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NDA Chemistry · Carbon and Its Compounds

Functional Groups and Common Organic Compounds

A functional group is the reactive part of an organic molecule that decides its family and properties — alcohols, acids, esters — plus a handful of named compounds the bank tests on sight.

Why this matters

Nine PYQs of pure recall: which group gives a fruity smell (ester), which acid is in a nettle sting (formic), why carbon monoxide is poisonous, and a few common formulas. Learn the group→family→property table and the named facts; there is nothing to derive.

Concept 1 of 3: Functional groups and their families

The functional group is the small cluster of atoms that gives an organic molecule its character. Swap the group and you change the family — an -OH makes an alcohol, a -COOH makes an acid, a -COO- makes a sweet-smelling ester.

Definition

The families the bank tests, with their group and a giveaway property:

  • Alcohol — group -OH — e.g. ethanol; neutral to litmus (does not turn litmus red).
  • Carboxylic acid — group -COOH — e.g. acetic acid (ethanoic), formic acid (methanoic); sour, turns blue litmus red.
  • Ester — group -COO- — e.g. ethyl acetate; sweet, fruity smell (used in flavourings).
  • Aldehyde / ketone — groups -CHO / C=O — e.g. formaldehyde, acetone.
Functional groupsAlcoholROH–OH (e.g. ethanol)Carboxylic acidRCOO–H–COOH (e.g. acetic acid)EsterRCOOR′–COO– (sweet, fruity smell)AldehydeRCOH–CHO (e.g. formaldehyde)
FamilyFunctional groupExampleGiveaway property
Alcohol-OHEthanolNeutral to litmus
Ethanol does NOT turn litmus red — alcohols are neutral, unlike acids.
Carboxylic acid-COOHAcetic acid; formic (methanoic) acidSour; turns blue litmus red
Ester-COO-Ethyl acetateSweet, fruity smell
Aldehyde / Ketone-CHO / C=OFormaldehyde / AcetoneReactive carbonyl group
Practice this concept5 quick reps

The same idea in a real exam question:

NDA · Apr 2024 · Q101Easy

Example 1 · Carbon and Its Compounds · Functional Groups and Common Organic Compounds

Which one among the following compounds has a sweet and fruity smell ?

Alcohol is neutral, acid turns litmus red

Ethanol (an alcohol) is neutral to litmus. Only the -COOH acids (acetic, formic) turn blue litmus red. Options that say ethanol turns litmus red are wrong.

Concept 2 of 3: Carbon monoxide and other named facts

A cluster of one-off recall facts the bank repeats: why carbon monoxide kills, where litmus comes from, and that carbon tops the periodic table for sheer number of compounds.

Definition

The recurring named facts:

  • Carbon monoxide (CO) is poisonous because it binds haemoglobin (forming carboxyhaemoglobin), blocking oxygen transport. CO is also a neutral oxide.
  • Litmus (the acid–base indicator) is extracted from lichens.
  • Carbon forms the largest number of compounds of any element (catenation + tetra-valency).
FactDetail
CO is poisonous because…It binds haemoglobin (carboxyhaemoglobin), blocking O₂ transport
CO is dangerous because of its affinity for haemoglobin — not because it is acidic. CO is a neutral oxide.
Litmus is derived from…Lichens
Element forming the most compoundsCarbon
Practice this concept3 quick reps

The same idea in a real exam question:

NDA · Apr 2018 · Q88Easy

Example 2 · Carbon and Its Compounds · Functional Groups and Common Organic Compounds

The Poisonous nature of Carbon monoxide (CO\text{CO}) is due to its

Concept 3 of 3: Common compounds — formula and use

A short formula-recall block: baking soda's decomposition is why cakes rise, and gypsum's formula carries its two waters of crystallization.

Definition

Two high-frequency formulas:

  • Baking soda = NaHCO₃ (sodium bicarbonate). On heating above ~70°C it decomposes, releasing CO₂ gas that makes dough rise: 2NaHCO₃ → Na₂CO₃ + H₂O + CO₂.
  • Gypsum = CaSO₄·2H₂O (calcium sulphate dihydrate).
Common nameFormulaKey fact / use
Baking sodaNaHCO₃Decomposes on heating → CO₂ makes cakes rise
It is the released CO₂ — not water vapour — that raises the dough.
GypsumCaSO₄·2H₂OTwo waters of crystallization; used to make plaster of Paris
Practice this concept3 quick reps

The same idea in a real exam question:

NDA · Apr 2020 · Q143Moderate

Example 3 · Carbon and Its Compounds · Functional Groups and Common Organic Compounds

At nearly 70°C, sodium bicarbonate shows the property of gradually decomposing, which makes it usable in bakery products. The product of decomposition responsible for this use of sodium bicarbonate is

Summary — formulas & gotchas at a glance

A revision cheat-sheet for the formulas and gotchas above. Click any concept name to jump back to its full explanation.

Reference tables (3)

Functional groups and their families4 rows
FamilyFunctional groupExampleGiveaway property
Alcohol-OHEthanolNeutral to litmus
Ethanol does NOT turn litmus red — alcohols are neutral, unlike acids.
Carboxylic acid-COOHAcetic acid; formic (methanoic) acidSour; turns blue litmus red
Ester-COO-Ethyl acetateSweet, fruity smell
Aldehyde / Ketone-CHO / C=OFormaldehyde / AcetoneReactive carbonyl group
Carbon monoxide and other named facts3 rows
FactDetail
CO is poisonous because…It binds haemoglobin (carboxyhaemoglobin), blocking O₂ transport
CO is dangerous because of its affinity for haemoglobin — not because it is acidic. CO is a neutral oxide.
Litmus is derived from…Lichens
Element forming the most compoundsCarbon
Common compounds — formula and use2 rows
Common nameFormulaKey fact / use
Baking sodaNaHCO₃Decomposes on heating → CO₂ makes cakes rise
It is the released CO₂ — not water vapour — that raises the dough.
GypsumCaSO₄·2H₂OTwo waters of crystallization; used to make plaster of Paris

Watch out for (1)

Test yourself on Carbon and Its Compounds

15 past NDA questions from this chapter, timed at 15 minutes and marked the way the exam marks it. You see your score and every answer the moment you finish. Free to start.