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MHT-CET Chemistry · Teaching notes

Alkynes — MHT-CET Chemistry

Alkynes is one of the smallest chapters in MHT-CET Chemistry, eleven past-year questions, but nine of them are MODERATE. They test four things: where the halogen sits in a haloalkyne, how a triple bond is made and extended, which catalyst stops at the cis-alkene, and the cyanide route that adds a carbon. Every PYQ is tagged.

Every subtopic, worked example, formula and trap in one printable document — answers shown, ready to share.

Subtopic notes

Formula & revision sheet

0 formulas · 4 reference tables · 3 gotchas across all subtopics — the exam-eve cheat-sheet

Alkynes: Haloalkynes and Hybridisation

Reference tables (1)

Haloalkynes and the Hybridisation of Carbon5 rows
StructureClass
CH₃CH₂C≡C–XHaloalkyneQ
Chloroethyne, HC≡C–ClHaloalkyneQ
CH₃C≡C–CH₂XPropargylic halideQ
CH₃CH₂CH=CH–XHaloalkene (vinylic)
sp² carbons in hexa-1,4-diyneZeroQ

Watch out for (1)

Making Alkynes, Partial Hydrogenation, and Adding a Carbon

Reference tables (3)

Double Dehydrohalogenation and Acetylide Alkylation3 rows
SequenceProduct
1,2-Dibromoethane → alc. KOH → A → NaNH₂ → BB = ethyneQ
A → LiNH₂ → ethynyl lithium → C₂H₅Br → but-1-yneA = ethyneQ
HC≡CH → HBr → HBr → alc. KOH → NaNH₂ → DD = ethyneQ
Partial Hydrogenation to a cis-Alkene3 rows
ReagentProduct from R–C≡C–R
Pd–C / quinoline (Lindlar)cis-alkeneQ
Na / liquid NH₃trans-alkeneQ
Ni or Pt, excess H₂Alkane
Adding One Carbon with Cyanide2 rows
SequenceB
CH₃I + KCN → A; A + Na/C₂H₅OH → BCH₃CH₂NH₂Q
CH₃Br → KCN → A → Na/C₂H₅OH → BCH₃CH₂NH₂Q

Watch out for (2)

PYQ weightage by concept

4 concepts · 10 PYQs — where the marks actually sit, so you know what to drill first

Alkynes: Haloalkynes and Hybridisation3 PYQs · 30%
ConceptPYQsShare
Haloalkynes and the Hybridisation of Carbon330%
Making Alkynes, Partial Hydrogenation, and Adding a Carbon7 PYQs · 70%
ConceptPYQsShare
Double Dehydrohalogenation and Acetylide Alkylation330%
Partial Hydrogenation to a cis-Alkene220%
Adding One Carbon with Cyanide220%

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