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SSC CGL Chemistry · Atomic Structure and Periodic Classification

The Periodic Table

Newlands' octaves and Mendeleev's table with their years and predictions, the group names and numbers, the blocks, and how atomic size changes across the table.

Why this matters

Twenty-one questions in the bank: 13 from the 2023 shifts and eight from the 2024 shifts, and none from the 2025 shifts. They ask a year, a group number or a family name, so the two tables here are the whole page.

Concept 1 of 2: Newlands and Mendeleev

Two early tables ordered the elements by atomic mass. Newlands saw a repeat every eighth element; Mendeleev left gaps and predicted what would fill them.

Definition

Newlands' Law of Octaves (1865):

  • The 56 known elements in order of atomic mass, from hydrogen (the lightest) to thorium (the 56th).
  • Every eighth element resembles the first, like notes of music: lithium and sodium match.
  • A flaw: cobalt and nickel sat under 'Do' with the halogens.

Mendeleev's table (1869):

  • 63 elements by atomic weight, with gaps for undiscovered ones.
  • Eka-aluminium became gallium (predicted mass 68); eka-silicon became germanium (72); eka-boron became scandium (44).
PointFact
Law of OctavesNewlands, 1865Q
Octaves ran fromHydrogen to thorium, 56 elementsQ
Lithium matchesSodiumQ
Co and Ni placed underDo, with the halogensQ
Eka-aluminiumGallium, mass 68Q
Eka-siliconGermaniumQ
Practise this conceptself-check · 3 quick reps

The same idea in a real exam question:

SSC CGL · 2023 · Tier I, 27 Jul 2023, Shift 2 · Q29Easy

Example 1 · Atomic Structure and Periodic Classification · The Periodic Table

When did Dmitri Mendeleev invent the periodic table, ordering the symbols of the chemical elements according to their atomic weights?

Hydrogen is the lightest, not the heaviest

Newlands began with hydrogen, the element of lowest atomic mass. A statement calling it the highest is the false one.

Concept 2 of 2: Groups, periods, blocks and trends

Each column is a family with a name; each row ends with a noble gas. A group number gives the valence electrons and a period number gives the shells, so the atomic number follows.

Definition

Families:

  • Group 1: alkali metals, highly electropositive (sodium). Group 2: alkaline earth metals (Mg, Ca, Sr, Ba, Ra).
  • Group 16: chalcogens. Group 17: halogens (F, Cl, Br, I). Group 18: noble gases (He, Xe).
  • Groups 3 to 12: transition elements, the d-block. Lanthanides: the rare earth elements (f-block).

Rows and trends:

  • Every period ends in a noble gas: period 5 ends at xenon. Period 6 holds tungsten, platinum; silicon is period 3.
  • Atomic size increases down a group (a shell is added each step). Atomic radius is measured in picometres.
  • Fluorine has electronegativity 4.0 on Pauling's scale, the highest.
  • Period 2, group 17 means shells 2, 7: atomic number 9.
GroupName
1Alkali metals
2Alkaline earth metalsQ
16ChalcogensQ
17HalogensQ
18Noble gases
3 to 12Transition elements, d-blockQ
Practise this conceptself-check · 3 quick reps

The same idea in a real exam question:

SSC CGL · 2023 · Tier I, 25 Jul 2023, Shift 1 · Q29Easy

Example 2 · Atomic Structure and Periodic Classification · The Periodic Table

Match the columns.
Column-A (Common name)Column-B (Group number in the Modern Periodic Table)
i. Alkali metalsa. 18
ii. Alkaline earth metalsb. 17
iii. Halogensc. 2
iv. Noble gasesd. 1

Lanthanides are f-block

The lanthanides are f-block rare earths, not d-block. The d-block is Groups 3 to 12.

Summary — formulas & gotchas at a glance

A revision cheat-sheet for the formulas and gotchas above. Click any concept name to jump back to its full explanation.

Reference tables (2)

Newlands and Mendeleev6 rows
PointFact
Law of OctavesNewlands, 1865Q
Octaves ran fromHydrogen to thorium, 56 elementsQ
Lithium matchesSodiumQ
Co and Ni placed underDo, with the halogensQ
Eka-aluminiumGallium, mass 68Q
Eka-siliconGermaniumQ
Groups, periods, blocks and trends6 rows
GroupName
1Alkali metals
2Alkaline earth metalsQ
16ChalcogensQ
17HalogensQ
18Noble gases
3 to 12Transition elements, d-blockQ

Watch out for (2)

Test yourself on Atomic Structure and Periodic Classification

15 past SSC CGL questions from this chapter, timed at 9 minutes and marked the way the exam marks it. You see your score and every answer the moment you finish. Free to start.