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CDS Chemistry · Matter and Its States

States of Matter and Evaporation

What the particle picture of matter says, the five states including plasma and the Bose-Einstein condensate, the two liquid elements, and what does and does not change the rate of evaporation.

Why this matters

Six CDS questions, five of them from 2019 and 2020. Two are on evaporation and turn on one idea: evaporation happens only at the surface.

Concept 1 of 2: Particles of matter and the five states

All matter is made of tiny particles that keep moving and pull on each other. How strongly they pull decides whether a substance is a solid, a liquid or a gas. At the extremes there are two more states: plasma, hot enough to strip electrons, and the Bose-Einstein condensate, cold enough that atoms act as one.

Definition

The particle picture and the states:

  • Particles of matter are always moving, so they intermix on their own (diffusion).
  • Particles attract each other; the force is strongest in solids, weaker in liquids, weakest in gases.
  • Solid, liquid, gas, then plasma (the fourth state, ionised gas) and the Bose-Einstein condensate (the fifth state, a gas of bosons cooled almost to absolute zero).
  • Only two elements are liquid at room temperature: bromine and mercury. Gallium and caesium melt just above it.
  • Hydrogen, nitrogen, oxygen and carbon dioxide are all gases at room temperature; CO₂ is triatomic, not diatomic.
StateHow particles behaveExample
SolidFixed places, strong attractionIce, iron
LiquidMove past each other, moderate attractionWater; bromine and mercury among elements
GasMove freely, weak attractionHydrogen, nitrogen, oxygen, carbon dioxide
Plasma (4th state)Ionised: free electrons and ionsLightning, the Sun
Bose-Einstein condensate (5th state)Atoms near absolute zero share one quantum stateMade in laboratoriesQ
Practice this conceptself-check · 4 quick reps

The same idea in a real exam question:

CDS · 2020 · CDS (II) 2020 — General Knowledge · Q98Moderate

Example 1 · Matter and Its States · States of Matter, Phase Changes and Diffusion

Identify the correct pair of elements among the following which are liquid at room temperature and standard pressure.

Fluorine is a gas, rubidium a solid

The liquid elements at room temperature are bromine and mercury. Fluorine is a gas, and thallium and rubidium are solids (rubidium melts at about 39 °C).

Plasma is the fourth state, BEC the fifth

The Bose-Einstein condensate is the fifth state of matter. Plasma is the fourth, and neither is a kind of solid.

Concept 2 of 2: What changes the rate of evaporation

Evaporation happens only at the surface, where the fastest particles escape into the air. So anything that gives particles more surface, more energy or more room in the air speeds it up. The total amount of liquid does not matter.

Definition

The factors:

  • Surface area up → faster.
  • Temperature up → faster.
  • Wind speed up → faster (it carries the vapour away).
  • Humidity up → slower (the air already holds vapour).
  • The mass of liquid does not affect the rate; it only decides how long evaporation lasts.
  • Evaporation cools the liquid left behind.
FactorEffect on rate
Larger surface areaIncreasesQ
Higher temperatureIncreases
Higher wind speedIncreases
Higher humidityDecreases
Mass of the liquidNo effectQ
Practice this concept3 quick reps

The same idea in a real exam question:

CDS · 2019 · CDS (II) 2019 — General Knowledge · Q75Moderate

Example 2 · Matter and Its States · States of Matter, Phase Changes and Diffusion

The rate of evaporation of liquid does not depend upon

More liquid does not mean faster evaporation

Evaporation is a surface process. The mass of liquid does not change its rate; surface area, temperature, wind and humidity do.

Humidity slows evaporation

Humid air already holds a lot of water vapour, so less can escape into it. An increase in humidity decreases the rate of evaporation.

Summary — formulas & gotchas at a glance

A revision cheat-sheet for the formulas and gotchas above. Click any concept name to jump back to its full explanation.

Reference tables (2)

Particles of matter and the five states5 rows
StateHow particles behaveExample
SolidFixed places, strong attractionIce, iron
LiquidMove past each other, moderate attractionWater; bromine and mercury among elements
GasMove freely, weak attractionHydrogen, nitrogen, oxygen, carbon dioxide
Plasma (4th state)Ionised: free electrons and ionsLightning, the Sun
Bose-Einstein condensate (5th state)Atoms near absolute zero share one quantum stateMade in laboratoriesQ
What changes the rate of evaporation5 rows
FactorEffect on rate
Larger surface areaIncreasesQ
Higher temperatureIncreases
Higher wind speedIncreases
Higher humidityDecreases
Mass of the liquidNo effectQ

Watch out for (4)

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