NDA Chemistry · Acids, Bases and Salts

Salts and Common Compounds

The household name↔formula table for the common salts (washing soda, baking soda, bleaching powder, gypsum, brine), what is manufactured from common salt, and the properties of bleaching powder.

Why this matters

Seven PYQs of name↔formula↔use recall plus two trap questions ('which is NOT made from common salt', 'which statement about bleaching powder is wrong'). The match-list question recurs almost verbatim — learn the four-way table and it is a guaranteed mark.

Concept 1 of 3

Common names and formulas of salts

Intuition

Every Indian entrance exam keeps a short list of household salts with their 'kitchen' name, chemical name and formula. The bank tests any column — give the name, ask the formula, or run a four-way match-list. Learn all three columns for each.

Definition

The high-frequency name↔formula facts:

  • Washing soda = Na2CO3·10H2O (sodium carbonate decahydrate).
  • Baking soda = NaHCO3 (sodium bicarbonate).
  • Bleaching powder = CaOCl2 (calcium oxychloride, also written Ca(OCl)Cl).
  • Gypsum = CaSO4·2H2O.
  • Brine = an aqueous solution of NaCl (common salt in water).
  • Milk of magnesia = Mg(OH)2 (magnesium hydroxide) — an antacid.
  • Limestone / Chalk / Marble = CaCO3. (Lime water is Ca(OH)2 solution — NOT CaCO3.)
Common nameChemical name / formula
Washing sodaSodium carbonate, Na2CO3·10H2OQ
Baking sodaSodium bicarbonate, NaHCO3
Bleaching powderCalcium oxychloride, CaOCl2
GypsumCalcium sulphate dihydrate, CaSO4·2H2O
BrineAqueous solution of NaCl (common salt)
Brine is NaCl in water — not NaOH, NaHCO3 or Na2CO3.
Milk of magnesiaMagnesium hydroxide, Mg(OH)2
Lime waterCalcium hydroxide solution, Ca(OH)2
Lime water is Ca(OH)2 — it does NOT represent calcium carbonate. Limestone, chalk and marble are the CaCO3 ones.
Practice this conceptself-check · 6 quick reps

Try it yourself

Match each common name to its formula: Washing soda, Baking soda, Bleaching powder, Gypsum.

Practice — Level 1 (6 reps)

Quick reps to lock in the method. Try each, then check.

  1. 1.
    Chemical formula of washing soda?
  2. 2.
    Chemical formula of baking soda?
  3. 3.
    Chemical formula of bleaching powder?
  4. 4.
    Brine is an aqueous solution of which compound?
  5. 5.
    Milk of magnesia is which compound?
  6. 6.
    Which does NOT represent calcium carbonate: lime water, limestone, chalk or marble?

From the bank · past-year question

Example 1Acids, Bases and SaltsEASY
Brine is an aqueous solution of

[Q66 · Apr · 2018]

Lime water is Ca(OH)2, not CaCO3

Limestone, chalk and marble are all calcium carbonate (CaCO3). Lime water is the odd one out — it is a solution of calcium hydroxide, Ca(OH)2, and does NOT represent calcium carbonate.

Milk of magnesia = Mg(OH)2, not a carbonate

Milk of magnesia is magnesium hydroxide, Mg(OH)2 — an antacid base. It is not magnesium carbonate, bicarbonate or sulphate.

Concept 2 of 3

Compounds manufactured from common salt

Intuition

Common salt (NaCl) is the feedstock for a whole family of sodium and chlorine chemicals — washing soda, baking soda and bleaching powder all trace back to NaCl. The bank's trap is plaster of Paris, which comes from gypsum, not salt.

Definition

What is and is not made from NaCl:

  • From NaCl (via the Solvay or chlor-alkali process): washing soda (Na2CO3), baking soda (NaHCO3), bleaching powder, NaOH and chlorine.
  • NOT from NaCl: Plaster of Paris — it is made from gypsum (CaSO4·2H2O), a calcium compound, not a sodium one.
CompoundMade from common salt?Actual source
Washing soda (Na2CO3)YesNaCl, via Solvay process
Baking soda (NaHCO3)YesNaCl, via Solvay process
Bleaching powderYesChlorine (from NaCl) + slaked lime
Plaster of ParisNoGypsum (CaSO4·2H2O)
Plaster of Paris is the trap — it is made from gypsum, NOT from common salt.
Practice this concept3 quick reps

Practice — Level 1 (3 reps)

Quick reps to lock in the method. Try each, then check.

  1. 1.
    Which is NOT made from common salt: bleaching powder, baking soda, plaster of Paris or washing soda?
  2. 2.
    Name two compounds manufactured from common salt.
  3. 3.
    Plaster of Paris is made from which raw material?

From the bank · past-year question

Example 2Acids, Bases and SaltsMODERATE
Common salt (NaCl\text{NaCl}) is not used as a raw material for preparation of which one of the following compounds ?

[Q100 · Apr · 2021]

Plaster of Paris comes from gypsum, not salt

Washing soda, baking soda and bleaching powder all start from NaCl. Plaster of Paris is the exception — it is made by heating gypsum (CaSO4·2H2O), a calcium mineral, so it is NOT a product of common salt.

