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NDA Chemistry · Formula sheet

Acids, Bases and Salts formulas

2 formulas, 13 reference tables and 21 common traps for NDA Chemistry Acids, Bases and Salts, grouped by subtopic.

Full notes with worked examples

Acid-Base Theory, Oxides and Electrolytes

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Classification of oxides: acidic, basic, neutral and amphoteric

TypeReacts withExamples
Acidic oxideBases (forms a salt)CO2, SO2, NO2
Basic oxideAcids (forms a salt)Na2O, MgO, CaO
Neutral oxideNeither acids nor basesCO, N2O, NO, H2O
CO (carbon monoxide) is the neutral oxide the bank loves — CO2 in contrast is acidic.
Amphoteric oxideBoth acids and basesAl2O3, ZnO
Non-metal oxides tend to be acidic; metal oxides tend to be basic; CO/N2O/NO are neutral; Al2O3/ZnO are amphoteric.

Electrolytes and electrical conductivity of solutions

Substance in waterConducts?Reason
NaOH (sodium hydroxide)Yes (basic solution)Strong electrolyte — gives Na+ and OH-
NaCl, CuSO4 (salts)YesIonise fully into free ions
HCl (strong acid)YesIonises fully into H+ and Cl-
CH3COOH (acetic acid)WeaklyWeak electrolyte — partial ionisation
SugarNoNon-electrolyte — dissolves as whole molecules, no ions
Sugar is the classic non-conducting solution — it is covalent and produces no ions.
CH3OH (methanol)NoNon-electrolyte — covalent, no ions

The first mineral acid discovered

Mineral acidFormulaNote
Nitric acidHNO3The first mineral acid discovered
Nitric acid is the bank's answer for 'first mineral acid discovered'.
Hydrochloric acidHClMineral acid — discovered later
Sulphuric acidH2SO4'King of chemicals', dibasic
Phosphoric acidH3PO4Tribasic mineral acid

Common traps

Match the definition to the right concept

'Acids give H+ and bases give OH- in water' is the Arrhenius concept, not Bronsted-Lowry. Bronsted-Lowry is the proton-transfer (donor/acceptor) one; Lewis is the electron-pair one.

NH3 is a base, not an acid

In a 'how many are Lewis acids?' list, NH3 is the base — its nitrogen lone pair is donated. AlCl3, BF3 and FeCl3 are the Lewis acids (all electron-pair acceptors).

Tribasic = phosphoric acid

Among HCl, HNO3, H2SO4 and H3PO4, the tribasic one is phosphoric acid (H3PO4) — three replaceable H+. HCl and HNO3 are monobasic; H2SO4 is dibasic.

CO is neutral, CO2 is acidic

Carbon monoxide (CO) is a neutral oxide — it forms no salt with acids or bases. Do not confuse it with CO2, which is acidic (it forms carbonic acid / carbonates).

Sugar dissolves but does not ionise

Sugar dissolves freely in water, but it dissolves as neutral molecules, not ions — so its solution does not conduct electricity. Salts, strong acids and strong bases all produce ions and DO conduct.

Common Acids — Names, Formulas, Sources and Uses

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Acid reactions: nitric acid with metals, and carbonates with HCl

Dilute nitric acid with copper

3 Cu+8 HNO3(dil.)→3 Cu(NO3)2+2 NO↑+4 H2O3\,\text{Cu} + 8\,\text{HNO}_3(\text{dil.}) \rightarrow 3\,\text{Cu(NO}_3)_2 + 2\,\text{NO}\uparrow + 4\,\text{H}_2\text{O}

Natural acids and their sources

SourceAcid present
Bee sting / Nettle sting / AntMethanoic acid (formic acid)
Bee, nettle and ant stings all inject methanoic (formic) acid — the cause of the burning pain.
VinegarEthanoic acid (acetic acid)
Curd / Sour milkLactic acid
Lemon, orange (citrus)Citric acid
Tamarind, grapesTartaric acid
Tomato, spinachOxalic acid
For 'acid in tomatoes', the NCERT-listed answer is oxalic acid (not citric, which is not offered in the bank's options).

