NDA Chemistry · Acids, Bases and Salts

Common Acids — Names, Formulas, Sources and Uses

The everyday acids the NDA tests by source (the acid in a bee sting, in tomatoes, in vinegar), by use (etching glass, cleaning gold), and by formula (naming the oxy-acids of a halogen).

Why this matters

The largest subtopic — eight PYQs, almost all single-fact recall. The bank repeats a tight set: natural acids and their sources, mineral acids and their industrial uses, the oxy-acid naming pattern, and two acid-reaction facts (which reaction gives NO gas, and which carbonate does NOT give CO2). Learn the source table and the two reaction traps and this subtopic is free marks.

Concept 1 of 4

Natural acids and their sources

Intuition

Many foods and stings owe their sour taste or sting to a specific acid. The bank pairs each source to its acid — bee sting to formic acid, vinegar to acetic acid, curd to lactic acid. Learn the pairs both ways.

Definition

The source↔acid pairs the bank tests (these follow the NCERT natural-acid table):

  • Bee sting / Nettle sting / Ant stingmethanoic acid (formic acid, HCOOH).
  • Vinegarethanoic acid (acetic acid, CH3COOH).
  • Curdlactic acid.
  • Lemon / Orange (citrus)citric acid.
  • Tamarind / Grapestartaric acid.
  • Tomato / Spinachoxalic acid (the NCERT-listed answer for tomato).
SourceAcid present
Bee sting / Nettle sting / AntMethanoic acid (formic acid)
Bee, nettle and ant stings all inject methanoic (formic) acid — the cause of the burning pain.
VinegarEthanoic acid (acetic acid)
Curd / Sour milkLactic acid
Lemon, orange (citrus)Citric acid
Tamarind, grapesTartaric acid
Tomato, spinachOxalic acid
For 'acid in tomatoes', the NCERT-listed answer is oxalic acid (not citric, which is not offered in the bank's options).
Practice this conceptself-check · 5 quick reps

Try it yourself

A nettle leaf stings and leaves a burning sensation, and vinegar tastes sour. Name the acid responsible in each.

Practice — Level 1 (5 reps)

Quick reps to lock in the method. Try each, then check.

  1. 1.
    Which acid is released by a bee sting?
  2. 2.
    Which acid is present in vinegar?
  3. 3.
    Which acid is present in curd?
  4. 4.
    Which acid is associated with tomatoes (NCERT answer)?
  5. 5.
    Which acid is present in tamarind and grapes?

From the bank · past-year question

Example 1Acids, Bases and SaltsMODERATE
Bee sting leaves an acid which causes pain and irritation. The acid released is

[Q105 · Sep · 2022]

Bee and nettle stings = methanoic acid, not acetic

The acid in a bee or nettle sting is methanoic acid (formic acid, HCOOH), NOT ethanoic (acetic) acid. Ethanoic acid is the one in vinegar.

Tomato = oxalic acid (in the bank)

Biochemically tomatoes are richest in citric acid, but when citric acid is not an option the NCERT-expected answer for tomato is oxalic acid. Tamarind is the tartaric-acid one — do not swap them.

Concept 2 of 4

Mineral acids and their uses

Intuition

Each common mineral acid has a signature industrial job. Hydrofluoric acid etches glass; dilute nitric acid cleans gold and silver; sulphuric acid is the workhorse 'king of chemicals'. The bank asks 'principal use of X' or 'which acid does job Y'.

Definition

The use↔acid facts the bank tests:

  • Hydrofluoric acid (HF) — used to etch glass (it attacks silica, SiO2).
  • Dilute nitric acid (HNO3) — used by goldsmiths to clean gold and silver (it dissolves base-metal impurities without attacking the noble metal).
  • Sulphuric acid (H2SO4) — the 'king of chemicals'; used in fertilisers, car batteries and many industrial processes.
AcidPrincipal use
Hydrofluoric acid (HF)Etching glass (attacks SiO2)
HF is stored in plastic, not glass, because it dissolves glass — hence its use in etching.
Dilute nitric acid (HNO3)Cleaning gold and silver articles (goldsmith)
Goldsmiths use dilute HNO3 — it removes base-metal impurities but leaves the noble metal.
Sulphuric acid (H2SO4)Fertilisers, batteries, industry ('king of chemicals')
Hydrochloric acid (HCl)Cleaning metal surfaces (pickling), lab reagent
Practice this concept4 quick reps

Practice — Level 1 (4 reps)

Quick reps to lock in the method. Try each, then check.

