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MHT-CET Chemistry · Teaching notes

Aromatic Compounds — MHT-CET Chemistry

Aromatic Compounds in MHT-CET Chemistry is a reactions chapter with one HARD question in thirty-five. It asks three kinds of thing: what makes a compound aromatic and which class it belongs to, where an incoming group goes on the benzene ring, and what happens to the side chain or the ring when it is oxidised, ozonised or diazotised. Every PYQ is tagged.

Every subtopic, worked example, formula and trap in one printable document — answers shown, ready to share.

Subtopic notes

Formula & revision sheet

0 formulas · 7 reference tables · 8 gotchas across all subtopics — the exam-eve cheat-sheet

Aromaticity, Classes of Aromatic Compounds and Natural Sources

Reference tables (2)

Aromaticity and the Classes of Aromatic Compounds5 rows
CompoundClass
TroponeNon-benzenoid aromaticQ
Aniline, phenol, naphthaleneBenzenoid aromaticQ
PyrroleHeterocycle with N in the ringQ
Halogen on a ring carbonHaloareneQ
C₆H₅SO₃NaSodium benzene sulphonateQ
Aromatic Compounds from Nature4 rows
CompoundSourceUse
Salicylic acidWillowAspirinQ
EugenolCloveFlavour, dental analgesicQ
ThymolThymeAntisepticQ
Methyl salicylateWintergreenPain-relief rub

Watch out for (1)

Electrophilic Substitution: the Reactions and Where the Group Goes

Reference tables (2)

The Substitution Reactions and Their Reagents5 rows
ReactionReagentProduct from benzene
Gattermann–Koch formylationCO, HCl / anhyd. AlCl₃C₆H₅CHOQ
Exhaustive chlorinationExcess Cl₂ / AlCl₃C₆Cl₆Q
IodinationI₂Not possible — reversibleQ
Friedel–Crafts alkylationCH₃Cl / anhyd. AlCl₃Toluene
Nitrationconc. HNO₃ + conc. H₂SO₄Nitrobenzene
Directing Effects: Ortho/Para or Meta5 rows
StartReagentMajor product
ChlorobenzeneCl₂ / AlCl₃1,4-dichlorobenzeneQ
AnisoleBr₂ in acetic acidp-bromoanisole (90%)Q
ChlorobenzeneCH₃Cl / anhyd. AlCl₃2- and 4-chlorotolueneQ
ChlorobenzeneCH₃COCl / anhyd. AlCl₃2- and 4-chloroacetophenoneQ
Phenolconc. HNO₃ / conc. H₂SO₄2,4,6-trinitrophenolQ

Watch out for (3)

Side-Chain Oxidation, Addition to Benzene, and Diazonium Chemistry

Reference tables (3)

Oxidising the Side Chain5 rows
StartReagentProduct
Ethylbenzenei) alk. KMnO₄ ii) H₃O⁺Benzoic acidQ
CumeneKMnO₄, KOH, Δ; then H₃O⁺Benzoic acidQ
EthylbenzeneDilute HNO₃Benzoic acidQ
TolueneCrO₂Cl₂ / CS₂; then H₃O⁺BenzaldehydeQ
PhenolCrO₃p-BenzoquinoneQ
Addition to Benzene: Ozonolysis and BHC3 rows
ReactionProduct
Benzene triozonide + Zn/H₂OGlyoxalQ
Reagent that converts the triozonide to glyoxalZn + H₂OQ
Benzene + Cl₂, UVBHC; γ-isomer = gammexaneQ
Diazonium Salts, Wurtz–Fittig and a Grignard on a Nitrile4 rows
ReactionProduct or reagent
Aniline + NaNO₂/HCl, coldBenzene diazonium chlorideQ
C₆H₅N₂Cl + R → benzeneR = ethanol (paper's key)Q
H₃PO₂/H₂O does the same job; the paper keys ethanol.
Wurtz–FittigAryl + alkyl halide with NaQ
Benzonitrile + C₆H₅MgBr, then H₃O⁺BenzophenoneQ

Watch out for (4)

PYQ weightage by concept

7 concepts · 35 PYQs — where the marks actually sit, so you know what to drill first

Aromaticity, Classes of Aromatic Compounds and Natural Sources8 PYQs · 23%
ConceptPYQsShare
Aromaticity and the Classes of Aromatic Compounds514%
Aromatic Compounds from Nature39%
Electrophilic Substitution: the Reactions and Where the Group Goes12 PYQs · 34%
ConceptPYQsShare
Directing Effects: Ortho/Para or Meta720%
The Substitution Reactions and Their Reagents514%
Side-Chain Oxidation, Addition to Benzene, and Diazonium Chemistry15 PYQs · 43%
ConceptPYQsShare
Oxidising the Side Chain823%
Diazonium Salts, Wurtz–Fittig and a Grignard on a Nitrile411%
Addition to Benzene: Ozonolysis and BHC39%

Test yourself on Aromatic Compounds

15 past MHT-CET questions from this chapter, timed at 14 minutes and marked the way the exam marks it. You see your score and every answer the moment you finish. Free to start.

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