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CDS Chemistry · Formula sheet

Metals and Non-Metals formulas

1 formula, 8 reference tables and 12 common traps for CDS Chemistry Metals and Non-Metals, grouped by subtopic.

Full notes with worked examples

Properties of Metals, Non-Metals and Metalloids

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Physical properties of metals

PropertyMeaningExample
Malleable and ductileBeaten into sheets; drawn into wiresGold, the best at bothQ
SonorousRings when struckSchool bellsQ
LustrousShiny surfacePolished silver
Good conductorCarries heat and electricitySilver best, then copperQ
CDS 2022 (II): silver and copper are the pair of very good heat conductors; lead and mercury are poor.

Non-metals that break the rules, and metalloids

ElementKindNotable property
IodineNon-metalLustrous (shiny)Q
CDS 2021 (I): iodine is the non-metal that is lustrous. Silicon and germanium are metalloids, not non-metals.
GraphiteNon-metal (carbon)Conducts electricity
DiamondNon-metal (carbon)Hardest natural substance
GermaniumMetalloidSemiconductorQ
SiliconMetalloidSemiconductor
Boron, arsenic, antimony, telluriumMetalloidsProperties of both metals and non-metals

Common traps

Mercury is neither malleable nor ductile

Mercury is a liquid at room temperature, so it cannot be beaten or drawn. Among Na, Au, Ce and Hg, only gold is clearly both malleable and ductile.

Silicon and germanium are metalloids

When a question asks for a non-metal that shines, silicon and germanium are wrong: they are metalloids. The answer is iodine.

The Reactivity Series

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Displacement: a more reactive metal pushes out a less reactive one

Displacement rule

A+BX→AX+Bonly if A is above BA + BX \rightarrow AX + B \quad \text{only if } A \text{ is above } B

The reactivity series and reactions with acids

MetalReaction with dilute HClReaction with oxygen
K, Na, CaViolentBurn readily
MgFast; gives H₂Burns with a white flameQ
CDS 2018 (II): magnesium with hydrochloric acid is the pair that gives hydrogen.
Al, Zn, FeSlower in that order; gives H₂Form oxides
PbVery slowForms an oxide
CuNo reaction (below H)Forms a black oxide when heated
Ag, AuNo reactionDo not form an oxideQ
CDS 2020 (II): silver is the metal that does not form an oxide with oxygen.
Order with dilute HCl, asked in CDS 2021 (II) and 2024 (I): Mg > Al > Zn > Fe.

Why reactive metals are stored under oil

SubstanceStored inWhy
Sodium, potassiumKeroseneReact violently with moisture and airQ
Asked in CDS 2021 (I) and 2026 (II).
LithiumParaffin waxFloats on oil, so oil cannot cover itQ
CDS 2024 (II), HARD: lithium is the one not stored under oil.
White phosphorusWaterCatches fire in air

Common traps

Nitric acid rarely gives hydrogen

Nitric acid is an oxidising acid. Zinc or copper with nitric acid gives oxides of nitrogen, not hydrogen. Use HCl or dilute H₂SO₄ for the hydrogen test.

Zinc sits above iron

The order is Mg > Zn > Fe. A statement giving 'Mg > Fe > Zn' is wrong.

Only the higher metal displaces

Copper is below lead, so Cu + PbCl₂ → CuCl₂ + Pb does not happen. Fe, Zn and Mg are all above copper, so each displaces copper from copper sulphate.

Sodium is under kerosene because of moisture, not evaporation

Sodium does not evaporate. It is kept under kerosene because it reacts violently with moisture and oxygen in the air.

Extraction of Metals and Alloys

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Ores and how metals are extracted

MetalMain oreExtracted by
AluminiumBauxite (Al₂O₃·2H₂O)Electrolysis of aluminaQ
SodiumRock salt (NaCl)Electrolysis of fused NaClQ
CDS 2025 (II): sodium is the metal won by electrolysis of its molten compound.
IronHaematite (Fe₂O₃)Reduction with coke in a blast furnace
ZincZinc blende (ZnS)Roasting, then reduction with carbon
MercuryCinnabar (HgS)Roasting
CopperCopper pyrites (CuFeS₂)Roasting and smelting

Common alloys and what they are made of

AlloyMade ofUsed for
SolderLead and tinJoining wires (low melting point)Q
BrassCopper and zincFittings, instruments
BronzeCopper and tinStatues, medals
Stainless steelIron, chromium, nickelUtensils; does not rust
DuraluminAluminium, copper, magnesium, manganeseAircraft bodies
AmalgamMercury with another metalDental fillings

Common traps

Roasting is for sulphides, calcination for carbonates

Roasting heats a sulphide ore in excess air. Calcination heats a carbonate ore in limited air. Smelting is the later reduction to the metal.

Electrolysis is for the most reactive metals

Sodium, potassium, calcium, magnesium and aluminium are won by electrolysis of a molten compound. Copper and tin are reduced by smelting, and gold occurs free, so none of them needs it.

Brass has zinc, bronze has tin

Both are copper alloys. Brass = copper + zinc; bronze = copper + tin. Solder is lead + tin, with no copper.

Corrosion and Its Prevention

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What each metal forms when it corrodes

MetalAttacked byProductColour
IronOxygen and waterFe₂O₃·xH₂O (rust)Reddish-brown
SilverSulphur / H₂S in airAg₂S (silver sulphide)BlackQ
Asked three times: CDS 2020 (I), 2020 (II) and 2021 (I).
CopperMoist carbon dioxideBasic copper carbonateGreenQ

Preventing corrosion, and anodising

MethodHow it protects
Painting, oilingKeeps air and moisture away
GalvanisingZinc coat corrodes first, protecting iron
Electroplating, tinningCoat of a less reactive metal
AnodisingAluminium as the anode; O₂ at the anode thickens the oxide filmQ
CDS 2023 (I), HARD: 'oxygen gas is evolved at the cathode' was the false statement.

Common traps

Silver does not form an oxide

Silver blackens because of sulphur, forming Ag₂S. Options naming silver oxide, silver carbonate or silver nitrate are wrong; so is the formula 'AgS'.

In anodising, oxygen forms at the anode

The aluminium is the anode, and oxygen is released there, where it combines with the metal to thicken the oxide film. Hydrogen comes off at the cathode.

Galvanising uses zinc, not tin

Galvanised iron is coated with zinc, which is more reactive than iron and corrodes first. A tin coat only shields the iron; once it is scratched, the iron rusts faster.

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