  1. 1.
    What is the principal use of hydrofluoric acid?
  2. 2.
    Which acid does a goldsmith use to clean gold and silver articles?
  3. 3.
    Why is hydrofluoric acid not stored in glass bottles?
  4. 4.
    Which acid is called the 'king of chemicals'?

From the bank · past-year question

Example 2Acids, Bases and SaltsEASY
The principal use of hydrofluoric acid is

[Q82 · Sep · 2017]

Glass etching = hydrofluoric acid only

Only hydrofluoric acid (HF) etches glass, because it reacts with the silica (SiO2) in glass. The other mineral acids do not attack glass — that is why they can be stored in glass bottles.

Concept 3 of 4

Naming oxy-acids: hypo-, -ous, -ic, per-

Intuition

The oxy-acids of a halogen (or sulphur, etc.) differ only in how many oxygen atoms they carry. The prefix/suffix encodes the count: 'hypo...ous' is the fewest oxygens, '...ic' is more, 'per...ic' is the most. Bromine's series runs HOBr, HBrO2, HBrO3, HBrO4.

Definition

The bromine oxy-acid series (lowest to highest oxidation state of Br):

  • Hypobromous acid = HOBr (also written HBrO) — the 'hypo...ous' name marks the lowest oxygen count.
  • Bromous acid = HBrO2.
  • Bromic acid = HBrO3.
  • Perbromic acid = HBrO4 — 'per...ic' marks the highest oxygen count.

The same naming pattern applies to chlorine: hypochlorous (HOCl), chlorous (HClO2), chloric (HClO3), perchloric (HClO4).

NameFormulaOxygen count
Hypobromous acidHOBr (HBrO)Lowest (hypo...ous)
The 'hypo-' prefix marks the lowest oxidation state — hypobromous acid is HOBr, not HBr.
Bromous acidHBrO2Low (...ous)
Bromic acidHBrO3High (...ic)
Perbromic acidHBrO4Highest (per...ic)
Practice this concept4 quick reps

Practice — Level 1 (4 reps)

Quick reps to lock in the method. Try each, then check.

  1. 1.
    What is the formula of hypobromous acid?
  2. 2.
    What is the formula of perbromic acid?
  3. 3.
    What is the formula of hypochlorous acid?
  4. 4.
    Which has more oxygen: bromic acid or bromous acid?

From the bank · past-year question

Example 3Acids, Bases and SaltsMODERATE
Which one of the following is the chemical formula of Hypobromous acid ?

[Q56 · Apr · 2021]

Hypobromous acid is HOBr, not HBr

HBr is hydrobromic acid (no oxygen). Hypobromous acid is the oxy-acid HOBr — the 'hypo...ous' name always means an oxy-acid with the fewest oxygens, never the binary hydracid.

Concept 4 of 4

Acid reactions: nitric acid with metals, and carbonates with HCl

Intuition

Two reaction facts recur. First: dilute nitric acid with copper gives NO gas, but concentrated nitric acid gives NO2 instead. Second: every carbonate (limestone, chalk, marble — all CaCO3) fizzes CO2 with HCl, but quicklime (CaO) gives no CO2 because it has no carbonate.

Definition

The two reaction facts:

  • Dilute HNO3 + Cu → NO gas (nitric oxide); concentrated HNO3 + Cu → NO2 (nitrogen dioxide). The concentration decides the gas.
  • Carbonates + HCl → CO2 — limestone, chalk and marble are all CaCO3 and all fizz CO2.
  • Quick lime (CaO) + HCl → CaCl2 + H2O only, with no CO2, because CaO is an oxide, not a carbonate.

Dilute nitric acid with copper

3Cu+8HNO3(dil.)3Cu(NO3)2+2NO+4H2O3\,\text{Cu} + 8\,\text{HNO}_3(\text{dil.}) \rightarrow 3\,\text{Cu(NO}_3)_2 + 2\,\text{NO}\uparrow + 4\,\text{H}_2\text{O}

Worked example

Limestone, chalk, marble and quick lime are each treated with dilute HCl. Which one does NOT release carbon dioxide, and why?
  1. Limestone, chalk and marble are all calcium carbonate (CaCO3); a carbonate + HCl releases CO2.
  2. Quick lime is calcium oxide (CaO) — it has no carbonate group.
  3. CaO + 2HCl gives CaCl2 + H2O only, with no CO2.
Answer:Quick lime (CaO) — it is an oxide, not a carbonate, so it releases no CO2.
Practice this concept4 quick reps

Practice — Level 1 (4 reps)

Quick reps to lock in the method. Try each, then check.

