PYQ Vault

Strategy

Score 73+ by taking the paper in the right order

25 questions × 4 marks = 100, with 1 mark lost for each wrong answer, on a clock shared with Physics and Maths. Chemistry is the section where many questions are answered on sight, so the plan is about order: what to answer first, what to calculate after, and what to guess.

marks out of 100
73+
questions attempted
22/25
accuracy on those
86%
of the shared clock
~50 min

The arithmetic of 73+

22 attempted questions at 86% accuracy is 19 right and 3 wrong: 19 × 4 − 3 = 73 marks. The other 3 are not simply left blank. Every multiple-choice question among them still gets an answer at the end, because a guess there is worth more than a blank:

Expected marks from guessing a JEE Mains Chemistry question, by format and by options still in play
QuestionExpected marks from a guessVerdict
MCQ, 4 options left+0.25A blind guess still pays on average. Never leave an MCQ blank at the end.
MCQ, 3 options left+0.67Rule out one option and the guess is worth two-thirds of a mark.
MCQ, 2 options left+1.5Down to two, a guess is worth more than a mark.
Numeric answerclose to −1A numeric answer has no options, so a guess is almost never right and still costs a mark. Enter one only when you have worked it out.

So the formats split. The physical chapters hold 55% of the numeric answers, and a numeric answer is worth something only when you can finish it. Those chapters must be owned, not half-learned. A multiple-choice question is worth something even when you cannot finish it, and more once one option is ruled out on sight.

The shared clock

180 minutes cover all three subjects, and every question pays the same 4 marks. The plan below is a starting budget of about 50 minutes for Chemistry, not a measurement; adjust it from your own mock tests.

  1. 1

    Give Chemistry less time than Maths

    The three subjects share one clock. Many Chemistry questions are answered on sight, so Chemistry can fund the other two. Start from the budget above and adjust it from your own mock tests.

  2. 2

    First sweep: everything you can answer on sight

    Go through all the Chemistry questions once. Answer the reactions, facts and orders you know, and mark the calculations and anything that needs thought.

  3. 3

    Second sweep: the calculations

    Come back to the marked calculations. Write the formula, carry units and powers of ten, and check that the answer is sensible before entering it.

  4. 4

    Last minutes: fill every MCQ

    Any multiple-choice question still blank gets an answer, after ruling out what you can. Numeric answers you have not worked out stay blank.

The formats the paper reuses

A few question formats turn up in every chapter. Each has a way of working that saves time and marks.

How to work each question format on the JEE Mains Chemistry paper
FormatHow to work itWhy
Two statementsJudge each statement on its own, as true or false, before you read the four combinations. Then pick the one combination that matches.The options pair the statements every possible way, so reading them first only invites a guess. One statement judged wrong sends you to the wrong option.
Match the listFix the one pair you are surest of and strike every option that breaks it. Then fix a second pair among what is left.Two certain pairs usually leave one option. Working through all four pairs in order wastes time on the pair you do not know.
How many of the followingMark each item yes or no on the page, then count the marks. Never count by eye or by pattern.Most numeric answers outside physical chemistry are counts like this. One item judged wrongly makes the whole answer wrong, and a wrong numeric answer still costs a mark.
A numeric answerRound only at the end, check the unit the question asks for, and enter the integer it asks for.There are no options to check against. A slip in a power of ten or a unit is a wrong answer.

Calculate — 7 chapters, 9.1 questions a paper

Chapters where 40% or more of the questions are calculations.

Physical chemistry. Most of its questions need arithmetic, and most of the paper's numeric answers come from here.

The approach

  • Learn each chapter's few working formulas until you can write them without looking. Most questions apply one or two of them in order.
  • Carry units and powers of ten through every line. A numeric answer is entered as an integer, so a slip in an exponent is a wrong answer.
  • Take these questions in the second sweep, after everything you can answer on sight.
  • Check that the answer is sensible: a negative concentration, a pH above fourteen or a rate that falls when it should rise means a slip.

Some Basic Concepts of Chemistry

1.50 a paper in 2025–26 · 1.48 in 2021–24 · 72% calculation · 54% numeric

Notes for Some Basic Concepts of Chemistry

The mole in every form: mass, gas volume, solution concentration, percentage composition and the limiting reagent. Its arithmetic runs through every other physical chapter.