Mineral acids and their uses

AcidPrincipal use
Hydrofluoric acid (HF)Etching glass (attacks SiO2)
HF is stored in plastic, not glass, because it dissolves glass — hence its use in etching.
Dilute nitric acid (HNO3)Cleaning gold and silver articles (goldsmith)
Goldsmiths use dilute HNO3 — it removes base-metal impurities but leaves the noble metal.
Sulphuric acid (H2SO4)Fertilisers, batteries, industry ('king of chemicals')
Hydrochloric acid (HCl)Cleaning metal surfaces (pickling), lab reagent

Naming oxy-acids: hypo-, -ous, -ic, per-

NameFormulaOxygen count
Hypobromous acidHOBr (HBrO)Lowest (hypo...ous)
The 'hypo-' prefix marks the lowest oxidation state — hypobromous acid is HOBr, not HBr.
Bromous acidHBrO2Low (...ous)
Bromic acidHBrO3High (...ic)
Perbromic acidHBrO4Highest (per...ic)

Common traps

Bee and nettle stings = methanoic acid, not acetic

The acid in a bee or nettle sting is methanoic acid (formic acid, HCOOH), NOT ethanoic (acetic) acid. Ethanoic acid is the one in vinegar.

Tomato = oxalic acid (in the bank)

Biochemically tomatoes are richest in citric acid, but when citric acid is not an option the NCERT-expected answer for tomato is oxalic acid. Tamarind is the tartaric-acid one — do not swap them.

Glass etching = hydrofluoric acid only

Only hydrofluoric acid (HF) etches glass, because it reacts with the silica (SiO2) in glass. The other mineral acids do not attack glass — that is why they can be stored in glass bottles.

Hypobromous acid is HOBr, not HBr

HBr is hydrobromic acid (no oxygen). Hypobromous acid is the oxy-acid HOBr — the 'hypo...ous' name always means an oxy-acid with the fewest oxygens, never the binary hydracid.

Quick lime has no carbonate, so no CO2

Limestone, chalk and marble are all CaCO3 and fizz CO2 with HCl. Quick lime is CaO — an oxide with no carbonate group — so it gives no CO2 (only CaCl2 and water).

Dilute HNO3 gives NO, concentrated gives NO2

With copper, dilute nitric acid produces NO, while concentrated nitric acid produces NO2. The concentration, not the metal, decides which oxide of nitrogen forms.

The pH Scale and Common Substances

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What the pH scale measures

Definition of pH

pH=−log⁡10[H+]\text{pH} = -\log_{10}[\text{H}^{+}]
  • [H+][\text{H}^{+}]hydrogen-ion concentration (mol/L)

pH values of common substances

SubstanceApprox. pHNature
Gastric juice1.5–2Strongly acidic — highest H+
Gastric juice has the lowest pH and therefore the highest H+ concentration of the common options.
Lemon juice2–3Acidic
Pure water7Neutral
Human body / blood7.0–7.8Slightly basic (narrow range)
The human body operates in the pH range 7.0–7.8 — the bank's answer.
Milk of magnesia10Basic (antacid)
Milk of magnesia (magnesium hydroxide) has pH about 10.
Sodium hydroxide solution13–14Strongly basic
Acid rainbelow 5.6Acidic — rain turns acidic below pH 5.6
For rain to be called 'acid rain', its pH must fall below 5.6.

Indicators and the acid-base nature of household items

Item / indicatorBehaviour
Turmeric stain + soap then waterYellow → reddish-brown → yellow
Turmeric goes reddish-brown in alkaline soap and back to yellow when the soap is washed away.
ToothpasteBasic (neutralises mouth acid)
FeCl3 solutionpH < 7 (acidic, by hydrolysis)
FeCl3 = strong-acid + weak-base salt, so it hydrolyses to an acidic solution (pH < 7).
NaCl, KCl solutionpH ≈ 7 (neutral)
NaOH solutionBasic (pH > 7)

Common traps

Higher H+ means LOWER pH

The statement 'the higher the hydrogen-ion concentration, the higher its pH' is NOT correct — it is the inverse. More H+ means a lower pH and a more acidic solution.

Acid rain threshold is pH 5.6, not 7

Normal rain is already slightly acidic (about pH 5.6) from dissolved CO2. Rain is only called acid rain when its pH falls BELOW 5.6 — not below 7.