  1. 1.
    What gas forms when dilute nitric acid reacts with copper?
  2. 2.
    What gas forms when concentrated nitric acid reacts with copper?
  3. 3.
    Which does NOT give CO2 with HCl: limestone, quick lime, chalk or marble?
  4. 4.
    What is the chemical name of limestone, chalk and marble?

From the bank · past-year question

Example 4Acids, Bases and SaltsMODERATE
Which one of the following will NOT produce carbon dioxide on reacting with an aqueous solution of hydrochloric acid?

[Q102 · Apr · 2019]

Quick lime has no carbonate, so no CO2

Limestone, chalk and marble are all CaCO3 and fizz CO2 with HCl. Quick lime is CaO — an oxide with no carbonate group — so it gives no CO2 (only CaCl2 and water).

Dilute HNO3 gives NO, concentrated gives NO2

With copper, dilute nitric acid produces NO, while concentrated nitric acid produces NO2. The concentration, not the metal, decides which oxide of nitrogen forms.

Summary — formulas & gotchas at a glance

A revision cheat-sheet for the formulas and gotchas above. Click any concept name to jump back to its full explanation.

Formulas (1)

  • Acid reactions: nitric acid with metals, and carbonates with HCl

    Dilute nitric acid with copper

    3Cu+8HNO3(dil.)3Cu(NO3)2+2NO+4H2O3\,\text{Cu} + 8\,\text{HNO}_3(\text{dil.}) \rightarrow 3\,\text{Cu(NO}_3)_2 + 2\,\text{NO}\uparrow + 4\,\text{H}_2\text{O}

Reference tables (3)

Natural acids and their sources6 rows
SourceAcid present
Bee sting / Nettle sting / AntMethanoic acid (formic acid)
Bee, nettle and ant stings all inject methanoic (formic) acid — the cause of the burning pain.
VinegarEthanoic acid (acetic acid)
Curd / Sour milkLactic acid
Lemon, orange (citrus)Citric acid
Tamarind, grapesTartaric acid
Tomato, spinachOxalic acid
For 'acid in tomatoes', the NCERT-listed answer is oxalic acid (not citric, which is not offered in the bank's options).
Mineral acids and their uses4 rows
AcidPrincipal use
Hydrofluoric acid (HF)Etching glass (attacks SiO2)
HF is stored in plastic, not glass, because it dissolves glass — hence its use in etching.
Dilute nitric acid (HNO3)Cleaning gold and silver articles (goldsmith)
Goldsmiths use dilute HNO3 — it removes base-metal impurities but leaves the noble metal.
Sulphuric acid (H2SO4)Fertilisers, batteries, industry ('king of chemicals')
Hydrochloric acid (HCl)Cleaning metal surfaces (pickling), lab reagent
Naming oxy-acids: hypo-, -ous, -ic, per-4 rows
NameFormulaOxygen count
Hypobromous acidHOBr (HBrO)Lowest (hypo...ous)
The 'hypo-' prefix marks the lowest oxidation state — hypobromous acid is HOBr, not HBr.
Bromous acidHBrO2Low (...ous)
Bromic acidHBrO3High (...ic)
Perbromic acidHBrO4Highest (per...ic)

Watch out for (6)

Mastery check — 4 interleaved questions

Try each one before clicking. Questions are interleaved across the concepts above, not grouped — interleaving sharpens transfer.

Example 1Acids, Bases and SaltsMODERATE
Stung by hairs of nettle leaves causes burning pain. This is due to the injection of

[Q58 · Apr · 2017]

Example 2Acids, Bases and SaltsMODERATE
Which one of the following acid is used by goldsmith for cleaning of gold and silver articles?

[Q89 · Sep · 2023]

Example 3Acids, Bases and SaltsMODERATE
Which one of the following reactions will give NO (nitric oxide) gas as one of the products?

[Q79 · Sep · 2018]

Example 4Acids, Bases and SaltsHARD
Which one of the following acids is predominantly found in tomatoes ?

[Q85 · Apr · 2021]

Drill every past-year question on this subtopic

8 questions from the bank — paginated, with cart and Word-export support.