Chemical Thermodynamics

1.39 a paper in 2025–26 · 0.76 in 2021–24 · 65% calculation · 60% numeric

Notes for Chemical Thermodynamics

Work of expansion, heat and the first law, Hess's law, then entropy and Gibbs energy. Signs decide most answers: who does work on whom, and which way heat flows.

Chemical Kinetics

1.37 a paper in 2025–26 · 0.75 in 2021–24 · 71% calculation · 63% numeric

Notes for Chemical Kinetics

Rate laws and order, the integrated first-order law with its half-life, and the Arrhenius equation. Most questions are one formula with logarithms.

Equilibrium

1.31 a paper in 2025–26 · 0.82 in 2021–24 · 60% calculation · 46% numeric

Notes for Equilibrium

Kc and Kp, Le Chatelier, then ionic equilibrium: pH, buffers, salt hydrolysis and solubility product. The ionic half carries most of the calculations.

Structure of Atom

1.23 a paper in 2025–26 · 0.84 in 2021–24 · 42% calculation · 35% numeric

Notes for Structure of Atom

Photons, the Bohr model and the hydrogen spectrum, de Broglie and uncertainty, then quantum numbers and electron configuration. Half calculation, half counting electrons and orbitals.

Electrochemistry

1.17 a paper in 2025–26 · 0.81 in 2021–24 · 58% calculation · 55% numeric

Notes for Electrochemistry

Cell potentials and the Nernst equation, Gibbs energy from a cell, conductance and Kohlrausch's law, and Faraday's laws. Sign conventions and units decide the answer.

Solutions

1.09 a paper in 2025–26 · 0.69 in 2021–24 · 65% calculation · 55% numeric

Notes for Solutions

Concentration terms, Raoult's law, and the four colligative properties with the van 't Hoff factor for electrolytes.

Drill — in teaching order

Reactions — 5 chapters, 5.4 questions a paper

Organic reaction chapters, under 40% calculation.

The organic reaction chapters. A question gives a reagent or a short scheme and asks for the product, or names a reaction.

The approach

  • Learn reactions as reagent and product pairs, and say what each reagent does to the molecule: adds, removes, replaces or rearranges.
  • Follow a scheme one step at a time and write each product down. Most wrong answers come from a skipped step.
  • Decide the site first: which carbon, which position on the ring, which atom of the nucleophile attacks. The site is where the options differ.
  • These are first-sweep questions. When a scheme stalls, mark it and move on.

Hydrocarbons

1.56 a paper in 2025–26 · 1.06 in 2021–24 · 23% calculation · 19% numeric

Notes for Hydrocarbons

Alkanes, addition to alkenes and alkynes, ozonolysis, aromaticity and substitution on benzene. Most questions ask which carbon the new group goes to.

Drill — in teaching order

Amines

1.34 a paper in 2025–26 · 1.09 in 2021–24 · 19% calculation · 15% numeric

Notes for Amines

Basicity, preparation, the tests that tell the classes apart, and diazonium salts with their replacement and coupling reactions.

Drill — in teaching order

Aldehydes, Ketones and Carboxylic Acids

1.12 a paper in 2025–26 · 1.22 in 2021–24 · 10% calculation · 8% numeric

Notes for Aldehydes, Ketones and Carboxylic Acids

Nucleophilic addition, the Grignard reagent, reductions, the tests, aldol and Cannizzaro, and acid strength. Short reaction schemes with a product to name.

Haloalkanes and Haloarenes

0.82 a paper in 2025–26 · 0.61 in 2021–24 · 7% calculation · 7% numeric

Notes for Haloalkanes and Haloarenes

The two substitution mechanisms and when each wins, the nucleophile and its product, elimination against substitution, and the haloarenes. Mechanism facts decide most answers.

Alcohols, Phenols and Ethers

0.60 a paper in 2025–26 · 0.79 in 2021–24 · 13% calculation · 10% numeric

Notes for Alcohols, Phenols and Ethers

Acidity of alcohols and phenols, dehydration with its carbocation shifts, the named reactions of phenol, and the cleavage of ethers by HI.