Concept 3 of 3

Bleaching powder: formula, uses and properties

Intuition

Bleaching powder (CaOCl2) is an oxidising agent that releases chlorine. Its jobs all rely on that: bleaching paper and textiles, and disinfecting water. The classic trap calls it a reducing agent — it is an OXIDISING agent.

Definition

Bleaching powder facts:

  • Formula CaOCl2 (calcium oxychloride); it is an oxidising agent, not a reducing agent.
  • Uses: bleaching wood pulp in paper factories, bleaching linen/cotton in textiles, and disinfecting drinking water.
  • Bleaching powder and DDT share one feature: both contain chlorine (bleaching powder is inorganic; DDT is organic).
Property / useDetail
Chemical natureOxidising agent (NOT reducing)
The bank's wrong statement is 'bleaching powder is a reducing agent' — it is an oxidising agent.
Use 1Bleaching wood pulp in paper factories
Use 2Bleaching linen and cotton in textiles
Use 3Disinfecting drinking water
Shared with DDTBoth contain chlorine
Bleaching powder and DDT both contain chlorine — bleaching powder is inorganic, DDT is organic.
Practice this concept4 quick reps

Practice — Level 1 (4 reps)

Quick reps to lock in the method. Try each, then check.

  1. 1.
    Is bleaching powder an oxidising agent or a reducing agent?
  2. 2.
    What feature do bleaching powder and DDT have in common?
  3. 3.
    Name one use of bleaching powder besides bleaching textiles.
  4. 4.
    Chemical formula of bleaching powder?

From the bank · past-year question

Example 3Acids, Bases and SaltsMODERATE
Which one of the following is NOT true for bleaching powder?

[Q68 · Apr · 2018]

Bleaching powder oxidises, it does not reduce

The statement 'bleaching powder is used as a reducing agent' is NOT true — bleaching powder is an oxidising agent (it releases chlorine). Its bleaching and disinfecting actions are oxidation.

Bleaching powder and DDT share chlorine, not calcium

The correct shared fact is that both contain chlorine. They do NOT both contain calcium (DDT has none), and they are not both organic (bleaching powder is inorganic) or both inorganic (DDT is organic).

Summary — formulas & gotchas at a glance

A revision cheat-sheet for the formulas and gotchas above. Click any concept name to jump back to its full explanation.

Reference tables (3)

Common names and formulas of salts7 rows
Common nameChemical name / formula
Washing sodaSodium carbonate, Na2CO3·10H2OQ
Baking sodaSodium bicarbonate, NaHCO3
Bleaching powderCalcium oxychloride, CaOCl2
GypsumCalcium sulphate dihydrate, CaSO4·2H2O
BrineAqueous solution of NaCl (common salt)
Brine is NaCl in water — not NaOH, NaHCO3 or Na2CO3.
Milk of magnesiaMagnesium hydroxide, Mg(OH)2
Lime waterCalcium hydroxide solution, Ca(OH)2
Lime water is Ca(OH)2 — it does NOT represent calcium carbonate. Limestone, chalk and marble are the CaCO3 ones.
Compounds manufactured from common salt4 rows
CompoundMade from common salt?Actual source
Washing soda (Na2CO3)YesNaCl, via Solvay process
Baking soda (NaHCO3)YesNaCl, via Solvay process
Bleaching powderYesChlorine (from NaCl) + slaked lime
Plaster of ParisNoGypsum (CaSO4·2H2O)
Plaster of Paris is the trap — it is made from gypsum, NOT from common salt.
Bleaching powder: formula, uses and properties5 rows
Property / useDetail
Chemical natureOxidising agent (NOT reducing)
The bank's wrong statement is 'bleaching powder is a reducing agent' — it is an oxidising agent.
Use 1Bleaching wood pulp in paper factories
Use 2Bleaching linen and cotton in textiles
Use 3Disinfecting drinking water
Shared with DDTBoth contain chlorine
Bleaching powder and DDT both contain chlorine — bleaching powder is inorganic, DDT is organic.

Watch out for (5)

Mastery check — 4 interleaved questions

Try each one before clicking. Questions are interleaved across the concepts above, not grouped — interleaving sharpens transfer.

Example 1Acids, Bases and SaltsEASY
Which one of the following does not\textbf{\text{not}} represent the salt, Calcium carbonate?

[Q73 · Sep · 2019]

Example 2Acids, Bases and SaltsMODERATE
Which one of the following statements regarding Bleaching powder and D.D.T. is correct?

[Q146 · Apr · 2020]

Example 3Acids, Bases and SaltsMODERATE
Match List I with List II and select the answer using the code given below the Lists : A. Washing soda | 1. CaOCl2\text{CaOCl}_2 B. Baking soda | 2. NaHCO3\text{NaHCO}_3 C. Bleaching powder | 3. Na2CO310H2O\text{Na}_2\text{CO}_3\cdot10\text{H}_2\text{O} D. Gypsum | 4. CaSO42H2O\text{CaSO}_4\cdot2\text{H}_2\text{O}

[Q81 · Apr · 2025]

Example 4Acids, Bases and SaltsEASY
Which one among the following is known as Milk of Magnesia ?

[Q104 · Apr · 2024]

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