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SSC CGL Chemistry · Acids, Bases and Salts

Acids, Bases and Their Reactions

Acetic acid and vinegar, baking soda in milk and fire extinguishers, what a metal and a dilute acid give, and the order of strength of the alkali hydroxides.

Why this matters

Eight questions in the bank: one from the 2023 shifts and seven from the 2024 shifts, seven of them EASY. Three ask the same reaction (a metal with dilute sulphuric acid), so the one general rule here answers them all.

Concept 1 of 2: Acids and bases at home

Two kitchen chemicals carry most of these questions: vinegar, an acid, and baking soda, a mild base.

Definition

Acids:

  • Ethanoic acid is acetic acid; vinegar is a 5 to 8% solution of it, used as a souring agent in pickles and sauces.

Baking soda (sodium bicarbonate, NaHCO3):

  • A white crystalline powder that neutralises both acids and bases; used as an antacid.
  • It gives off CO2 in soda-acid fire extinguishers.
  • A milkman adds a little to milk to raise its pH from about 6 to slightly alkaline, so the milk sours later.
SubstanceUse
VinegarAcetic acid; souring agentQ
Sodium bicarbonateFire extinguishers, antacidQ
Practise this conceptself-check · 3 quick reps

The same idea in a real exam question:

SSC CGL · 2024 · Tier I, 18 Sep 2024, Shift 1 · Q33Easy

Example 1 · Acids, Bases and Salts · Acids, Bases and Their Reactions

Why does the milkman add a very small amount of baking soda to fresh milk?

Alkaline means a higher pH

Making milk slightly alkaline means raising its pH. Options saying the soda reduces the pH to alkaline are wrong.

Concept 2 of 2: Metals with acids, and base strength

A reactive metal pushes hydrogen out of a dilute acid. The metal joins the acid's other part to make a salt, and hydrogen bubbles off.

Definition

The rule: metal + dilute acid gives salt + hydrogen.

  • Zinc + sulphuric acid gives zinc sulphate + hydrogen (it burns with a pop).
  • Magnesium + dilute sulphuric acid gives magnesium sulphate + hydrogen. Sulphur dioxide comes only from hot, concentrated acid.

Base strength: down Group 1 the hydroxides grow stronger: CsOH > KOH > NaOH > LiOH.

ReactionProducts
Zn + H2SO4ZnSO4 + H2Q
Mg + dilute H2SO4MgSO4 + H2Q
Strongest alkali hydroxideCsOHQ
Practise this conceptself-check · 3 quick reps

The same idea in a real exam question:

SSC CGL · 2024 · Tier I, 23 Sep 2024, Shift 2 · Q34Easy

Example 2 · Acids, Bases and Salts · Acids, Bases and Their Reactions

What is the gas evolved when zinc reacts with sulphuric acid?

Dilute acid gives hydrogen, not SO2

With dilute sulphuric acid, metals give hydrogen. Sulphur dioxide is the decoy; it needs hot, concentrated acid.

Summary — formulas & gotchas at a glance

A revision cheat-sheet for the formulas and gotchas above. Click any concept name to jump back to its full explanation.

Reference tables (2)

Acids and bases at home2 rows
SubstanceUse
VinegarAcetic acid; souring agentQ
Sodium bicarbonateFire extinguishers, antacidQ
Metals with acids, and base strength3 rows
ReactionProducts
Zn + H2SO4ZnSO4 + H2Q
Mg + dilute H2SO4MgSO4 + H2Q
Strongest alkali hydroxideCsOHQ

Watch out for (2)

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