Structure and recall — 7 chapters, 10.0 questions a paper

Structure, bonding and descriptive chapters, under 40% calculation.

Naming, bonding, periodic trends, the blocks of the periodic table, complexes and biomolecules. Most questions test an exact fact, an order or a count from a list.

The approach

  • Learn orders together with their exceptions. The exception is usually what the question tests.
  • For a count from a list, judge every item separately and mark it on the page before counting.
  • Work structure questions from the structure: draw the molecule or complex, count electron pairs or d electrons, then answer.
  • Most of these are first-sweep questions. A fact you do not know is an MCQ to guess at the end, never a numeric answer to guess.

Organic Chemistry - Some Basic Principles and Techniques

2.05 a paper in 2025–26 · 1.65 in 2021–24 · 35% calculation · 29% numeric

Notes for Organic Chemistry - Some Basic Principles and Techniques

Naming, isomers, electron effects and reactive intermediates, then purification and the detection and estimation of elements. The heaviest chapter on the recent papers, and the base for every organic chapter.

Coordination Compounds

1.89 a paper in 2025–26 · 1.44 in 2021–24 · 35% calculation · 29% numeric

Notes for Coordination Compounds

Naming complexes, counting isomers, and crystal field theory with spin-only magnetic moments. Many of its numeric answers are counts from a list.

The d- and f-Block Elements

1.45 a paper in 2025–26 · 1.58 in 2021–24 · 28% calculation · 21% numeric

Notes for The d- and f-Block Elements

Electronic configurations, oxidation states and magnetic moments across the series, the lanthanoid contraction, and the chemistry of dichromate and permanganate.

Chemical Bonding and Molecular Structure

1.28 a paper in 2025–26 · 1.27 in 2021–24 · 35% calculation · 31% numeric

Notes for Chemical Bonding and Molecular Structure

VSEPR shapes, hybridisation, bond order from molecular orbital theory, dipole moments and hydrogen bonding. Mostly structure work on given molecules.

Biomolecules

1.15 a paper in 2025–26 · 0.92 in 2021–24 · 15% calculation · 12% numeric

Notes for Biomolecules

Carbohydrates, amino acids and proteins, vitamins, enzymes and nucleic acids. A recall chapter, with a few counts of peptides and stereocentres.

Classification of Elements and Periodicity

1.12 a paper in 2025–26 · 0.75 in 2021–24 · 13% calculation · 7% numeric

Notes for Classification of Elements and Periodicity

Periodic trends in size, ionisation enthalpy, electron gain enthalpy and electronegativity, with their known exceptions. Short questions, decided by the exceptions.

The p-Block Elements

1.09 a paper in 2025–26 · 1.43 in 2021–24 · 14% calculation · 9% numeric

Notes for The p-Block Elements

Groups thirteen to eighteen: trends, the inert pair effect, oxoacids, interhalogens and xenon compounds. Exact recall of structures and reactions.

The rest of the bank

One chapter is still on the paper but sets under 0.5 questions a paper, so it has notes but no playbook. The 8 chapters below it left the syllabus and are no longer set. They are listed so the 28-chapter bank is accounted for; their past questions stay in the bank for anyone working through older papers.

Chapters outside the strands: the small chapter still on the paper and the chapters that left the syllabus, with total questions and the last year set
ChapterQuestions2025–26Last set
Organic Reaction MechanismsFunctional-group tests and mechanism questions that span the organic chapters. Small on the recent papers; its notes are worth a read once the reaction chapters are done.480.272026
The s-Block ElementsLeft the syllabus880.112026
General Principles and Processes of Isolation of ElementsLeft the syllabus740.052025
PolymersLeft the syllabus460.032025
Environmental ChemistryLeft the syllabus650.002023
HydrogenLeft the syllabus640.002023
Surface ChemistryLeft the syllabus640.002024
Chemistry in Everyday LifeLeft the syllabus490.002023
Solid StateLeft the syllabus330.002024

A few recent questions are still filed under chapters that left the syllabus. They are on live topics, such as salt analysis, so a “last set” year there does not mean the chapter is back.

Own the 7 Calculate chapters

They hold 55% of the numeric answers, the questions a guess cannot save. The other strands are mostly answered on sight once learned.