutral in a reaction

Water is amphiprotic: it is a base when it takes a proton from HSO₄⁻ or HCl, and an acid when it gives a proton to NH₃. Read which way the proton moves.

A Lewis acid ACCEPTS electrons

Lewis acids are electron-pair acceptors (BF₃, AlCl₃, metal ions). A set containing NH₃, H₂O, OH⁻ or F⁻ is not 'all Lewis acids', because each of those has a lone pair to donate.

Every alkali is a base, not the reverse

'All bases are alkalis' is false. Copper oxide, copper hydroxide and iron hydroxide are bases that do not dissolve in water, so they are not alkalis.

Dilution lowers concentration

Adding water does not create H₃O⁺ ions; it spreads them out. The number of ions per unit volume decreases on dilution.

Non-metal oxides are acidic

Non-metals give acidic oxides (CO₂, SO₂). Metals give basic oxides. A statement that non-metals dissolved in water 'produce basic oxides' or 'provide hydroxides' has it backwards.

Amphoteric is not the same as neutral

ZnO and Al₂O₃ react with acids and with bases. CO and NO react with neither. MgO, CaO and Na₂O are purely basic, and P₄O₁₀ is purely acidic.

The pH Scale and Indicators

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The pH scale

Definition of pH

pH=−log⁡10[H+]\text{pH} = -\log_{10}[\text{H}^{+}]
  • [H+][\text{H}^{+}]hydrogen-ion concentration in mol/L

pH of everyday substances

SubstanceApprox. pHNature
Gastric juice1.5–2Strongly acidic
Lemon juice2.2Acidic
Coffee5Weakly acidic
Pure water7Neutral
Blood7.4Slightly basic
Milk of magnesia10Mild base (antacid)Q
CDS 2022 (II): milk of magnesia is a mild base.
Sodium hydroxide solution13–14Strong base
CDS 2023 (I) order of increasing pH: lemon juice < coffee < blood < milk of magnesia.

Acid-base indicators

IndicatorIn acidIn base
Litmus (from lichen)RedBlueQ
CDS 2022 (I): litmus comes from a lichen.
PhenolphthaleinColourlessPink
Methyl orangeRedYellow
TurmericYellowReddish-brown
Universal indicatorRed to yellow as pH risesGreen at 7, then blue to violetQ
CDS 2021 (II): it is a mixture and shows many colours, but it is not used for titrations.

Common traps

pH 0 is the most acidic, not neutral

pH 0 means [H⁺] = 1 mol/L, the strong-acid end of the scale. Neutral is 7, not 0.

Liming soil RAISES its pH

Lime and dolomite are bases. Spreading them neutralises soil acidity, so the pH goes up. They do not add nitrogen or phosphorus.

Universal indicator is not a titration indicator

Universal indicator changes colour gradually across the whole scale, so it cannot mark a sharp end point. Titrations use one indicator such as phenolphthalein or methyl orange.

Acids in Food and the Body

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Acids in fruits, foods and household products

Source or useAcid
Lemon, orangeCitric acid
Vitamin C (amla, citrus)Ascorbic acidQ
CDS 2019 (II): vitamin C is ascorbic acid.
TomatoOxalic acidQ
Asked in CDS 2021 (I) and again in a 2026 (II) match-the-list.
Tamarind, grapesTartaric acidQ
CDS 2023 (II): 'oxalic acid is found in tamarind paste' was the incorrect statement.
Curd, sour milkLactic acid
Vinegar (5–8% in water), picklesAcetic acidQ
Mild antisepticBoric acidQ
CDS 2020 (I) matched boric acid to antiseptic, citric acid to preservative, Mg(OH)₂ to antacid, acetic acid to pickle.

Acids in stings and in the stomach

SourceAcidKind
Ant or bee stingMethanoic (formic) acidOrganicQ
Nettle leaf hairsMethanoic (formic) acidOrganicQ
Asked twice: CDS 2021 (II) and 2022 (II).
Stomach (gastric juice)Hydrochloric acidMineralQ
Asked twice: CDS 2020 (I) and 2022 (I). HCl is the only mineral acid among the usual options.
Tired musclesLactic acidOrganic

Common traps

Tomato is oxalic, tamarind is tartaric

The two are swapped often in the options. Oxalic acid is in tomato and spinach; tartaric acid is in tamarind and grapes.

Milk of magnesia is a base, not an acid

In a list of 'compound and use', magnesium hydroxide is the antacid: it is a mild base that neutralises excess stomach acid.

The stomach acid is hydrochloric, not sulphuric

Gastric juice contains hydrochloric acid. Sulphuric, nitric and formic acids are distractors; lactic and uric acids are organic, not mineral.

Nettle and ant share one acid

Both inject methanoic (formic) acid. Citric, tartaric and acetic acids are food acids and do not sting.

Common Salts and Carbonates

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Trade names and formulas of common salts

Trade nameChemical nameFormula
Baking soda (cooking soda)Sodium hydrogen carbonateNaHCO₃Q
CDS 2026 (II): cooking soda is NaHCO₃, not Na₂CO₃.
Washing sodaSodium carbonate decahydrateNa₂CO₃·10H₂O
Soda ashSodium carbonate (anhydrous)Na₂CO₃
Bleaching powderCalcium oxychlorideCaOCl₂
Plaster of ParisCalcium sulphate hemihydrateCaSO₄·½H₂O (2CaSO₄·H₂O)Q
CDS 2017 (II): its paste holds a fractured bone in place.
GypsumCalcium sulphate dihydrateCaSO₄·2H₂O
Slaked limeCalcium hydroxideCa(OH)₂
QuicklimeCalcium oxideCaO

Water of crystallisation

SaltFormulaWaters per formula unit
Copper sulphate (blue vitriol)CuSO₄·5H₂O5Q
CDS 2020 (I): copper sulphate crystals carry five water molecules.
Washing sodaNa₂CO₃·10H₂O10
GypsumCaSO₄·2H₂O2
Plaster of ParisCaSO₄·½H₂O½

Calcium carbonate and hydrogen carbonates

Material or useCompound
Marble, chalk, limestoneCalcium carbonate, CaCO₃Q
CDS 2026 (II): all three are forms of calcium carbonate.
PearlCalcium carbonate (nacre)Q
Soda-acid fire extinguisherSodium hydrogen carbonate with sulphuric acidQ
No solid hydrogen carbonateLithiumQ
CDS 2016 (II), HARD: LiHCO₃ exists only in solution.

Common traps

Baking soda and washing soda are different salts

Baking soda is NaHCO₃ (a hydrogen carbonate). Washing soda is Na₂CO₃·10H₂O (a carbonate with ten waters). Most wrong options swap these two.

Plaster of Paris has half a water, not two

Plaster of Paris is CaSO₄·½H₂O. Gypsum, which it turns into when it sets, is CaSO₄·2H₂O.

Blue vitriol has five waters

Copper sulphate crystals are CuSO₄·5H₂O. Options of 2, 4 or 6 are distractors.

The extinguisher uses the hydrogen carbonate

A soda-acid extinguisher uses sodium hydrogen carbonate (NaHCO₃), not sodium carbonate or sodium chloride.

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