FeCl3 is acidic, not neutral

FeCl3 looks like a simple chloride salt but its solution is acidic (pH < 7) — it is the salt of strong acid HCl and weak base Fe(OH)3, so it hydrolyses. NaCl and KCl, in contrast, are neutral.

Salts and Common Compounds

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Common names and formulas of salts

Common nameChemical name / formula
Washing sodaSodium carbonate, Na2CO3·10H2OQ
Baking sodaSodium bicarbonate, NaHCO3
Bleaching powderCalcium oxychloride, CaOCl2
GypsumCalcium sulphate dihydrate, CaSO4·2H2O
BrineAqueous solution of NaCl (common salt)
Brine is NaCl in water — not NaOH, NaHCO3 or Na2CO3.
Milk of magnesiaMagnesium hydroxide, Mg(OH)2
Lime waterCalcium hydroxide solution, Ca(OH)2
Lime water is Ca(OH)2 — it does NOT represent calcium carbonate. Limestone, chalk and marble are the CaCO3 ones.

Compounds manufactured from common salt

CompoundMade from common salt?Actual source
Washing soda (Na2CO3)YesNaCl, via Solvay process
Baking soda (NaHCO3)YesNaCl, via Solvay process
Bleaching powderYesChlorine (from NaCl) + slaked lime
Plaster of ParisNoGypsum (CaSO4·2H2O)
Plaster of Paris is the trap — it is made from gypsum, NOT from common salt.

Bleaching powder: formula, uses and properties

Property / useDetail
Chemical natureOxidising agent (NOT reducing)
The bank's wrong statement is 'bleaching powder is a reducing agent' — it is an oxidising agent.
Use 1Bleaching wood pulp in paper factories
Use 2Bleaching linen and cotton in textiles
Use 3Disinfecting drinking water
Shared with DDTBoth contain chlorine
Bleaching powder and DDT both contain chlorine — bleaching powder is inorganic, DDT is organic.

Common traps

Lime water is Ca(OH)2, not CaCO3

Limestone, chalk and marble are all calcium carbonate (CaCO3). Lime water is the odd one out — it is a solution of calcium hydroxide, Ca(OH)2, and does NOT represent calcium carbonate.

Milk of magnesia = Mg(OH)2, not a carbonate

Milk of magnesia is magnesium hydroxide, Mg(OH)2 — an antacid base. It is not magnesium carbonate, bicarbonate or sulphate.

Plaster of Paris comes from gypsum, not salt

Washing soda, baking soda and bleaching powder all start from NaCl. Plaster of Paris is the exception — it is made by heating gypsum (CaSO4·2H2O), a calcium mineral, so it is NOT a product of common salt.

Bleaching powder oxidises, it does not reduce

The statement 'bleaching powder is used as a reducing agent' is NOT true — bleaching powder is an oxidising agent (it releases chlorine). Its bleaching and disinfecting actions are oxidation.

Bleaching powder and DDT share chlorine, not calcium

The correct shared fact is that both contain chlorine. They do NOT both contain calcium (DDT has none), and they are not both organic (bleaching powder is inorganic) or both inorganic (DDT is organic).

Water of Crystallization

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Water of crystallization of common salts

SaltFormulaWater molecules
Blue vitriol (copper sulphate)CuSO4·5H2O5
Green vitriol (ferrous sulphate)FeSO4·7H2O7
Ferrous sulphate crystal carries 7 water molecules.
Washing sodaNa2CO3·10H2O10
GypsumCaSO4·2H2O2
Mohr's saltFeSO4·(NH4)2SO4·6H2O6
Potassium permanganateKMnO40 (none)
KMnO4 has NO water of crystallization — the bank's answer for 'which salt has none'.

Water of crystallization and colour

FormColourCause
CuSO4·5H2O (hydrated)BlueWater of crystallization
The blue colour of copper sulphate crystals is due to water — heat it out and it turns white.
CuSO4 (anhydrous, after heating)WhiteWater removed

Common traps

KMnO4 has no water of crystallization

Blue vitriol (5), washing soda (10) and Mohr's salt (6) are all hydrates. Potassium permanganate (KMnO4) is the one with no water of crystallization — there is no dot-water term in its formula.

Blue copper sulphate owes its colour to water

The blue of copper sulphate crystals is caused by the water of crystallization, not by oxygen, nitrogen or hydrogen. Heating drives the water off and the solid turns white.

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