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CDS Chemistry · Metals and Non-Metals

Extraction of Metals and Alloys

Which ore gives which metal, roasting against calcination, why the most reactive metals need electrolysis, and what common alloys are made of.

Why this matters

Four CDS questions, all EASY or MODERATE: one ore, one process name, one extraction method and one alloy. Each is a single fact from the tables below.

Concept 1 of 2: Ores and how metals are extracted

How a metal is won depends on how reactive it is. Unreactive metals such as gold occur free. Middle metals such as iron and zinc are roasted or calcined to an oxide and then reduced with carbon. The most reactive metals hold on to their partners so tightly that only electricity can pull them apart.

Definition

The steps and the methods:

  • Roasting: heating a sulphide ore strongly in excess air, giving the oxide (2ZnS + 3O₂ → 2ZnO + 2SO₂).
  • Calcination: heating a carbonate ore in limited air, giving the oxide and CO₂.
  • Smelting / reduction: the oxide is reduced to the metal, usually with carbon.
  • Electrolysis of the molten compound for the most reactive metals (K, Na, Ca, Mg, Al): sodium from fused NaCl (Down's process), aluminium from alumina made from bauxite.
MetalMain oreExtracted by
AluminiumBauxite (Al₂O₃·2H₂O)Electrolysis of aluminaQ
SodiumRock salt (NaCl)Electrolysis of fused NaClQ
CDS 2025 (II): sodium is the metal won by electrolysis of its molten compound.
IronHaematite (Fe₂O₃)Reduction with coke in a blast furnace
ZincZinc blende (ZnS)Roasting, then reduction with carbon
MercuryCinnabar (HgS)Roasting
CopperCopper pyrites (CuFeS₂)Roasting and smelting
Practice this conceptself-check · 4 quick reps

The same idea in a real exam question:

CDS · 2021 · CDS (II) 2021 — General Knowledge · Q11Easy

Example 1 · Metals and Non-Metals · Extraction of Metals and Alloys

What is the name of the process that converts sulphide ores into oxides by heating strongly in the presence of excess air ?

Roasting is for sulphides, calcination for carbonates

Roasting heats a sulphide ore in excess air. Calcination heats a carbonate ore in limited air. Smelting is the later reduction to the metal.

Electrolysis is for the most reactive metals

Sodium, potassium, calcium, magnesium and aluminium are won by electrolysis of a molten compound. Copper and tin are reduced by smelting, and gold occurs free, so none of them needs it.

Concept 2 of 2: Common alloys and what they are made of

An alloy is a mixture of a metal with other metals or carbon, made to change a property: harder, lower melting, rust-proof. Each alloy has a fixed recipe, and CDS asks for it.

Definition

The alloys to know:

  • Solder: lead and tin; low melting point, used to join electrical wires.
  • Brass: copper and zinc. Bronze: copper and tin.
  • Steel: iron and a little carbon. Stainless steel: iron with chromium and nickel; it does not rust.
  • Duralumin: aluminium with copper, magnesium and manganese; light and strong, for aircraft.
  • An amalgam is any alloy of mercury.
AlloyMade ofUsed for
SolderLead and tinJoining wires (low melting point)Q
BrassCopper and zincFittings, instruments
BronzeCopper and tinStatues, medals
Stainless steelIron, chromium, nickelUtensils; does not rust
DuraluminAluminium, copper, magnesium, manganeseAircraft bodies
AmalgamMercury with another metalDental fillings
Practice this concept4 quick reps

The same idea in a real exam question:

CDS · 2021 · CDS (II) 2021 — General Knowledge · Q12Easy

Example 2 · Metals and Non-Metals · Extraction of Metals and Alloys

What are the constituents of alloy solder ?

Brass has zinc, bronze has tin

Both are copper alloys. Brass = copper + zinc; bronze = copper + tin. Solder is lead + tin, with no copper.

Summary — formulas & gotchas at a glance

A revision cheat-sheet for the formulas and gotchas above. Click any concept name to jump back to its full explanation.

Reference tables (2)

Ores and how metals are extracted6 rows
MetalMain oreExtracted by
AluminiumBauxite (Al₂O₃·2H₂O)Electrolysis of aluminaQ
SodiumRock salt (NaCl)Electrolysis of fused NaClQ
CDS 2025 (II): sodium is the metal won by electrolysis of its molten compound.
IronHaematite (Fe₂O₃)Reduction with coke in a blast furnace
ZincZinc blende (ZnS)Roasting, then reduction with carbon
MercuryCinnabar (HgS)Roasting
CopperCopper pyrites (CuFeS₂)Roasting and smelting
Common alloys and what they are made of6 rows
AlloyMade ofUsed for
SolderLead and tinJoining wires (low melting point)Q
BrassCopper and zincFittings, instruments
BronzeCopper and tinStatues, medals
Stainless steelIron, chromium, nickelUtensils; does not rust
DuraluminAluminium, copper, magnesium, manganeseAircraft bodies
AmalgamMercury with another metalDental fillings

Watch out for (3)

Test yourself on Metals and Non-Metals

10 past CDS questions from this chapter, timed at 10 minutes and marked the way the exam marks it. You see your score and every answer the moment you finish. Free to start.