PYQ Vault

NDA Chemistry · Carbon and Its Compounds

Common Carbon Compounds and Pigments

The everyday names, formulas and uses of carbonate and bicarbonate compounds, their waters of crystallization, and the pigments used in paints.

Why this matters

Ten PYQs of name↔formula↔use recall — washing soda, baking soda, dry ice, chalk — plus the water-of-crystallization counts and a 'which is not a pigment' trap. This is a memorise-the-table subtopic; the only catch is the hydration numbers.

Concept 1 of 3: Common names, formulas and uses

The bank keeps a short list of household carbon compounds and asks the formula, the common name, or the use — any of the three columns. Learn all three for each.

Definition

The high-frequency name↔formula↔use facts:

  • Washing soda = Na₂CO₃·10H₂O (sodium carbonate decahydrate).
  • Baking soda = NaHCO₃ (sodium bicarbonate).
  • Dry ice = solid CO₂ (sublimes directly to gas; used as a refrigerant).
  • Chalk and marble = CaCO₃ (calcium carbonate).
  • Vinegar = acetic acid (ethanoic acid, a dilute solution).
  • Silica gel = a desiccant (drying agent that absorbs moisture).
Common nameChemical name / formulaUse or identity
Washing sodaNa₂CO₃·10H₂OCleaning, water softening
Baking sodaNaHCO₃Baking, antacid
Dry iceSolid CO₂Refrigerant — sublimes, no liquid
Dry ice is solid carbon dioxide, NOT frozen water.
Chalk / MarbleCaCO₃Building, blackboard chalk
VinegarAcetic (ethanoic) acidFood preservative, flavouring
Silica gelSiO₂ (hydrated)Desiccant — absorbs moisture
Practice this concept5 quick reps

The same idea in a real exam question:

NDA · Apr 2018 · Q67Easy

Example 1 · Carbon and Its Compounds · Common Carbon Compounds and Pigments

Which one of the following is the chemical formula of Washing Soda?

Dry ice is CO₂, not ice

'Dry ice' is solid carbon dioxide, not frozen water. It sublimes (solid → gas) with no liquid stage, which is why it is 'dry'.

Concept 2 of 3: Water of crystallization

Water of crystallization is the fixed number of water molecules locked into a crystal's structure, written after a dot in the formula. The bank asks for the count for a few specific salts — memorise the numbers.

Definition

The hydration numbers the bank tests:

  • Blue vitriol (copper sulphate) = CuSO₄·5H₂O → 5.
  • Washing soda (sodium carbonate) = Na₂CO₃·10H₂O → 10.
  • Gypsum (calcium sulphate) = CaSO₄·2H₂O → 2.
  • Plaster of Paris = (CaSO₄)₂·H₂O (i.e. CaSO₄·½H₂O) → one water shared between two formula units of CaSO₄.
SaltFormulaWater molecules
Blue vitriol (copper sulphate)CuSO₄·5H₂O5
Washing sodaNa₂CO₃·10H₂O10
GypsumCaSO₄·2H₂O2
Plaster of Paris(CaSO₄)₂·H₂O1 (shared by two CaSO₄ units)
Plaster of Paris has ONE water of crystallization per TWO formula units of CaSO₄ — i.e. CaSO₄·½H₂O.
Practice this concept4 quick reps

The same idea in a real exam question:

NDA · Apr 2020 · Q144Moderate

Example 2 · Carbon and Its Compounds · Common Carbon Compounds and Pigments

Number of molecules of water of crystallization in copper sulphate, sodium carbonate and Gypsum are

Plaster of Paris = half a water per CaSO₄

Plaster of Paris is written (CaSO₄)₂·H₂O — one water molecule shared by two units of CaSO₄. It is not two waters; gypsum (CaSO₄·2H₂O) is the one with two.

Concept 3 of 3: Pigments and carbon black

Pigments are the insoluble solids that give paint its colour. The bank lists three white pigments and slips in one non-pigment (silica). Carbon black is the black pigment, made by burning hydrocarbons with too little air.

Definition

The pigment facts:

  • White pigments: zinc oxide, white lead, and chalk (CaCO₃).
  • Silica is NOT a pigment (it is a filler/abrasive).
  • Carbon black is a black pigment made by the incomplete combustion of hydrocarbons (burning in a limited supply of air).
SubstancePigment?Note
Zinc oxideYes (white)Common white pigment
White leadYes (white)Traditional white pigment
Chalk (CaCO₃)Yes (white)Cheap white pigment/filler
SilicaNoA filler/abrasive, not a pigment
Of zinc oxide, chalk, white lead and silica, the odd one out (NOT a pigment) is silica.
Carbon blackYes (black)Made by incomplete combustion of hydrocarbons
Practice this concept3 quick reps

The same idea in a real exam question:

NDA · Apr 2022 · Q88Moderate

Example 3 · Carbon and Its Compounds · Common Carbon Compounds and Pigments

Which one of the following is not\textbf{\text{not}} a pigment?

Summary — formulas & gotchas at a glance

A revision cheat-sheet for the formulas and gotchas above. Click any concept name to jump back to its full explanation.

Reference tables (3)

Common names, formulas and uses6 rows
Common nameChemical name / formulaUse or identity
Washing sodaNa₂CO₃·10H₂OCleaning, water softening
Baking sodaNaHCO₃Baking, antacid
Dry iceSolid CO₂Refrigerant — sublimes, no liquid
Dry ice is solid carbon dioxide, NOT frozen water.
Chalk / MarbleCaCO₃Building, blackboard chalk
VinegarAcetic (ethanoic) acidFood preservative, flavouring
Silica gelSiO₂ (hydrated)Desiccant — absorbs moisture
Water of crystallization4 rows
SaltFormulaWater molecules
Blue vitriol (copper sulphate)CuSO₄·5H₂O5
Washing sodaNa₂CO₃·10H₂O10
GypsumCaSO₄·2H₂O2
Plaster of Paris(CaSO₄)₂·H₂O1 (shared by two CaSO₄ units)
Plaster of Paris has ONE water of crystallization per TWO formula units of CaSO₄ — i.e. CaSO₄·½H₂O.
Pigments and carbon black5 rows
SubstancePigment?Note
Zinc oxideYes (white)Common white pigment
White leadYes (white)Traditional white pigment
Chalk (CaCO₃)Yes (white)Cheap white pigment/filler
SilicaNoA filler/abrasive, not a pigment
Of zinc oxide, chalk, white lead and silica, the odd one out (NOT a pigment) is silica.
Carbon blackYes (black)Made by incomplete combustion of hydrocarbons

Watch out for (2)

Test yourself on Carbon and Its Compounds

15 past NDA questions from this chapter, timed at 15 minutes and marked the way the exam marks it. You see your score and every answer the moment you finish. Free to start.